Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction     

Megan FULLER  Yongsong HUANG 《Meteoritics & planetary science》2003,38(3):357-363

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.  相似文献   

Demographic transition in Sri Lanka: a spatial perspective   总被引：1，自引：0，他引：1  

Fuller GA 《Population geography : a journal of the Association of Population Geographers of India》1984,6(1-2):1-11

Demographic transition theory involves a lagging fertility transition induced by a leading mortality transition. This article focuses on the linkage between the mortality and fertility transitions in Sri Lanka; it discusses the measurement of areal fertility, demonstrates the use of a measure not commonly used in population geography, and shows areal association between past mortality and recent fertility. The Coale or Princeton fertility indices allow a reasonably good view of structural and behavioral aspects of fertility; the Coale indices examine the contribution of structure to total fertility and the contribution of marital fertility. Although recent fertility decline has been less rapid than the post-war mortality decline, Sri Lanka's crude birth rate in 1975 was the 5th lowest in Asia. Sri Lanka experienced very high crude death rates in 1930, and quite low rates in 1950 and in subsequent years. This demonstrates an association between historic mortality and recent fertility, and that association can be linked deductively to demographic transition theory. In 1930, malaria was endemic throughout the Dry Zone of Sri Lanka, and hyperendemic in several districts. The Spearman rank correlation coefficients reveal the strongest relationship between malaria and nuptiality; this lends evidence to the notion that structural influences on fertility--such as delayed marriage--are more important than influences on marital fertility--such as coital frequency. The evidence suggests that mortalily decline in Sri Lanka led to an increase in fertility in those areas where malaria had been concentrated. This suggests the possibility that measures constituting malaria control or eradication also stimulate increased fertility; therefore, anti-malarial programs must be integrated with family planning.  相似文献   

Determination of food web support and trophic position of the mummichog,Fundulus heteroclitus, in New Jersey smooth cordgrass (Spartina alterniflora), common reed (Phragmites australis), and restored salt marshes     

C. A. Currin  S. C. Wainright  K. W. Able  M. P. Weinstein  C. M. Fuller 《Estuaries and Coasts》2003,26(2):495-510

The invasion ofPhragmites australis into tidal marshes formerly dominated bySpartina alterniflora has resulted in considerable interest in the consequences of this invasion for the ecological functions of marsh habitat. We examined the provision of trophic support for a resident marsh fish,Fundulus heteroclitus, in marshes dominated byP. australis, byS. alterniflora, and in restored marshes, using multiple stable isotope analysis. We first evaluated our ability to distinguish among potential primary producers using the multiple stable isotope approach. Within a tidal creek system we found significant marsh and elevation effects on microalgal isotope values, and sufficient variability and overlap in primary producer isotope values to create some difficulty in identifying unique end members. The food webs supportingF. heteroclitus production were examined using dual isotope plots. At both sites, the δ¹³C values ofF. heteroclitus were clustered over values for benthic microalgae (BMI) and approximately midway between δ¹³C values ofSpartina andPhragmites. Based on comparisons of fish and primary producer δ¹³C, δ¹⁵N, and δ³⁴S values, and consideration ofF. heteroclitus feeding habits, we conclude that BMI were a significant component of the food web supportingF. heteroclitus in these brackish marshes, especially recently-hatched fish occupying pools on the marsh surface. A 2‰ difference in δ¹³C betweenFundulus occupying nearly adjacentSpartina andPhragmites marshes may be indicative of relatively less reliance on BMI and greater reliance onPhragmites production inPhragmites-dominated marshes, a conclusion consistent with the reduced BMI biomass found inPhragmites marshes. The mean δ¹³C value ofF. heteroclitus from restored marshes was intermediate between values of fish from naturally occurringSpartina marshes and areas invaded byPhragmites. We also examined the isotopic evidence for ontogenetic changes in the trophic position of larval and juvenileF. heteroclitus. We found significant positive relationships betweenF. heteroclitus δ¹⁵N values and total length, reflective of an increase in trophic position as fish grow.F. heteroclitus δ¹⁵N values indicate that these fish are feeding approximately two trophic levels above primary producers.  相似文献   

Geochemistry of the Uintjiesberg kimberlite, South Africa: petrogenesis of an off-craton, group I, kimberlite   总被引：2，自引：0，他引：2  

Megan Harris  Anton le Roex  Cornelia Class 《Lithos》2004,74(3-4):149-165

The Uintjiesberg kimberlite diatreme occurs within the Proterozoic Namaqua–Natal Belt, South Africa, approximately 60 km to the southwest of the Kaapvaal craton boundary. It is a group I, calcite kimberlite that has an emplacement age of 100 Ma. Major and trace element data, in combination with petrography, are used to evaluate its petrogenesis and the nature of its source region. Macrocryst phases are predominantly olivine with lesser phlogopite, with very rare garnet and Cr-rich clinopyroxene. Geochemical variation amongst the macrocrystic samples (Mg# 0.85–0.87, SiO₂=27.0–29.3%, MgO=26.1–30.5%, CaO=10.9–13.5%) is shown to result from 10% to 40% entrainment and partial assimilation of peridotite xenoliths, whereas that shown by the aphanitic samples (Mg# 0.80–0.83, SiO₂=19.1–23.0%, MgO=17.9–23.9%, CaO=16.5–23.7%) is consistent with 7–25% crystal fractionation of olivine and minor phlogopite. Changing trajectories on chemical variation diagrams allow postulation of a primary magma composition with 25% SiO₂, 26% MgO, 2.3% Al₂O₃, 5%H₂O, 8.6% CO₂ and Mg#=0.85.

