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For the ammonia-oxidizing bacterium Nitrosomonas europaea, grown autotrophically using semicontinuous culturing, average biomass was depleted in 13C relative to CO2 dissolved in the medium by ca. 20‰ and the total-lipid extract was depleted in 13C relative to biomass by 3.7‰. The n-alkyl lipids (weighted average of fatty acids) and isoprenoid lipids (weighted average of hopanoids) were both depleted in 13C relative to biomass by about 9‰. The large depletion in the isoprenoid lipids seems to indicate that isotopic fractionations associated with the biosynthesis of methylerythritol phosphate (MEP) affected at least two carbon positions in each isoprene unit. Among the fatty acids, trans-9-hexadecenoic acid was most depleted (13.0‰ relative to biomass), followed by cis-9- hexadecenoic acid (9.6‰) and hexadecanoic acid (6.9‰). Isotopic relationships between the three acids suggest that significant isotope effects were associated with the desaturation and cis to trans isomerization of fatty acids. Given these observations, hopanoids produced by ammonia-oxidizing bacteria growing in natural waters are likely to be depleted in 13C by 26–30‰ relative to dissolved CO2. Since CO2 at aquatic oxyclines is often depleted in 13C, the range of δ values expected for hopanoids is ca. −34‰ to −55‰. The δ values of geohopanoids observed in numerous studies and attributed to unspecified chemoautotrophs fall within this range.  相似文献   
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Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types. Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F 0| > 4σF 0] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal, where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified as autoepitaxy.  相似文献   
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In this study, the inverse method is used to compute the Kuroshio in the East China Sea and southeast of Kyushu and the currents east of the Ryukyu Islands, on the basis of hydrographic data obtained during September-October, 1987 by R/V Chofu Maru. The results show that: (1)A part of the Taiwan Warm Current has a tendency to converge to the shelf break; (2) the Kuroshio flows across the section C3 (PN) with a reduced current width, and the velocity of the Kuroshio at the section C3 increases and its maximum current speed is about 158 cm/s, and its volume transport here is about 26×106m3/s; (3) the Kuroshio has two current cores at the sections C3 (PN) and B2 (at the Tokara Strait); (4) the currents east of the Ryukyu Islands are found to flow northward over the Ryukyu Trench during September-October, 1987. The velocities of the currents are not strong throughout the depths. At the section C2 east of the Ryukyu Islands, the maximum current speed is at the 699 m levei and its magnitude is 25 cm/s, and i  相似文献   
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It is shown by a numerical experiment with fine grid that the finite difference form of rotation of the Coriolis force used in ENDOH (1973) gives practically the same solution as that obtained by the use of the finite difference form pointed out byTakano (1974).  相似文献   
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A numerical experiment is made using a barotropic model for the western boundary currents. The time-dependent, non-linear vorticity equation is integrated with and without the variable of bottom topography. The inertial and frictional boundary flow is resolved with a fine grid size of 10 km. Connection of the western boundary currents with the general circulation is facilitated by giving the fixed Sverdrup transport at the eastern boundary of the model (400 km offshore).For the flat bottom topography, steady flow forRe=35 shows dynamical balance essentially of a frictional model. The transient response leading to the formation of the western boundary currents in the model seems to support theLighthill's theory (1969). ForRe=350, unsteady features revealed byBryan (1963) is re-established. A phenomenon of barotropic instability is also observed with sufficient resolution. For the model with a continental slope the steady flow is also obtained forRe=35. The boundary currents flow over the continental slope, deviating offshore as they flow northward.  相似文献   
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Time-series measurements of temperature, salinity, suspended matter and beam attenuation coefficient () were measured at four hour intervals for about two days in June/ July 1982 in the middle shelf region and the coastal region of the southeastern Bering Sea. Current meters were also moored at the same locations.Depth-time distributions of indicated that profiles of suspended matter resulted from a combined process of resuspension of underlying sediments and sinking of suspended particles. Average-values for all measurements for particles revealed that the upward transport of particles due to resuspension formed a boundary layer, with a thickness apparently related to scalar speed. The average-profiles of the particle volume concentration were assumed to result from a balance between the sinking and diffusive flux of particles under a steady state, and the upward fluxes were calculated. Within the boundary layer, values of the upward fluxes of particulate organic matter linearly decreased with the logarithm of distance from the bottom. Fluxes of organic carbon at the upper edge of the boundary layer were 0.375 gC·m–2·day–1 in the middle shelf region (18 m above the bottom, bottom depth=78m) and 0.484gC·m–2·day–1 in the coastal region (25 m above the bottom, bottom depth=33m), and fluxes of nitrogen in both regions were 0.067 gN·m–2·day–1. The flux of organic carbon obtained in the middle shelf region (18 m above the bottom) agreed approximately with the flux (0.416 gC·m–2·day–1) calculated by substituting primary production data into the empirical equation of Suess (1980).  相似文献   
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