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1.
Semi-continuous (1/30 min) records of physicochemical parameters (T,S, DO and pH) have been measured at 1.50 m in Mediterranean coastal waters (Marseilles) from 1998 to 2000, together with meteorological parameters. Physicochemical data were studied in order to synthesise the information at different time scales (inter-annual, season, day, hour), particularly the semi-conservative DO and pH response to hydroclimatic variables. At a daily time scale, important circadian dynamic has been measured under all circumstances with a strong reactivity to irradiance change under the influence of biological activity. This work may contribute to the definition of new tools for coastal waters observation. To cite this article: N. Bensoussan et al., C. R. Geoscience 336 (2004).  相似文献   
2.
We describe the tectono‐sedimentary evolution of a Middle Jurassic, rift‐related supra‐detachment basin of the ancient Alpine Tethys margin exposed in the Central Alps (SE Switzerland). Based on pre‐Alpine restoration, we demonstrate that the rift basin developed over a detachment system that is traced over more than 40 km from thinned continental crust to exhumed mantle. The detachment faults are overlain by extensional allochthons consisting of upper crustal rocks and pre‐rift sediments up to several kilometres long and several hundreds of metres thick, compartmentalizing the distal margin into sub‐basins. We mapped and restored one of these sub‐basins, the Samedan Basin. It consists of a V‐shape geometry in map view, which is confined by extensional allochthons and floored by a detachment fault. It can be restored over a minimum distance of 11 km along and about 4 km perpendicular to the basin axis. Its sedimentary infill can be subdivided into basal (initial), intermediate (widening) and top (post‐tectonic) facies tracts. These tracts document (1) formation of the basin initially bounded by high‐angle faults and developing into low‐angle detachment faults, (2) widening of the basin and (3) migration of deformation further outboard. The basal facies tract is made of locally derived, poorly sorted gravity flow deposits that show a progressive change from hangingwall to footwall‐derived lithologies. Upsection the sediments develop into turbidity current deposits that show retrogradation (intermediate facies tract) and starvation of the sedimentary system (post‐tectonic facies tract). On the scale of the distal margin, the syn‐tectonic record documents a thinning‐ and fining‐upward sequence related to the back stepping of the tectonically derived sediment source, progressive starvation of the sedimentary system and migration of deformation resulting in exhumation and progressive delamination of the thinned crust during final rifting. This study provides valuable insights into the tectono‐sedimentary evolution and stratigraphic architecture of a supra‐detachment basin formed over hyper‐extended crust.  相似文献   
3.
In this study, we examined hyporheic annelid assemblages along a gradient of flow permanence (FP) and compared assemblages in gaining (groundwater-fed) and losing (runoff-fed) sections of the alluvial Selwyn River, New Zealand. To reduce the effects of poor taxonomic resolution, we used a dataset with most taxa identified to the genus or species level. We predicted that annelid assemblages would vary in structure and composition along FP gradients due to differences in desiccation resistance between taxa. We also predicted that groundwater-fed (gaining) and runoff-fed (losing) river sections would be inhabitated by dissimilar annelid assemblages due to differences in river-aquifer connections and recolonization sources. We found a negative relationship between taxon richness and FP, indicating that, on average, two annelid taxa are lost from hyporheic assemblages in the Selwyn River with every 10% decrease in FP. Low FP appears to favour annelid taxa that tolerate moist or dry conditions in sediments, as shown by a negative relationship between FP and the proportion of desiccation-tolerant taxa. A high proportion of hypogean taxa distinguished the groundwater-fed and perennial-gaining reach from the other reaches. In spite of the large differences in physical structure between the intermittent-gaining and the ephemeral-losing reach, we found few between-reach differences in annelid assemblages and, in particular, no differences in % hypogean taxa. These varied results illustrate the need to employ both categorical and continuous variables in ecological analyses: the combined categorical and gradient approach used in the present study is likely to explain more variability than either univariate approach alone.  相似文献   
4.
This study is devoted to the physicochemical and mineralogical characterizations of palygorskite from Marrakech High Atlas, Morocco. The raw clay and its Na+-saturated <2 μm fraction were characterized using chemical, structural, and thermal analytical techniques. Measurements of specific surface area and porous volume are reported. The clay fraction was found to be made up of 95 % of palygorskite and 5 % of sepiolite. An original feature of this palygorskite is its deficiency in zeolitic H2O. The half-cell structural formula of its dehydrated form was determined on the basis of 21 oxygens to be (Si7.92Al0.08)(Mg2.15Al1.4Fe0.4Ti0.05 $ \square_{1} $ )(Ca0.03Na0.08K0.04)O21, while the hydrated form could be formulated as (Si7.97Al0.03)(Mg2.17Al1.46Fe0.40Ti0.05)(Ca0.03Na0.07K0,03)O20.18(OH)1.94(OH2)3.88·2.43 H2O. These formulas show that the (Al3++Fe3+)/Mg2+ ratio is around 0.84, revealing a pronounced dioctahedral character. Further, inside its octahedral sheet, it was determined that the inner M1 sites are occupied by vacancies, whereas the M2 sites are shared between 90 % of trivalent cations (78 % for Al3+ and 22 % for Fe3+), 7.5 % of Mg2+, and 2.5 % of Ti4+, all of them linked to 1.94 of structural hydroxyls. The two remaining Mg2+ by half-cell occupy edge M3 sites and are coordinated to 3.88 molecules of OH2. Channels of this palygorskite are deficient in zeolitic H2O since they contain only 2.43 H2O molecules. A correlation was found between these results and the observation of very intense and well-resolved FTIR bands arising from dioctahedral domains (mainly Al2OH, Fe2OH, and AlFeOH) along with very small responses from a trioctahedral domain (Mg3OH). Accordingly, a schematic representation of the composition of the octahedral sheet was proposed. The cation exchange capacity, specific surface area, and total pore volume were also assessed to be ca. 21.2 meq/100 g, 116 m2/g, and 0.458 cm3/g, respectively.  相似文献   
5.
