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1.
R. B. Trumbull M.-S. Krienitz B. Gottesmann M. Wiedenbeck 《Contributions to Mineralogy and Petrology》2008,155(1):1-18
Tourmaline is widespread in metapelites and pegmatites from the Neoproterozoic Damara Belt, which form the basement and potential
source rocks of the Cretaceous Erongo granite. This study traces the B-isotope variations in tourmalines from the basement,
from the Erongo granite and from its hydrothermal stage. Tourmalines from the basement are alkali-deficient schorl-dravites,
with B-isotope ratios typical for continental crust (δ11B average −8.4‰ ± 1.4, n = 11; one sample at −13‰, n = 2). Virtually all tourmaline in the Erongo granite occurs in distinctive tourmaline-quartz orbicules. This “main-stage”
tourmaline is alkali-deficient schorl (20–30% X-site vacancy, Fe/(Fe + Mg) 0.8–1), with uniform B-isotope compositions (δ11B −8.7‰ ± 1.5, n = 49) that are indistinguishable from the basement average, suggesting that boron was derived from anatexis of the local
basement rocks with no significant shift in isotopic composition. Secondary, hydrothermal tourmaline in the granite has a
bimodal B-isotope distribution with one peak at about −9‰, like the main-stage tourmaline, and a second at −2‰. We propose
that the tourmaline-rich orbicules formed late in the crystallization history from an immiscible Na–B–Fe-rich hydrous melt.
The massive precipitation of orbicular tourmaline nearly exhausted the melt in boron and the shift of δ11B to −2‰ in secondary tourmaline can be explained by Rayleigh fractionation after about 90% B-depletion in the residual fluid.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
2.
Krienitz M.-S.; Haase K. M.; Mezger K.; Shaikh-Mashail M. A. 《Journal of Petrology》2007,48(8):1513-1542
A geochemical and petrological study of Miocene to recent alkalibasalts, basanites, hawaiites, mugearites, trachytes, and phonoliteserupted within the Harrat Ash Shamah volcanic field was performedto reconstruct the magmatic evolution of southern Syria. Themajor element composition of the investigated lavas is mainlycontrolled by fractional crystallization of olivine, clinopyroxene,± Fe–Ti oxides and ± apatite; feldspar fractionationis restricted to the most evolved lavas. Na2O and SiO2 variationswithin uncontaminated, primitive lavas as well as variably fractionatedheavy rare earth element ratios suggest a formation by variabledegrees of partial melting of different garnet peridotite sourcestriggered, probably, by changes in mantle temperature. The isotopicrange as well as the variable trace element enrichment observedin the lavas imply derivation from both a volatile- and incompatibleelement-enriched asthenosphere and from a plume component. Inaddition, some lavas have been affected by crustal contamination.This effect is most prominent in evolved lavas older than 3·5Ma, which assimilated 30–40% of crustal material. In general,the periodicity of volcanism in conjunction with temporal changesin lava composition and melting regime suggest that the Syrianvolcanism was triggered by a pulsing mantle plume located underneathnorthwestern Arabia. KEY WORDS: 40Ar/39Ar ages; intraplate volcanism; mantle plume; partial melting; Syria 相似文献
3.
Vorgestellt wird cine Algizidtestvariante, die es erlaubt, unter laboratoriumsmäßig standardisierten Bedingungen ein repräsentatives Sortiment von Vertretern aus den Gruppen der Cyanophyceen, Diatomeen sowie monadaler, kokkaler und ulotrichaler Chlorophyceen zur Überprüfung der Wirksamkeit neu entwiekelter Substanzen einzusetzen. Die Testergebnisse liegen bereits nach 10 bzw. 24 h vor. Die elf Algenreinkulturstämme werden asynchron in Suspensionen bei 30 °C unter Dauerlicht kultiviert. Die Überprüfung der Wirksamkeit der Herbizide Amitrol, Paraquat, Atrazin, Fenuron und 2,4-D-Säure sowie der Algizide Quartolan, Cumasina ,,aktiv“ und Dimanin A zeigte, daß sich der als Bezugsorganismus eingesetzte Reinkulturstamm der Species Chlorella vulgaris (A 6) in seiner Empfindlichkeit gegenüber algiziden Substanzen als repräsentativ für einen großen Teil der übrigen Testorganismen erwies. Abweichungen in der Algizidempfindlichkeit einzelner Vertreter haben ihre Ursache vorwiegend in physiologischen und anatomisehen Besonderheiten bzw. im jeweiligen Volumen-Oberflächenverhältnis und der Bildung von Coenobien. Deshalb kann ein Test mit den ausgewählten Organismen in kurzer Zeit eine umfassende Aussage über den Wirkungsgrad algizider Substanzen ermöglichen. 相似文献
4.
