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1.
V. Garnier D. Ohnenstetter G. Giuliani P. Blanc D. Schwarz 《Mineralogy and Petrology》2002,76(3-4):179-193
Summary ?Mong Hsu rubies of the “trapiche” type are sporadically seen in the gem market. However, they have never been described in
the field. The study of the nature of solid inclusions, the variation of trace-element contents, as well as the cathodoluminescence
behaviour of six “trapiche” rubies permit the conclusion that these rubies crystallised in the same geological environment
(marble-type deposit) as the normal rubies from Mong Hsu: (1) Cr and V are the main chromophorous elements in both ruby types;
they act, together with Ti, as activators or quenchers for cathodoluminescence; (2) calcite, dolomite, rutile, mica, diaspore,
apatite, chlorite, and feldspar are solid inclusions found in both ruby types; (3) the presence of bastn?site in trapiche
ruby and fluorite in non-trapiche ruby indicates the circulation of F-bearing fluids during ruby deposition; (4) the distribution
of trace-element contents in the crystal is similar for both ruby types. In the Cr2O3 vs. Fe2O3 and Cr2O3 vs. Fe2O3/TiO2 diagrams, the population fields of Mong Hsu “trapiche” and non-“trapiche” rubies overlap. They are distinct from those of
rubies and sapphires hosted in basalts from South-east Asia.
Received October 30, 2001; revised version accepted March 25, 2002 相似文献
2.
L. Beccaluva D. Ohnenstetter M. Ohnenstetter A. Paupy 《Contributions to Mineralogy and Petrology》1984,85(3):253-271
Within the Vourinos ophiolite evidence of two magmatic series has been preserved in cognate cumulates and in effusive and hypabyssal rocks, which constitute the earlier Krapa sequence and the younger Asprokambo sequence. The Asprokambo dyke basic magmas which are poor in incompatible elements and relatively Ni and Cr rich, bear some resemblance to very low Ti basalts (transitional to boninites) found in subduction related arcs or interarc basins. Krapa series magmas from sills, massive and pillow lavas are best equated with low-K tholeiites of island arc suites. Compositions of Al- and Ti- poor Cpx in lavas from both series are comparable to those in island arc basalts, the Asprokambo Cpx being richer in Ca and Cr than those from Krapa.The large volume of cumulates from the Krapa sequence displays the following crystallization order: Ol±Sp, Cpx, Pl±Opx, Mt. Periodic influx of fresh magma batches into the magma chamber occurred mainly during the formation of the lower cumulates (wehrlite, Ol-clinopyroxenite and melagabbro). The upper cumulates, gabbronorite and leucogabbronorite with minor Mt-bearing gabbronorite, crystallized in the upper levels of a magma chamber which became progressively smaller with time. In the Asprokambo sequence, Ol+Sp, Opx, Cpx, PI and Amph are the successively crystallizing phases. The ortho to heteradcumulates consist of websterite, Pl-websterite, gabbronorite, amphibole bearing leuconorite, diorite and granophyre. In cumulates, especially in the lower Krapa sequence, significant subsolidus reaction was probably induced by the persistence of high geothermal gradients linked to continuous magmatism. Petrological features indicate that the evolution of the Krapa series is more compatible with an intermediate fractional/equilibrium crystallization history in an initially open system, whereas nearly perfect fractional crystallization in closed system may have occurred in the small Asprokambo magma chambers. Chemical variations in the lavas of both series can be explained in terms of crystallization of the observed cumulates. Significantly, the Asprokambo intrusives have igneous Mg-hornblende and vanadium bearing, chromian, aluminous titaniferous magnetite, crystallization of which is responsible for the calcalkaline evolutionary trend of these rocks. Major and trace element modelling necessitates a two stage model for the petrogenesis of the Vourinos parental melts, involving high-degree remelting of previously depleted mantle sources favoured by the influx of subduction derived hydrous fluids. The primary magmas parental to the Krapa and Asprokambo series could have been derived respectively by 20 and 30% equilibrium partial fusion of variably depleted lherzolitic sources, leaving residua having a harzburgitic to dunitic composition. 相似文献
3.
4.
