Occurrence of noble metals in aluminum- and chromium- rich objects in ordinary chondrites and of baddeleyite (ZrO2) in a chromite inclusion     

M. Christophe Michel-Lvy  E. Robin  Ph. Blanc 《Meteoritics & planetary science》1995,30(1):15-19

Abstract— Platinum group elements (PGE) enrichments are found in Fe-Ni blebs (<1 μm) in Al- and Cr-rich objects in the ordinary chondrites Ste. Marguerite, Forest Vale, Montferré. In Ste. Marguerite, high ZrO₂ concentrations (baddeleyite) are also present in a chromite inclusion. Iridium enrichment in this material compared to its metal content is confirmed by INAA. The widespread occurrence of PGE in Al- and Cr-rich objects, mostly present in H-group chondrites of nearly equilibrated types, must be taken into account to understand their conditions of formation.  相似文献   

Trace-element contents and cathodoluminescence of “trapiche” rubies from Mong Hsu, Myanmar (Burma): geological significance     

V. Garnier  D. Ohnenstetter  G. Giuliani  P. Blanc  D. Schwarz 《Mineralogy and Petrology》2002,76(3-4):179-193

Summary ?Mong Hsu rubies of the “trapiche” type are sporadically seen in the gem market. However, they have never been described in the field. The study of the nature of solid inclusions, the variation of trace-element contents, as well as the cathodoluminescence behaviour of six “trapiche” rubies permit the conclusion that these rubies crystallised in the same geological environment (marble-type deposit) as the normal rubies from Mong Hsu: (1) Cr and V are the main chromophorous elements in both ruby types; they act, together with Ti, as activators or quenchers for cathodoluminescence; (2) calcite, dolomite, rutile, mica, diaspore, apatite, chlorite, and feldspar are solid inclusions found in both ruby types; (3) the presence of bastn?site in trapiche ruby and fluorite in non-trapiche ruby indicates the circulation of F-bearing fluids during ruby deposition; (4) the distribution of trace-element contents in the crystal is similar for both ruby types. In the Cr₂O₃ vs. Fe₂O₃ and Cr₂O₃ vs. Fe₂O₃/TiO₂ diagrams, the population fields of Mong Hsu “trapiche” and non-“trapiche” rubies overlap. They are distinct from those of rubies and sapphires hosted in basalts from South-east Asia. Received October 30, 2001; revised version accepted March 25, 2002  相似文献   

Th sorption and export models in the water column: A review   总被引：2，自引：3，他引：2  

Nicolas Savoye  Claudia Benitez-Nelson  Adrian B. Burd  J. Kirk Cochran  Matthew Charette  Ken O. Buesseler  George A. Jackson  Matthieu Roy-Barman  Sabine Schmidt  Marc Elskens 《Marine Chemistry》2006,100(3-4):234

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.  相似文献   

Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System     

E. Lemaire  G. Blanc  J. Schäfer  A. Coynel  H. Etcheber 《Aquatic Geochemistry》2006,12(1):21-38

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.  相似文献   

Re-Os Isotopic Measurements at the Femtomole Level in Natural Samples   总被引：17，自引：0，他引：17  

Jean Louis Birck  Matthieu Roy Barman  Françoise Capmas 《Geostandards and Geoanalytical Research》1997,21(1):19-27

Here we describe a new chemical separation method for Os and an improved mass spectrometric procedure for Re and Os. This technique is based on the selective extraction of OsO₄ from aqueous solution in liquid bromine. Among other advantages, this procedure avoids the cumbersome distillation procedure for Os and uses only commercial "off the shelf" PFA teflon labware. Blank levels for 0.5 g sample sizes are: 0.06 pg and 0.5 pg for Os and Re respectively. Samples containing as little as 1 pg g⁻¹ Os can be analysed reliably with this method. Adaptation to other dissolution methods is also discussed.  相似文献   

A short range interaction model applied to illite/smectite mixed-layer minerals     

P. Blanc  A. Bieber  B. Fritz  J. Duplay 《Physics and Chemistry of Minerals》1997,24(8):574-581

We present a solid solution model, able to take into account short-range interactions up to the third nearest neighbor. This model has been applied to illite/smectite mixed-layer clay minerals and tests the relative thermodynamic stability of each illite/smectite stacking sequence. The non-ideal energy terms have been calculated, showing a strong decrease of the interaction energy as the distance between elements grows. From ΔG _m calculations the model predicts the following succession in I/S stacking sequences as X _i tends to 1:R1, R2 and then R3. This succession agrees well with some mineralogical observations in natural series. Received: July 12, 1996 / Revised, accepted: March 21, 1997  相似文献   

Nouvelles données pour l’histoire des fluctuations holocènes du niveau du lac de Neuchatel (Suisse): la séquence sédimentaire de Marin-Les Piécettes     

Michel Magny  Matthieu Honegger et Laurent Chalumeau 《Eclogae Geologicae Helvetiae》2005,98(2):249-259