Forward melting models, assuming 0.5% melting, indicate derivation of the primary Uintjiesberg kimberlite magma from a source enriched in light rare earth elements (LREE) by 10× chondrite and heavy REE (HREE) by 0.8–2× chondrite, the latter being dependent on the proportion of residual garnet. Significant negative Rb, K, Sr, Hf and Ti anomalies present in the inferred primary magma composition are superimposed on otherwise generally smooth primitive mantle-normalized trace element patterns, and are inferred to be a characteristic of the primary magma composition. The further requirement for a source with chondritic or lower HREE abundances, residual olivine with high Fo content (Fo₉₄) suggests derivation from a mantle previously depleted in mafic melt but subsequently enriched in highly incompatible elements prior to kimberlite genesis. These requirements are interpreted in the context of melting of continental lithospheric mantle previously enriched by metasomatic fluids derived from a sublithospheric (plume?) source.  相似文献   

February floods in the lower North Island, 2004: Catastrophe – causes and consequences     

Ian C. Fuller 《New Zealand geographer》2005,61(1):40-50

Abstract: The February 2004 Manawatu floods in New Zealand were the result of a naturally occurring, although unusual, storm. Up to 300 mm of rain fell on the already saturated ground of the lower North Island over two days, generating substantial and rapid runoff from catchment slopes. Rivers rose quickly, inundating unprotected farmland and properties and in places breaching stopbanks. There was widespread slope failure in the hill country of the lower North Island, affecting an area of ca. 7500 km². Slopes under scrub, plantation forest and native bush were not as badly affected as those under pasture, where slopes typically failed by shallow translational landsliding. Flooding caused catastrophic channel change in a number of small to medium sized channel systems in the upland fringes. Whilst the occurrence of landsliding and channel changes during an extreme event such as this is natural, the intensity of both landsliding and channel erosion was exacerbated by human activity within the catchments.  相似文献   

The limits of crisis data: analytical and ethical challenges of using social and mobile data to understand disasters     

Kate Crawford  Megan Finn 《GeoJournal》2015,80(4):491-502

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Water resources sustainability in a globalizing world: who uses the water?          下载免费PDF全文

Megan Konar  Tom P. Evans  Morgan Levy  Christopher A. Scott  Tara J. Troy  Charles J. Vörösmarty  Murugesu Sivapalan 《水文研究》2016,30(18):3330-3336

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Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand          下载免费PDF全文

S. S. Vale  I. C. Fuller  J. N. Procter  L. R. Basher  I. E. Smith 《水文研究》2016,30(5):812-829

Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Diffusive fractionation of trace elements in basaltic melt     

Megan E. Holycross  E. Bruce Watson 《Contributions to Mineralogy and Petrology》2016,171(10):80

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Response of low‐angle dunes to variable flow          下载免费PDF全文

Megan L. Hendershot  Jeremy G. Venditti  Ryan W. Bradley  Ray A. Kostaschuk  Michael Church  Mead A. Allison 《Sedimentology》2016,63(3):743-760

Current understanding of bedform dynamics is largely based on field and laboratory observations of bedforms in steady flow environments. There are relatively few investigations of bedforms in flows dominated by unsteadiness associated with rapidly changing flows or tides. As a consequence, the ability to predict bedform response to variable flow is rudimentary. Using high‐resolution multibeam bathymetric data, this study explores the dynamics of a dune field developed by tidally modulated, fluvially dominated flow in the Fraser River Estuary, British Columbia, Canada. The dunes were dominantly low lee angle features characteristic of large, deep river channels. Data were collected over a field ca 1·0 km long and 0·5 km wide through a complete diurnal tidal cycle during the rising limb of the hydrograph immediately prior to peak freshet, yielding the most comprehensive characterization of low‐angle dunes ever reported. The data show that bedform height and lee angle slope respond to variable flow by declining as the tide ebbs, then increasing as the tide rises and the flow velocities decrease. Bedform lengths do not appear to respond to the changes in velocity caused by the tides. Changes in the bedform height and lee angle have a counterclockwise hysteresis with mean flow velocity, indicating that changes in the bedform geometry lag changes in the flow. The data reveal that lee angle slope responds directly to suspended sediment concentration, supporting previous speculation that low‐angle dune morphology is maintained by erosion of the dune stoss and crest at high flow, and deposition of that material in the dune trough.  相似文献