M. Ohnenstetter 《Mineralogy and Petrology》1992,46(1):85-107
Summary Positive platinum and gold anomalies (up to 130 and 54 ppb, respectively)have been identified in ophiolitic mantle peridotites from the Monte Maggiore Massif(MMM), Corsica.Forty-four grains of platinum-group minerals (PGM) were found in seven rock samples with Pt, Pd, Os and Ir contents as low as 20,10, 5 and 1.9 ppb, respectively. PGM are mainly alloys: of native osmium, iridium, platinum, palladium and gold, tetraferroplatinum more or less rich in copper, the Cu-bearing equivalent of rustenburgite, potarite, moncheite and Ni-rich merenskyite. The presence of these low temperature minerals (<650°C) which precipitated after the pentlandite, allows us to rule out the possibility of a magmatic origin for platinum group element (PGE) anomalies. Therefore the model presented here proposes the late precipitation of PGM linked to a hydrothermal system created by the rising of a fluid-enriched magma occurring under a mid-oceanic ridge during the diapiric uprising of asthenospheric mantle at about 0.9 GPa.Compositional evolution of tetraferroplatinum and late stage precipitation of tellurides and intermetallic compounds are evidence of PGE fractionation as the fluid became progressively enriched in Te, Bi, Cu, Sri and Pb, and depleted in S. This occurred during the transport and entrapment of the fluid in cooler parts of the residual peridotite surrounding the melting zone.The proposed mechanism for PGE anomalies in the Monte Maggiore mantle peridotites illustrates a mineralizing process involving concentration and transport of PGE through a fluid-rich medium followed by sudden precipitation of PGM along preferential fractures caused by a thermal gradient.
With 3 Figures and 2 Plates 相似文献
Enrichissement en éléments du groupe du platine (EGP) dans les péridotites ophiolitiques du manteau supérieur, massif du Monte Maggiore, Corse: mise en évidence, à partir d'études minéralogiques, d'un métasomatisme lié à un fluide minéralisant
Résumé Dans le Massif du Monte Maggiore (MMM), Corse, des anomalies de platine et d'or (respectivement, jusqu' à 130 et 54 ppb) ont été mises en évidence dans des péridotites du manteau ophiolitique.Quarante quatre grains de minéraux du groupe du platine (MGP) ont été observés dans sept échantillons ayant des teneurs en Pt, Pd, Os et Ir respectivement aussi faibles que 20, 10, 5 et 1,9 ppb. Les MGP sont principalement des alliages: osmium, iridium, platine, palladium et or natifs, téétraferroplatine plus ou moins riche en cuivre, équivalent cuprifère de la rustenburgite, potarite, ainsi que monchéite et merenskyite riche en nickel. Ces minéraux de basses températures (< 650 °C) qui ont précipité après la pentlandite permettent d'écarter une origine magmatique pour les anomalies en éléments du groupe du platine (EGP). A l'opposé, le modèle propose une précipitation tardive des MGP liée à un système hydrothermal créé par la montée d'un magma enrichi en fluides, au sein d'un diapir mantellique ascendant à l'aplomb d'une dorsale médioocéaniq,ue, sous des pressions de l'ordre de 0.9 GPa.L'évolution de la composition des tétraferroplatines et la cristallisation tardive des tellurures et des composés intermétalliques témoignent du fractionnement des EGP, alors que le fluide minéralisant s'enrichit progressivement en Te, Bi, Cu, Sn et Pb et s'appauvrit en S. Ceci s'est produit durant le transport et le piégeage du fluide dans les zones plus froides du massif représentées par les péridotites résiduelles autour de la zone de fusion.Le mécanisme proposé pour les péridotites anomales en EGP du manteau du Monte Maggiore illustre un type de processus minéralisant impliquant la concentration et le transport des EGP dans un milieu enrichi en fluides, suivi de la précipitation rapide des MGP le long de fractures préférentielles sous l'effet d'un gradient thermique.
With 3 Figures and 2 Plates 相似文献
5.
