Astrometric investigation with the Tautenburg Schmidt telescope     

W. R. Dick  S. Hirte  E. Schilbach  R. -D. Scholz 《Astrophysics and Space Science》1991,177(1-2):229-234

The observations and the plate reduction technique for the determination of positions and absolute proper motions which is used in Potsdam are described. Recent results have shown that an accuracy of about 0 _. 1 for positions and 0 _. ⁷ cent _. ^–1 for proper motions can be achieved both for bright (8^m–12^m) and faint (16^m–18^m) stars. Three astrometric programmes using the Tautenburg plates are presented.  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

Induction of vitellogenin in vivo and in vitro in the model teleost medaka (Oryzias latipes): comparison of gene expression and protein levels   总被引：5，自引：0，他引：5  

Scholz S  Kordes C  Hamann J  Gutzeit HO 《Marine environmental research》2004,57(3):235-244

Quantification of the egg yolk precursor vitellogenin (VTG) in fish has become a standard technique to detect estrogenic effects of known chemicals and environmental samples. In the present study, we have analysed VTG induction by estradiol, ethynylestradiol and genistein exposure in the model teleost medaka (Oryzias latipes) and demonstrate that the medaka is a suitable model system to analyse estrogenic effects. By comparing VTG gene expression and protein levels we show that in principal both techniques can be used to study VTG induction in vivo (juvenile and adult males) and in vitro (primary cultures of male liver cells). If a short term in vivo or in vitro exposure is performed, detection of mRNA might be sufficient. For long term studies with the need to detect weak estrogenic chemicals and a precise quantification, immuno-chemical detection may be favoured.  相似文献   

Investigation of the stable isotope fractionation in speleothems with laboratory experiments     

E. Wiedner  D. Scholz  A. Mangini  D. Polag  C. Mühlinghaus  M. Segl 《Quaternary International》2008,187(1):15

Many speleothems show evidence for calcite precipitation under disequilibrium conditions. To improve the understanding of these kinetic processes, several laboratory experiments were performed to study the fractionation of stable oxygen and carbon isotopes during the precipitation of calcite. Carbonate was precipitated under controlled conditions from both a body of standing water (beaker experiments) and a solution flowing along a channel (channel experiments) at a relative humidity of 100%. Slow degassing of CO₂, simulated by the beaker experiments, results in δ¹⁸O values in equilibrium with the solution. In contrast, the δ¹³C values show a significant enrichment, inversely proportional to the height of the solution in the beakers. Fast degassing of CO₂, simulated by the channel experiments, showed an enrichment of both δ¹³C and δ¹⁸O and a slope of Δδ¹³C/Δδ¹⁸O of 1.4±0.6. These results represent experimental evidence for the Hendy effect, which is manifested in (i) a progressive increase in δ¹⁸O and δ¹³C away from the growth axis and (ii) a positive correlation between δ¹⁸O and δ¹³C along a single growth layer of a stalagmite.  相似文献   

Micromechanics of the velocity and normal stress dependence of rock friction   总被引：1，自引：0，他引：1  

Weibin Wang  Christopher H. Scholz 《Pure and Applied Geophysics》1994,143(1-3):303-315

Among the second-order effects on friction the most important are those of variable normal stress and of slip velocity. Velocity weakening, which is usually considered the source of the stick-slip instability in rock friction, has been observed in velocity stepping experiments with Westerly granite. The friction change, , was –0.01 to –0.008 for a tenfold velocity increase. Using normal closure measurements, we observed dilation upon each increase in sliding rate. We also observed, for the first time, time-dependent closure between surfaces during static loading. The dilation that occurred during the velocity stepping experiment was found to be that expected from the static time-dependent closure phenomenon. This change in closure was used to predict friction change with an elastic contact model. The calculated friction change which results from a change in contact area and asperity interlocking, is in good agreement with the observed velocity dependence of steady-state friction. Variable normal stress during sliding has two effects, first in creating new partial slip contacts and locking some existing fully sliding contacts and second in increasing interlocking, for instance when normal load is suddenly increased. As a result, a transient change in friction occurs upon a sudden change in normal load.  相似文献   

Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions     

B. Meyer  F. Scholz 《Physics and Chemistry of Minerals》1997,24(1):50-52

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996  相似文献   

Regional and temporal changes in epizoobiontic bryozoan-communities of Flustra foliacea (Linnaeus, 1758) and implications for North Sea ecology     