Geochemical compositions of lower crustal and lithospheric mantle xenoliths found in alkali basaltic lavas from the Harrat Ash Shamah volcanic field in southern Syria place constraints on the formation of the Arabian–Nubian Shield in northern Arabia. Compositions of lower crustal granulites are compatible with a cumulate formation from mafic melts and indicate that they are not genetically related to their host rocks. Instead, their depletion in Nb relative to other incompatible elements points to an origin in a Neoproterozoic subduction zone as recorded by an average depleted mantle Sm–Nd model age of 630 Ma.Lithospheric spinel peridotites typically represent relatively low degree (< 10%) partial melting residues of spinel lherzolite with primitive mantle compositions as indicated by major and trace element modelling of clinopyroxene and spinel. The primary compositions of the xenoliths were subsequently altered by metasomatic reactions with low degree silicate melts and possibly carbonatites. Because host lavas lack these signatures any recent reaction of the lherzolites with their host magma can be ruled out. Sm–Nd data of clinopyroxene from Arabian lithospheric mantle lherzolites yield an average age of 640 Ma suggesting that the lithosphere was not replaced since its formation and supporting a common origin of the Arabian lower crustal and lithospheric mantle sections.The new data along with published Arabian mantle xenolith compositions are consistent with a model in which the lithospheric precursor was depleted oceanic lithosphere that was overprinted by metasomatic processes related to subduction and arc accretion during the generation of the Arabian–Nubian Shield. The less refractory nature of the northern Arabian lithosphere as indicated by higher Al, Na and lower Si and Mg contents of clinopyroxenes compared to the more depleted nature of the south Arabian lithospheric mantle, and the comparable low extent of melt extraction suggest that the northern Arabian lithosphere formed in a continental arc system, whereas the lithosphere in the southern part of Arabia appears to be of oceanic arc origin. 相似文献
5.
M. -S. Krienitz R. B. Trumbull A. Hellmann J. Kolb F. M. Meyer M. Wiedenbeck 《Mineralium Deposita》2008,43(4):421-434
We determined the boron isotope and chemical compositions of tourmaline from the Hira Buddini gold deposit within the Archean
Hutti-Maski greenstone belt in southern India to investigate the evolution of the hydrothermal system and to constrain its
fluid sources. Tourmaline is a minor but widespread constituent in the inner and distal alteration zones of metabasaltic and
metadacite host rocks associated with the hydrothermal gold mineralization. The Hira Buddini tourmaline belongs to the dravite–schorl
series with variations in Al, Fe/(Fe+Mg), Ca, Ti, and Cr contents that can be related to their host lithology. The total range
of δ11B values determined is extreme, from −13.3‰ to +9.0‰, but 95% of the values are between −4 and +9‰. The boron isotope compositions
of metabasalt-hosted tourmaline show a bimodal distribution with peak δ11B values at about −2‰ and +6‰. The wide range and bimodal distribution of boron isotope ratios in tourmaline require an origin
from at least two isotopically distinct fluid sources, which entered the hydrothermal system separately and were subsequently
mixed. The estimated δ11B values of the hydrothermal fluids, based on the peak tourmaline compositions and a mineralization temperature of 550°C,
are around +1 and +10‰. The isotopically lighter of the two fluids is consistent with boron released by metamorphic devolatilization
reactions from the greenstone lithologies, whereas the 11B-rich fluid is attributed to degassing of I-type granitic magmas that intruded the greenstone sequence, providing heat and
fluids to the hydrothermal system.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
6.