Gaston?GiulianiEmail author Anthony?Fallick Daniel?Ohnenstetter Guy?Pegere 《Mineralium Deposita》2009,44(2):221-231
Alluvial and colluvial gem sapphires are common in the basaltic fields of the French Massif Central (FMC) but sapphire-bearing
xenoliths are very rare, found only in the Menet trachytic cone in Cantal. The O-isotope composition of the sapphires ranges
between 4.4 and 13.9‰. Two distinct groups have been defined: the first with a restricted isotopic range between 4.4 and 6.8‰
(n = 22; mean δ18O = 5.6 ± 0.7‰), falls within the worldwide range defined for blue-green-yellow sapphires related to basaltic gem fields (3.0 < δ18O < 8.2‰, n = 150), and overlaps the ranges defined for magmatic sapphires in syenite (4.4 < δ18O < 8.3‰, n = 29). A second group, with an isotopic range between 7.6 and 13.9‰ (n = 9), suggests a metamorphic sapphire source such as biotite schist in gneisses or skarns. The δ18O values of 4.4–4.5‰ for the blue sapphire-bearing anorthoclasite xenolith from Menet is lower than the δ18O values obtained for anorthoclase (7.7–7.9‰), but suggest that these sapphires were derived from an igneous reservoir in
the subcontinental spinel lherzolitic mantle of the FMC. The presence of inclusions of columbite-group minerals, pyrochlore,
Nb-bearing rutile, and thorite in these sapphires provides an additional argument for a magmatic origin. In the FMC lithospheric
mantle, felsic melts crystallized to form anorthoclasites, the most evolved peraluminous variant of the alkaline basaltic
melt. The O-isotopic compositions of the first group suggests that these sapphires crystallized from felsic magmas under upper
mantle conditions. The second group of isotopic values, typified for example by the Le Bras sapphire with a δ18O of 13.9‰, indicates that metamorphic sapphires from granulites were transported to the surface by basaltic magma. 相似文献
6.
M. Ohnenstetter D. Ohnenstetter Ph. Vidal J. Cornichet D. Hermitte J. Mace 《Earth and Planetary Science Letters》1981,54(3):397-408
In Corsica, albitites and albite-granites are considered to be the latest products of an ophiolitic magma. Two albitites have been selected for a study of the morphology, typology and age of their zircons, applying for the first time the U-Pb method to Western Tethyan ophiolites. Both samples come from the Rospigliani series, possibly formed in a transform fault zone. The first one shows a cumulate texture, whereas the second has features indicative of more rapid cooling. Zircons have precipitated at the end of the fractional crystallization process after a strong enrichment in alkali and incompatible elements. In a typological diagram they plot at high temperature and high agpaicity indexes. These abundant large, euhedral to subhedral zircons, sometimes with fine zoning, may also contain inclusions of granitic composition which testifies to K fractionation in ophiolitic magmas. The U-Pb age of 161±3Myr is in the range of the ages obtained for Alpine and Apennines ophiolites. All these ophiolitic remnants belonging to the Liguro-Piedmont Basin may represent a portion of the Central Atlantic Ocean created during Middle and Upper Jurassic times. 相似文献
7.
Karl Hans Wedepohl Maryse H. Delevaux Bruce R. Doe 《Contributions to Mineralogy and Petrology》1978,65(3):273-281
New lead isotopic compositions have been measured for Paleozoic bedded and vein ore deposits of Europe by the high precision thermal emission (triple filament) technique. Eleven samples have been analyzed from the Upper Permian Kupferschiefer bed with representatives from Poland to England, three samples from the Middle Devonian Rammelsberg deposit and one from the Middle Devonian Meggen deposit, both of which are conformable ore lenses and are in the Federal Republic of Germany (FRG); and also two vein deposits from the FRG were analyzed, from Ramsbeck in Devonian host rocks and from Grund in Carboniferous host rocks. For Kupferschiefer bed samples from Germany, the mineralization is of variable lead isotopic composition and appears to have been derived about 250 m.y. ago from 1700 m.y. old sources, or detritus of this age, in Paleozoic sedimentary rocks. Samples from England, Holland, and Poland have different isotopic characteristics from the German samples, indicative of significantly different source material (perhaps older). The isotopic variability of the samples from the Kupferschiefer bed in Germany probably favors the lead containing waters coming from shoreward (where poor mixing is to be expected) rather than basinward (where better mixing is likely) directions. The data thus support the interpretation of the metal source already given by Wedepohl in 1964. Data on samples from Rammelsberg and Meggen tend to be slightly less radiogenic than for the Kupferschiefer, about the amount expected if the leads were all derived from the same source material but 100 to 150 m.y. apart in time. The vein galena from Ramsbeck is similar to that from Rammelsberg conformable ore lenses, both in rocks of Devonian age; vein galena from Grund in Upper Carboniferous country rocks is similar to some bedded Kupferschiefer mineralization in Permian rocks, as if the lead composition was formed at about the same time and from similar source material as the bedded deposits. Although heat has played a more significant role in the formation of some of these deposits (veins and Rammelsberg-Meggen) than in others (Kupferschiefer), there is no indication of radically different sources for the lead, all apparently coming from sedimentary source material containing Precambrian detritus. One feldspar lead sample from the Brocken-Oker Granite is not the same in isotopic composition as any of the ores analyzed.Publication authorized by the Director, U.S. Geological Survey 相似文献
8.
