Air–sea CO2 fluxes in the north-eastern shelf of the Gulf of Cádiz (southwest Iberian Peninsula)     

Mariana Ribas-Ribas  Abelardo Gómez-Parra  Jesús M. Forja 《Marine Chemistry》2011,123(1-4):56-66

An intra-annual investigation of the fugacity of CO₂ (fCO₂) has been conducted in surface waters of the north-eastern shelf of the Gulf of Cádiz (SW Iberian Peninsula) in four cruises made in 2006 and 2007. Intra-annual variability of fCO₂ was assessed and is discussed in terms of mixing, temperature and biology. In the study area of the shelf, thermodynamic control over fCO₂ predominates from early May to late November, and this is opposite and similar in magnitude to the net biological effect. However, biological control over fCO₂ predominates during winter. The results suggest that surface waters in the coastal area are under-saturated with respect to atmospheric CO₂ during most of the year; therefore they represent a sink for atmospheric CO₂ between November and May (? 1.0 mmol m^? 2 day^? 1), but a weak source in June (1.3 mmol m^? 2 day^? 1). In contrast, the coastal ecosystems studied (the lower estuary of Guadalquivir Estuary and Bay of Cádiz) acted as a weak sink for atmospheric CO₂ during February (? 1.3 mmol m^? 2 day^? 1) and as a source between May and November (2.6 mmol m^? 2 day^? 1). The resulting mean annual CO₂ flux in the north-eastern shelf of the Gulf of Cádiz was ? 0.07 mol m^? 2 year^? 1 (? 0.2 mmol m^? 2 day^? 1), indicating that the area acts as a net sink on an annual basis.  相似文献   

Lake sedimentary processes and vegetation changes over the last 45k cal a bp in the uplands of south-eastern Amazonia     

José Tasso Felix Guimarães  Prafulla Kumar Sahoo  Mariana Maha Jana Costa De Figueiredo  Karen da Silva Lopes  Markus Gastauer  Silvio Junio Ramos  Cecilio Frois Caldeira  Pedro Walfir M. Souza-Filho  Luiza Santos Reis  Marcio Sousa Da Silva  Paulo Rogenes Pontes  Renato Oliveira Da Silva Junior  Tarcísio Magevski Rodrigues 《第四纪科学杂志》2021,36(2):255-272

This study addresses paleoclimate influences in a southern Amazonia ecotone based on multiproxy records from lakes of the Carajás region during the last 45k cal a bp. Wet and cool environmental conditions marked the initial deposition in shallow depressions with detrital sediments and high weathering rates until 40k cal a bp. Concomitantly, forest and C3 canga plants, along with cool-adapted taxa, developed; however, short drier episodes enabled expansion of C4 plants and diagenetic formation of siderite. A massive event of siderite formation occurred approximately 30k cal a bp under strong drier conditions. Afterwards, wet and cool environmental conditions returned and persisted until the Last Glacial Maximum (LGM). The LGM was marked by lake-level lowstands and subaerial exposure. The transition from the LGM to the Holocene is marked by the onset of oscillations in temperature and humidity, with an expansion of forest and canga plants. Cool taxa were present for the last time in the Carajás region ~ 9.5–9k cal a bp. After 10k cal a bp , shallow lakes became upland swamps due to natural infilling processes, but the current vegetation types and structures of the plateaus were acquired only after 3k cal a bp under wetter climatic conditions.  相似文献   

Ecotoxicological evaluation of dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro State,Brazil) using bioassays with earthworms and collembolans     

Mariana Vezzone  Ricardo Cesar  Helena Polivanov  Aline Serrano  Danielle Siqueira  Leticia Abreu  Miriam Bianchi  Maria Elizabeth Correia  Zuleica Castilhos  Tácio de Campos 《Environmental Earth Sciences》2018,77(21):743

The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   

Tritium in the Dead Sea     

I. Carmi  J.R. Gat  M. Stiller 《Earth and Planetary Science Letters》1984,71(2):377-389

Tritium data in the Dead Sea for the period 1960–1979 are given. Tritium levels have increased until 1965 in the upper layers of the Dead Sea reaching a level of 170 TU, in response to the atmospheric buildup of tritium from thermonuclear testing. The levels have been decreasing ever since, both because of rapidly declining atmospheric concentrations of tritium and because of mixing of the surface layers with tritium deficient, deeper water masses. The depth of penetration of the tracer delineated the depth of meromictic stratification and successfully monitored the deepening of the pycnocline, until the overturn in 1979 homogenised the entire tritium profile. Modelling the changing tritium inventory over this period showed the predominance of the direct exchange across the air/sea interface, both in the buildup of tritium in the lake and also in its subsequent removal from it. The good fit between calculated and measured tritium inventories confirmed the evaporation estimate of 1.46 m/yr (the mean value for the period) with a precision unattained by other methods.  相似文献   