F. Bitschofsky  S. Forster  J. Scholz 《Estuarine, Coastal and Shelf Science》2011,91(3):423-433

Until recently, bryozoans have not been used as indicators for changes in bottom communities or climate control in the North Sea Basin, despite a 200-year history of bryozoan collecting. The epizoobiontic bryozoan fauna of Flustra foliacea (Linnaeus, 1758) was analysed on 51 sample stations kept in four German museums. The samples cover the entire North Sea and different time periods (1776–2008, mainly the period of 1904/1905 compared to 1980–87). Cluster analysis shows a differentiation into a northern and a southern North Sea assemblage. The northern assemblage is characterized by Amphiblestrum flemingii (Busk, 1854), Callopora dumerilii (Audouin, 1826) and Tricellaria ternata (Ellis & Solander, 1786), while the southern North Sea is characterized by Electra pilosa (Linnaeus, 1767), Crisia eburnea (Linnaeus, 1758) and Plagioecia patina (Lamarck, 1816). Spatial separation approximately follows the 50 m depth contour. The temporal distribution patterns of bryozoans are discussed in terms of NAO (North Atlantic Oscillation) and temperature variations.  相似文献   

Impact of climate variability and streamflow alteration on groundwater contribution to the base flow of the Lower Zab River (Iran and Iraq)     

Ruqayah Mohammed  Miklas Scholz 《Environmental Earth Sciences》2016,75(21):1392

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Mechanisms of seismic quiescences   总被引：7，自引：0，他引：7  

Christopher H. Scholz 《Pure and Applied Geophysics》1988,126(2-4):701-718

In the past decade there have been major advances in understanding the seismic cycle in terms of the recognition of characteristic patterns of seismicity over the entire tectonic loading cycle. The most distinctive types of patterns are seismic quiescences, of which three types can be recognized:post-seismic quiescence, which occurs in the region of the rupture zone of an earthquake and persists for a substantial fraction of the recurrence time following the earthquake,intermediate-term quiescences, which appear over a similar region and persist for several years prior to large plate-rupturing earthquakes, andshort-term quiescences, which are pronounced lulls in premonitory swarms that occur in the hypocentral region hours or days before an earthquake. Although the frequency with which intermediate-term and short-term quiescences precede earthquakes is not known, and the statistical significance of some of the former has been challenged, there is a need, if this phenomena is to be considered a possibly real precursor, to consider physical mechanisms that may be responsible for them.The characteristic features of these quiescences are reviewed, and possible mechanisms for their cause are discussed. Post-seismic quiescence can be readily explained by any simple model of the tectonic loading cycle as due to the regional effect of the stress-drop of the previous principal earthquake. The other types of quiescence require significant modification to any such simple model. Of the possibilities considered, only two seem viable in predicting the observed phenomena, dilatancy hardening and slip weakening. Intermediate-term quiescences typically occur over a region equal to or several times the size of the rupture zone of the later earthquake and exhibit a relationship between the quiescence duration and size of the earthquake: they thus involve regional hardening or stress relaxation and agree with the predictions of the dilatancy-diffusion theory. Short-term quiescences, on the other hand, are more likely explained by fault zone dilatancy hardening and/or slip weakening within a small nucleation zone. Because seismicity is a locally relaxing process, seismicity should follow a behaviour known in rock mechanics as the Kaiser effect, in which only a very slight increase in strength, due to dilatancy hardening or decrease in stress due to slip weakening, is required to cause quiescence. This is in contrast to other precursory phenomena predicted by dilatancy, which require large dilatant strains and complete dilatancy hardening.Lamont-Doherty Geological Observatory  相似文献   

Copper Uptake by Blue-Green Algae     

V. Lüderitz  F. Scholz 《洁净——土壤、空气、水》1989,17(5):537-542

Experiments to study the influence of biomass concentration and pH on copper uptake by blue-green algae were performed. Differential pulse anodic stripping voltammetry (DPASV) was used for copper analysis. The maximum copper uptake per unit of biomass depends only on copper concentration and not on biomass concentration. Hence the copper toxicity is independent of biomass over a wide range. A main factor influencing copper uptake is the pH. Whereas the copper uptake of Aphanizomenon gracile is rapid at pH = 8.2 we did not find a significant uptake at pH = 5.7. The copper uptake at the higher pH value is followed by a nearly complete release of this copper, accompanied by a fast shortening of trichomes. There was no significant copper uptake in Oscillatoria redekei at pH = 8.2, but at pH = 7.2 the uptake pattern of this species is similar to that of Aphanizomenon at pH = 8.2. The results suggest that the metal ion uptake mechanisms of different species have not the same pH optima.  相似文献