Kiplagat Kotut Stephen G. Njuguna Francis M. Muthuri Lothar Krienitz 《Limnologica》1999,29(4):377-392
Variations in some physical, chemical, and nutrient conditions were investigated at Turkwel Gorge Reservoir and its inflowing river, Suam between 1994 and 1995. Seasonal changes in inflow volume had the greatest impact on the reservoir and river conditions investigated. A wide fluctuation in inflow volume combined with a regulated outflow independent of season resulted in a draw down of over 10 m in each year. Flood inflows during the wet season resulted in the lowest values of Secchi depth (range, 0.09–2.16 m), electrical conductivity (EC, range = 140–200 mS cm−1) and total alkalinity (TA, range = 75–111 mg l−1) while the highest values were measured during the dry season. A functional relation between EC and TA (TA = 0.529 mg l−1, EC: R2 = 0.876) suggests a predominance of carbonates among the anions. Vertical profiles of temperature and dissolved oxygen (DO) revealed that the reservoir is monomictic with a wide variation in the depth of the daily mixed layer. High values of pH (range = 6.7–8.9) and DO (range = 4.9–9.2 mg l−1) were associated with periods of peak phytoplankton photosynthesis while the lowest values followed reservoir mixing. Peak total nitrogen (TN, range = 119–526 μg l−1) and total phosphorus (TP, range = 8.9–71.6 μg l−1) levels during the wet season resulted from increased river loading. Values of dissolved reactive silica (DRS, range = 0.41–9.77 mg l−1) showed a wet season decline which was related to diatom depletion during the wet season. Annual reservoir areal loading rates of 27.38, 10.90 and 408.5 mg m−2 were computed for TN, TP and DRS respectively based on estimates of inflowing river loads in 1994.
At the inflowing river Suam, low levels of EC (range = 107–210 μS cm−1) and TA (range = 62–125 mg l−1) occurred during the wet season while the highest levels occurred shortly before the river dried up. The first flood water at the resumption of river inflow in March was characterized by very low levels of DO (range = 1.8–8.2 mg l−1) and high levels of TN (range = 205–3354 μg l−1) and TP (102–1259 μg l−1). River pII (6.9–7.7) and DRs (range = 9.01–19.93 mg l−1) varied irregularly throughout the year. 相似文献
7.
Robert B. Trumbull Marc-Sebastian Krienitz Günter Grundmann Michael Wiedenbeck 《Contributions to Mineralogy and Petrology》2009,157(3):411-427
Tourmalines from the Habachtal emerald deposit in the Eastern Alps formed together with emerald in a ductile shear zone during
blackwall metasomatism between pelitic country rocks and a serpentinite body. Electron microprobe and secondary ion mass spectrometric
(SIMS) analyses provide a record of chemical and B-isotope variations in tourmalines which represent an idealized profile
from metapelites into the blackwall sequence of biotite and chlorite schists. Tourmaline is intermediate schorl-dravite in
the country rock and become increasingly dravitic in the blackwall zones, while F and Cr contents increase and Al drops. Metasomatic
tourmaline from blackwall zones is typically zoned optically and chemically, with rim compositions rich in Mg, Ti, Ca and
F compared with the cores. The total range in δ11B values is −13.8 to −5.1‰ and the within-sample variations are typically 3–5‰. Both of these ranges are beyond the reach
of closed-system fractionation at the estimated 500–550°C conditions of formation, and at least two boron components with
contrasting isotopic composition are indicated. A key observation from tourmaline core analyses is a systematic shift in δ11B from the country rock (−14 to −10‰) to the inner blackwall zones (−9 to −5‰). We suggest that two separate fluids were channeled
and partially mixed in the Habachtal shear zone during blackwall alteration and tourmaline-emerald mineralization. A regional
metamorphic fluid carried isotopically light boron as observed in the metapelite country rocks. The other fluid is derived
from the serpentinite association and has isotopically heavier boron typical for MORB or altered oceanic crust.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
8.
