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Susanna Carbonin Gabriella Salviulol Rosalba Munno Mirella Desiderio A. Dal Negro 《Mineralogy and Petrology》1989,41(1):1-10
Summary The crystal structures of 20 natural diopsides have been refined. For some samples, microprobe analyses show a Si deficiency in the tetrahedron with no A1 present; this suggests that some Ti4+ may enter the tetrahedral site. Geometrical variations in these samples with respect to the others are discussed in the light of this Si Ti4+ substitution. The volumes of their M1 sites are larger because of the absence of R3+ cations, the octahedron being very regular; in the same way, the volumes of M2 sites of these samples are greater not because of different site occupancies but because of significant charge modifications around the O3 and O1 oxygens, caused by the tetrahedral site. The low distortion of M1 site and the lengthening of (M2-O1) and M2-O3 bond lengths are a clue to the presence of small amounts of Ti at the tetrahedral site.
Kristallchemische untersuchung natürlicher diopside: Geometrische hinweise für tetraedrische Si-Ti substitution
Zusammenfassung Die Kristallstrukturen von zwanzig natürlichen Diopsiden sind verfeinert worden. In einigen Proben zeigen Mikrosondenanalysen zu geringe Si-Werte im Tetraeder ohne daß A1 anwesend wäre. Dies weist darauf hin, daß Ti4+ Tetraederplätze einnehmen könnte. Geometrische Variationen in diesen Proben werden im Lichte der genannten Substitution diskutiert. Die Volumen von M1-Plätzen sind größer wegen der Abwesenheit von R3+ Kationen, wobei das Oktaeder sehr gleichmäßig ist. Die Volumina von M2-Plätzen sind noch größer nicht wegen verschiedener Besetzungen dieser Plätze sondern wegen signifikanter Ladungsmodifikationen im Bereich von O3 und O1 Sauerstoffen, die durch die tetraedrische Position bewirkt wird. Die geringe Distortion der M1-Plätze und die Verlängerung der (M2-O1) und (M2-O3) Abstände weisen auf die Anwesenheit von geringen Titangehalten auf Tetraederplätzen hin.相似文献
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George Contopoulos Mirella Harsoula Georgios Lukes-Gerakopoulos 《Celestial Mechanics and Dynamical Astronomy》2012,113(3):255-278
We study the periodic orbits and the escapes in two different dynamical systems, namely (1) a classical system of two coupled oscillators, and (2) the Manko-Novikov metric which is a perturbation of the Kerr metric (a general relativistic system). We find their simple periodic orbits, their characteristics and their stability. Then we find their ordered and chaotic domains. As the energy goes beyond the escape energy, most chaotic orbits escape. In the first case we consider escapes to infinity, while in the second case we emphasize escapes to the central ??bumpy?? black hole. When the energy reaches its escape value, a particular family of periodic orbits reaches an infinite period and then the family disappears (the orbit escapes). As this family approaches termination it undergoes an infinity of equal period and double period bifurcations at transitions from stability to instability and vice versa. The bifurcating families continue to exist beyond the escape energy. We study the forms of the phase space for various energies, and the statistics of the chaotic and escaping orbits. The proportion of these orbits increases abruptly as the energy goes beyond the escape energy. 相似文献
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Matthew B. Alkire Kelly K. Falkner James Morison Robert W. Collier Christopher K. Guay Russell A. Desiderio Ignatius G. Rigor Miles McPhee 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(11):1432-1443
Here we report the first optical, sensor-based profiles of nitrate from the central Makarov and Amundsen and southern Canada Basins of the Arctic Ocean. These profiles were obtained as part of the International Polar Year program during spring 2007 and 2008 field seasons of the North Pole Environmental Observatory (NPEO) and Beaufort Gyre Exploration Program (BGEP). These nitrate data were combined with in-situ, sensor-based profiles of dissolved oxygen to derive the first high-resolution vertical NO profiles to be reported for the Arctic Ocean. The focus of this paper is on the halocline layer that insulates sea ice from Atlantic water heat and is an important source of nutrients for marine ecosystems within and downstream of the Arctic. Previous reports based on bottle data have identified a distinct lower halocline layer associated with an NO minimum at about S=34.2 that was proposed to be formed initially in the Nansen Basin and then advected downstream. Greater resolution afforded by our data reveal an even more pronounced