Iron in the Dead Sea     

A. Nishri  M. Stiller 《Earth and Planetary Science Letters》1984,71(2):405-414

The distributions of dissolved and of particulate iron in the Dead Sea during the period which preceeded its overturn and thereafter (1977–1980) are reported. During 1977–1978, the vertical profiles of the iron phases revealed facets of the mixing pattern: the progressive deepening of the pycnocline, restricted mixing within the upper water mass and penetration of surface waters into the deepest layer. The inventories of particulate iron suggest resuspension of bottom sediments in November 1978 and after the overturn the gradual disappearance from the water column of iron sulfides and iron oxy-hydroxides. Fluxes of iron from and to the lake in the undisturbed meromictic Dead Sea have been estimated: it appears that diffusion of divalent iron from bottom sediments was the major source for the standing crop of iron in the lower water mass. Low settling velocities of solid particles in the dense and viscous Dead Sea is one of the causes for the relatively large concentrations of particulate iron. The rate constant for oxidation of divalent iron in Dead Sea sediment interstitial waters is larger by two orders of magnitude than in other natural waters.  相似文献   

Thermomagnetic analysis of magnetite parts of serpentinite samples and results of other investigations     

Dr. H. Stiller  Dr. Dr. F. Frölich Dipl.-Geophys.  F. Ch. Wagner 《Pure and Applied Geophysics》1961,49(1):129-136

Summary The normal type of serpentinites consists of chrysotile. The magnetite parts are essential parts of the structure of chrysotile serpentinites (primary magnetite). Chrysotile is changed to antigorite by mechanical deformations. The magnetite parts of rock structure are lost and they sat down in the veins of serpentinite rocks (secondary magnetite). In this paper the thermomagnetic diagrams and the results of X-ray investigations of secondary and primary magnetite are described. Some results of susceptibility measurements are given. The secondary magnetite is characterized by a region of oxydation in the interval 280–400° C (secondary magnetite-Fe₂O₃-Fe₂O₃). The oxydation to -Fe₂O₃ is remarkably. On the thermomagnetic diagrams of primary magnetite no typical oxydation region is to be seen. The oxydation: primary magnetite-Fe₂O₃ is very small. The interval of measured susceptibility values amounts to (10–1500)·10^–6 cgs units. The essential variability of the main parts of serpentinite samples is characterized by the great changes of susceptibility values from point to point.The determined values of specific saturation magnetization (Gauss. cm³ g^–1), the X-ray powder data, and some results on remanent magnetization are given.

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Zusammenfassung Die Normaltypserpentinite bestehen aus Chrysotil. Der Magnetit ist Bestandteil der Struktur der Chrysotilserpentinite (primärer Magnetit). Unter dem Einfluß mechanischer Deformationen geht Chrysotil in Antigorit über. Die Magnetitanteile der Gesteinsstruktur gehen verloren und scheiden sich auf Klüften ab (sekundärer Magnetit). In der vorliegenden Arbeit werden die thermomagnetischen Abhängigkeiten und die Ergebnisse von Röntgenuntersuchungen des sekundären und primären Magnetits beschrieben. Es werden einige Ergebnisse der Suszeptibilitätsmessungen angeführt. Der sekundäre Magnetit wird durch einen Oxydationsbereich im Temperaturintervall 280–400° C charakterisiert (sekundärer Magnetit-Fe₂O₃-Fe₂O₃). Die Oxydation zu -Fe₂O₃ ist beträchtlich. Die thermomagnetischen Diagramme des primären Magnetits zeigen keinen typischen Oxydationsbereich. Die Oxydation: primärer Magnetit-Fe₂O₃ ist sehr gering. Das Intervall der gemessenen Suszeptibilitätswerte beträgt (10–1500)·10^–6 CGS-Einheiten. Die starke Veränderlichkeit der Hauptbestandteile der Serpentinitproben wird durch die großen Änderungen der Suszeptibilitätswerte von Punkt zu Punkt gekennzeichnet.Die gemessenen Werte der Sättigungsmagnetisierung (Gauss.cm³ g^–1), der Röntgenuntersuchungen und einige Ergebnisse über die remanente Magnetisierung werden gegeben.

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Geodynamics and state of the earth's interior     

Heinz Stiller  Siegfried Franck  Diedrich Möhlmann 《Journal of Geodynamics》1984,1(1):79-100

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International Symposium on Seismology and Physics of Solids of the Earth's Interior in Jena     

Heinz Stiller 《Journal of Geodesy》1974,48(4):425-426

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Interpretation of Changes in Curie-Temperatures Observed in Rocks     

H. Löffler  F. Frölich  H. Stiller 《Geophysical Journal International》1965,9(5):411-422

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Temporal variability of the Buenos Aires, Argentina, urban heat island     

Inés Camilloni  Mariana Barrucand 《Theoretical and Applied Climatology》2012,107(1-2):47-58

This paper describes the statistical characteristics and temporal variability of the urban heat island (UHI) intensity in Buenos Aires using 32-year surface meteorological data with 1-h time intervals. Seasonal analyses show that the UHI intensity is strongest during summer months and an “inverse” effect is found frequently during the afternoon hours of the same season. During winter, the UHI effect is in the minimal. The interannual trend and the seasonal variation of the UHI for the main synoptic hours for a longer record of 48?years are studied and associated to changes in meteorological factors as low-level circulation and cloud amount. Despite the population growth, it was found a negative trend in the nocturnal UHI intensity that could be explained by a decline of near clear-sky conditions, a negative trend in the calm frequencies and an increase in wind speed. Urban to rural temperature differences and rural temperatures are negatively correlated for diurnal and nocturnal hours both for annual and seasonal scales. This result is due to the lower interannual variability of urban temperatures in comparison to rural ones.  相似文献