Peter Kasprzak Rainer KoschelLothar Krienitz Thomas GonsiorczykKarl Anwand Uwe LaudeKlaus Wysujack Henry BrachThomas Mehner 《Limnologica》2003,33(3):190-204
The Feldberger Haussee, a highly eutrophic stratified hard-water lake located in the eastern part of Germany's Baltic lake district, was selected for a restoration programme combining external nutrient loading reduction and long-term biomanipulation. In 1980 the external phosphorus loading (1.8 g TP m−2 a−1) decreased by 90%, but water quality did not improve significantly within the following 6 years. In 1985 biomanipulation was initiated, with manual removal of cyprinid fish coupled with piscivore introductions as the principal measures. The expected changes in the pelagic community and improvements of water quality occurred after a delay of several years. Despite intensive manual removal of cyprinids and stocking of piscivores, standing stocks of cyprinid fish remained relatively high (130-260 kg ww ha−1) after some years of decline. Compared to the pre-biomanipulation period, mean seasonal (May-September) Daphnia spp. biomass roughly doubled (0.037 g C m−3vs. 0.084 g C m−3). However, the predominance of small (<1 mm) D. cucullata throughout the whole investigation period indicated that planktivory was still substantial. Paired observations between edible phytoplankton biomass and Daphnia spp. indicated that a significant decline in algal stocks would only occur if herbivorous biomass was above a certain threshold (0.2 g C m−3). Reduced external and internal loading in concert with pelagic calcite precipitation were most likely responsible for the decline in lake phosphorus concentrations, thereby substantially improving the water quality of Feldberger Haussee. Although this is not supported by quantitative evidence, we hypothesize that resource-related water quality improvements were caused by changes in the structure of the pelagic community leading to increased calcite precipitation. In agreement with the results of other investigations, we conclude that because stabilising mechanisms such as macrophyte growth were lacking in Feldberger Haussee, biomanipulation in stratified lakes may not be as successful as has been observed in shallow lakes. However, in hard-water lakes, calcite precipitation may act as another stabilising resource-related mechanism. Phosphorus associated with sedimenting calcite particles is insensitive to redox-conditions and may therefore not be re-mobilised from lake sediments even if hypolimnetic oxygen is depleted. 相似文献
9.
M.-S. Krienitz K. M. Haase K. Mezger V. Eckardt M. A. Shaikh-Mashail 《Contributions to Mineralogy and Petrology》2006,151(6):698-716
The Miocene to Quaternary lavas of northwestern Syria range from basanite, alkali basalts, and tholeiites to basaltic andesites, hawaiites, and mugearites. Crustal assimilation and fractional crystallization processes (AFC) modified the composition of the mantle derived magmas. Crustal assimilation is indicated by decreasing Nb/U (52.8–17.9) and increasing Pb/Nd (0.09–0.21) and by variable isotopic compositions of the lavas (87Sr/86Sr: 0.7036–0.7048, 143Nd/144Nd: 0.51294–0.51269, 206Pb/204Pb: 18.98–18.60) throughout the differentiation. Modeling of the AFC processes indicates that the magmas have assimilated up to 25% of continental upper crust. The stratigraphy of the lavas reveals decreasing degrees and increasing depths of melting with time and the strongly fractionated heavy rare earth elements indicate melt generation in the garnet stability field. Modeling of melt formation based on trace element contents suggests that 8–10% melting of the asthenospheric mantle source produced the tholeiites, whereas basanite and alkali basalts are formed by 2–4% melting of a similar source.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users. 相似文献
10.
Andreas Ballot Stephan PflugmacherClaudia Wiegand Kiplagat KotutLothar Krienitz 《Limnologica》2003,33(1):2-9
This paper presents data on the first identification, characterization and quantification of hepatotoxic microcystins and neurotoxic anatoxin-a in water samples of Lake Baringo, Kenya. The shallow turbid Lake Baringo was investigated five times between June 2001 and May 2002. The phytoplankton community was mainly dominated by the cyanobacterium Microcystis aeruginosa. Due to the high turbidity the phytoplankton biomass was low, ranging between 1.5 and 8.2 mg L−1. High mean total phosphorus concentration (1.0 mg L−1) and mean total nitrogen concentration (2.8 mg L−1) typical for hypertrophic lakes were found. Using HPLC technique the hepatotoxins microcystin-LR, -RR and -YR and the neurotoxin anatoxin-a were detected in the water samples. The microcystin concentrations varied from 310 to 19800 μg microcystin-LR equivalents g−1 DW and the anatoxin-a concentration ranged from 270 to 1260 μg g−1 DW. To our knowledge this is the first evidence of cyanobacterial toxins in Lake Baringo. 相似文献