Resume. Les fouilles archéologiques réalisées de 1998 à 2002 sur le site néolithique de Marin-Les Piécettes sur la rive nord-ouest du lac de Neuchatel ont offert l’opportunité d’observer deux séquences sédimentaires intéressantes pour la reconstitution des variations holocènes du niveau du lac, en particulier au cours de la période correspondant au changement de cours de l’Aar en direction du nord-est, vers 5650–5500 cal BP. La géométrie des corps sédimentaires et les changements lithologiques permettent de reconna?tre plusieurs phases majeures de bas niveaux relatifs du plan d’eau vers 6870, 5660, 5060–3990, 3580, 2280, 1640 et 1170 cal BP. Le site néolithique de Marin-Les Piécettes s’est développé vers 5454–5433 cal BP à la faveur d’un court épisode de bas niveau du lac qui a interrompu une importante phase de haut niveau au début du Subboréal. Les événements paléohydrologiques identifiés à Marin-Les Piécettes apparaissent cohérents avec ceux reconstitués sur le site de Montilier au bord du lac de Morat, ainsi qu’avec les variations paléohydrologiques reconstituées à partir des lacs du Jura, du Plateau suisse et des Préalpes du Nord fran?aises. Ceci suggère qu’ils témoignent d’un signal climatique. La séquence sédimentaire de Marin-Les Piécettes met enfin en évidence la formation d’un cordon littoral sur la rive nord-ouest du lac juste après 5660 cal BP. Manuscrit re?u le 22 septembre 2004 Révision acceptée le 11 mars 2005  相似文献   

Hydrogen isotopic composition of water from fossil micrometeorites in howardites     

Matthieu Gounelle  Cécile Engrand  Philip A. Bland  Michael E. Zolensky  Jean Duprat 《Geochimica et cosmochimica acta》2005,69(13):3431-3443

We have measured the hydrogen isotopic composition (D/H ratios) of the water from 13 carbonaceous chondritic microclasts (CCMs, size <1 mm) trapped in two howardites (Kapoeta and Yamato-793497) early in the evolution of Solar System. The division into tochilinite-rich; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich CCM types is corroborated by the hydrogen isotopic compositions. Both mineralogy and hydrogen isotopic compositions demonstrate that tochilinite-rich CCMs represent CM2 chondritic matter. In contrast, there is no good match between the isotopic and mineralogical properties of the magnetite-rich CCMs and the known groups of carbonaceous chondrites, suggesting that magnetite-rich CCMs represent a new kind of chondritic matter, not yet sampled in meteorite collections. This demonstrates that the view of the asteroid belt revealed by the collection of meteorites is incomplete. The study of (micro)clasts offers a unique opportunity to better decipher the nature and relative abundance of asteroids.The average hydrogen isotopic composition of water belonging to CCMs, D/H = (152.0 ± 4.8) × 10⁻⁶ (1σ_m), is similar to that of Antarctic micrometeorites (AMMs), D/H = (161.2 ± 3.8) × 10⁻⁶ (1σ_m). The similarity, in terms of mineralogy and hydrogen isotopic composition, between CCMs and AMMs demonstrates that the composition of the micrometeorites has not been modified over the whole history of the Solar System. It indicates that the composition of the micrometeorite flux onto Earth has been, and is, dominated by a mixture of CM2-like; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich carbonaceous chondritic matter exemplified by CCMs found in howardites. Because CCMs have not suffered atmospheric entry, they provide an abundant source of pristine micrometeorites.The average D/H ratio of the whole population of CCMs is identical within errors to that of the Earth (149 ± 3 × 10⁻⁶). The match between the CCMs D/H ratio and that of the Earth is especially remarkable because 1) three different populations of CCMs are needed to make the D/H ratio of the Earth; 2) there is no single carbonaceous chondrite group for which a similar match exists. This observation suggests that CCMs population might be representative of the late veneer agent(s) that delivered water to the Earth.  相似文献   

Environmental changes over the past 25 000 years in the southern Middle Atlas,Morocco          下载免费PDF全文

Jalal Tabel  Carla Khater  Ali Rhoujjati  Laurent Dezileau  Ilham Bouimetarhan  Matthieu Carre  Laurence Vidal  Abdelfattah Benkaddour  Majda Nourelbait  Rachid Cheddadi 《第四纪科学杂志》2016,31(2):93-102

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Elastoplastic model with loading memory surfaces (LMS) for monotonic and cyclic behaviour of geomaterials     

Hervé di Benedetto  Matthieu Blanc  Samir Tiouajni  Alan Ezaoui 《国际地质力学数值与分析法杂志》2014,38(14):1477-1502

A new elastoplastic model called loading memory surface based on the critical state concept and the multi‐surface framework is proposed for geomaterials. The model uses a hypoelastic formulation and two plastic mechanisms. The formulations of the model are made in three‐dimensional stress–strain space and work under both monotonic and cyclic loadings. A newly introduced formalism makes it possible to obtain the cyclic response directly from the monotonic loading one. This formalism gives a three‐dimensional generalization of the well‐known Masing rule. The model has been validated against test results of Hostun sand under several conditions: monotonic and cyclic, drained and undrained, tests in compression and in extension, and at different confining pressures and different densities. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献