NO minimum within the upper, cold halocline of the Makarov Basin. Thus a distinct lower salinity source ventilated the Makarov and not the Amundsen Basin. In addition, a larger Eurasian River water influence overlies this halocline source in the Makarov. Observations in the southern Canada Basin corroborate previous studies confirming multiple lower halocline influences including diapycnal mixing between Pacific winter waters and Atlantic-derived lower halocline waters, ventilation via brine formation induced in persistent openings in the ice, and cold, O2-rich lower halocline waters originating in the Eurasian Basin. These findings demonstrate that continuous sensing of chemical properties promises to significantly advance understanding of the maintenance and circulation of the halocline. 相似文献
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Peña-Icart M Villanueva Tagle ME Alonso-Hernández C Rodríguez Hernández J Behar M Pomares Alfonso MS 《Marine environmental research》2011,72(1-2):60-66
Knowing the metal extraction capacity of a digestion method is crucial for a better environmental interpretation of metal concentrations determined in sediments. One of the main problems at the present is the lack of harmonization of information obtained by two of the most popular sediment partial digestion methods: ISO 11466.3 (aqua regia) and EPA 3050B (HNO?--H?O?--HCl). In the present work, the amount of Cu, Ni and Pb leached by using both methods was compared with the total content of those elements in marine sediments collected, as an example, from the Cienfuegos Bay, Cuba. Similar amounts of Cu were extracted by both methods; while leaching of Ni and Pb were different. Generally, the EPA method extracted more Ni than the ISO method. In contrast, Pb was extracted in a larger amount by the ISO method. Some explanations are given for the observed results. X-ray Diffraction, X-ray Fluorescence, Particle Induced X-ray Emission Spectrometry and Energy Dispersive X-ray coupled to Scanning Electron Microscopy were employed for this purpose. On the other hand, none of the methods studied extracted simultaneously the fraction of all the metals, probably provided by human activity (Theoretical Anthropogenic Fraction) in both sediments studied. The use of ISO 11466.3 or EPA 3050B is recommended since the analytical performance parameters of both, in combination with Flame Atomic Absorption Spectrometry, are adequate. For a better environmental interpretation of the analytical results, information on the extraction efficiency of the selected method for specific elements and sediments under study should also be provided, together with the determined concentrations. 相似文献
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Reef islands are morphologically dynamic features located on atolls and platform reefs that are very sensitive to wave‐induced processes on different timescales. The planform morphological evolution of reef islands is widely described; however, the mechanisms of the volumetric variations in response to wave energy are still poorly documented. To assess their multitemporal vertical and horizontal mobility, we performed a series of synchronous measurements of the volumetric changes and incident wave energies at two reef islands and a shingle bank at the Rocas Atoll in the South Atlantic Ocean. The results show the differences in the magnitudes and locations of the sediment mobility between the reef islands. Whereas one island remained stable on all timescales, with only small volumetric changes concentrated at its extremities, the other island (Farol Island) showed high mobility, especially during the energetic northern swell season. The gross volumetric change reached 10.03 × 103 m3 (5% of the total island volume) on a daily timescale; however, on a seasonal scale, the gross erosion was compensated by the gross accretion, indicating a cyclical seasonal pattern. Moreover, the observed volumetric changes induced by the waves on both daily and seasonal timescales did not result in large shoreline displacements. However, long‐term oceanward erosion and substantial lagoonward accretion were observed at Farol Island on a decadal scale, resulting in a pronounced change in its planform morphology. This appears to be promoted by at least three sediment transport pathways induced by waves at the atoll, including sediment adjustment between the reef islands. Our results show that reef islands on the same atoll can have very distinct morphological behaviors on daily, seasonal and decadal scales in response to the same boundary conditions. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
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