Jean Macaudière William L. Brown Daniel Ohnenstetter 《Contributions to Mineralogy and Petrology》1985,89(1):39-51
The very fine-grained (1 m) polygonal microcrystalline texture occurring in the groundmass of pseudotachylite veins in the Harris meta-anorthosite and its variation with position are described and an origin by crystallization from a melt at very large undercooling suggested. The intrusive nature of the veins is shown by their geometry and internal structures. Clasts, which are almost always only plagioclase, are generally concentrated towards the centres of veins. Flow of tens of millimetres can account for this concentration in millimetre-thick veins as a result of the Bagnold effect. The veins are generally thin (5 m to 5 mm or more), are frequently zoned and always contain transparent granules of high relief (probably Al-rich pyroxene) and opaque granules of magnetite up to a few micrometres in size. The granules are either uniformly distributed in microcrystalline textures or concentrated locally giving cellular textures. In some veins, spherulitic or bow-tie textures occur. The coarsest textures are found in the centres of the thickest veins. The groundmass of the pseudotachylite is never completely isotropic but consists of a mosaic of transparent plagioclase crystals decreasing in size from the centres of thick veins to less than 1 m in thin veins or in the margins of thicker veins. This fine microcrystalline texture was studied by both scanning and transmission electron microscopy and consists of polyhedral crystals of regular size in the range 0.2–1.5 m, which show little sign of deformation. The local composition of the pseudotachylites varies little from the average compositions of the rocks in optically homogeneous veins, the variation being within the compositional space defined by the minerals of the host rock. This shows that homogenization of the pseudotachylite has occurred. In cellular veinsdifferentiation has occurred as the compositions of the cell centres lie outside those of the minerals of the host rock. This was produced by segregation of the granules, pyroxene being absent from the host rock. The plagioclase in the pseudotachylite is more disordered than that in the host rock. All the microtextures described are absent from the associated cataclasites and cannot be due to recrystallization of a fine-grained and intensely strained rock powder. The physical state on and after intrusion was that of a melt and injection was followed by crystallization. The melt was produced by more or less total fusion of the host rock minerals at shallow depth by heat produced during local faulting and perhaps during crack propagation. The fine microcrystalline texture very closely resembles that produced during hypercooling of molten metals and alloys. It thus possibly formed not by devitrification but from a melt at much greater degrees of undercooling than the spherulitic and bow-tie textures. 相似文献
9.
Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin 总被引：1，自引：1，他引：1
Gaston Giuliani Anthony Fallick Michel Rakotondrazafy Daniel Ohnenstetter Alfred Andriamamonjy Théogène Ralantoarison Saholy Rakotosamizanany Marie Razanatseheno Yohann Offant Virginie Garnier Christian Dunaigre Dietmar Schwarz Alain Mercier Voahangy Ratrimo Bruno Ralison 《Mineralium Deposita》2007,42(3):251-270
The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone
geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and
alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks).
In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation
of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits
(placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios
(18O/16O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ18O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ18O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths
contained in the alkali basalt of Soamiakatra have δ18O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ18O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo).
The δ18O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in
placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ18O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ18O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety
of colored sapphires and rubies, with δ18O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum
from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have
a large variety of colored sapphires and rubies with a large variation in δ18O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire,
syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire. 相似文献
10.
John S. Stacey Bruce R. Doe Ralph J. Roberts Maryse H. Delevaux John W. Gramlich 《Contributions to Mineralogy and Petrology》1980,74(2):175-188
New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation.The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics.In the eastern part of the shield, east of longitude 44°20E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100±300 m.y. (2).The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also from near Muscat in Oman. These data are the first to indicate such old continental material in these regions. 相似文献