On the rocky coasts of the northwestern Mediterranean basin, biogenic littoral rims built by the coralline rhodophyte Lithophyllum lichenoides develop, whose remains may be preserved for millennia when submerged in a rising sea environment. These remains can be used as biological indicators of recent sea-level variations. Our survey of the continental coasts of Var and Bouches du Rhône, west of Marseilles (southern France) and of northern Corsica shows that relative sea level rose about 1.6 m in the study area during the last 4500 years without exceeding the present datum. The rate of sea-level rise was 0.4 mm per year between 4500 and 1500 yr B.P. and slowed down to 0.2 mm per year from 1500 yr B.P. to present time. There are also morphological indications of an acceleration of the rate of sea-level rise during the last century, supporting the evidence of tide gauges. Regions at the periphery of the above zone (Alpes Maritimes, Italian border zone, and the French and Spanish Catalonia regions) were also surveyed, but a weaker development of Lithophyllum rims and bad preservation of algal remains led to unconvincing dates which could also be linked to regional tectonic trends.  相似文献   
6.
The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (<1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO3 solutions. Total Hg(II) concentrations ranged from 6.2 × 10?8 to 6.3 × 10?3 M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10?8 to 1.1 × 10?4 M, and (b) 6.4 × 10?4 to 6.3 × 10?3 M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH)2 was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH)2 in the interlayer of the interstratified clay minerals can be proposed. Hg(OH)2 was partially desorbed by repeated equilibrations in 0.1 M NaNO3 solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10?5 M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10?3 M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH)2 was retained by adsorption on clay mineral surfaces.  相似文献   
7.
This paper presents a fuzzy approach for the MAritime RISk Assessment (MARISA) applied to safety at sea. The aim of this work is to define automatically an individual ship risk factor which could be used in a decision making system. To achieve this purpose, a modular and hierarchical structure using fuzzy logic has been developed. It allows us to obtain a fuzzy risk factor (FRF) composed of a static risk factor (SRF) and a dynamic risk factor (DRF). The static risk factor assessment takes into account several static data relative to the ship (age, flag, gross tonnage, number of companies, duration of detention and type). The dynamic risk factor is evaluated by considering the meteorological conditions (sea state, wind speed and visibility) and the moment of the day. Moreover, the MARISA graphic interface developed with the Labview software is presented. This interface allows several simulations to be carried out to validate the fuzzy method proposed. Simulation results are presented.  相似文献   
8.
In this study, we propose a fuzzy approach in order to evaluate the maritime risk assessment applied to safety at sea and more particularly, the pollution prevention on the open sea. The work is based on the decision-making system, named MARISA, presented in Balmat et al. (2009). This system allowed defining a risk factor for each ship according to ship’s characteristics and weather conditions. In this novel paper, the proposed system takes into account the ship speed evolution and the ship position with respect to maritime shipping lanes is developed. To validate the method, we present an example of results with real data.  相似文献   
9.
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10.
Using synthetic geometrical clouds and radiative microwave model, we examine the possibility to correct the estimations of liquid water path (LWP) or rain rate with cloud cover measurement. This information may be gotten by co-localized measurements of microwave and infrared/visible measurements on new satellites (TRMM, ADEOS 2, …). In a first step, the effects of fractional cloud cover on microwave brightness temperatures (TB) are investigated in three typical cases of nonprecipitating and precipitating (stratiform and convective) clouds. The beam-filling error (BFE) on brightness temperatures may be analyzed with the known spatial variability using 1D or 3D radiative transfer model. Relationships between BFE and subpixel cloud fraction (CF) are discussed according to the cloud type. We tested several parameters that characterize the horizontal cloud inhomogeneity within a radiometer field of view. BFE was found very sensitive to cloud type and inhomogeneity and is maximum for raining cloud with open spatial structure. In order to account for the uncertainty introduced by the spatial distribution, dependence of BFE on textural-based parameters is also discussed using homogeneity, entropy and an indicator of CF horizontal gradient.  相似文献   
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