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1.
Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K2O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H2O, K2O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H2O and K2O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K2O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.  相似文献   
2.
Anatexis of metapelitic rocks at the Bandelierkop Quarry (BQ) locality in the Southern Marginal Zone of the Limpopo Belt occurred via muscovite and biotite breakdown reactions which, in order of increasing temperature, can be modelled as: (1) Muscovite + quartz + plagioclase = sillimanite + melt; (2) Biotite + sillimanite + quartz + plagioclase = garnet + melt; (3) Biotite + quartz + plagioclase = orthopyroxene ± cordierite ± garnet + melt. Reactions 1 and 2 produced stromatic leucosomes, which underwent solid‐state deformation before the formation of undeformed nebulitic leucosomes by reaction 3. The zircon U–Pb ages for both leucosomes are within error identical. Thus, the melt or magma formed by the first two reactions segregated and formed mechanically solid stromatic veins whilst temperature was increasing. As might be predicted from the deformational history and sequence of melting reactions, the compositions of the stromatic leucosomes depart markedly from those of melts from metapelitic sources. Despite having similar Si contents to melts, the leucosomes are strongly K‐depleted, have Ca:Na ratios similar to the residua from which their magmas segregated and are characterized by a strong positive Eu anomaly, whilst the associated residua has no pronounced Eu anomaly. In addition, within the leucosomes and their wall rocks, peritectic garnet and orthopyroxene are very well preserved. This collective evidence suggests that melt loss from the stromatic leucosome structures whilst the rocks were still undergoing heating is the dominant process that shaped the chemistry of these leucosomes and produced solid leucosomes. Two alternative scenarios are evaluated as generalized petrogenetic models for producing Si‐rich, yet markedly K‐depleted and Ca‐enriched leucosomes from metapelitic sources. The first process involves the mechanical concentration of entrained peritectic plagioclase and garnet in the leucosomes. In this scenario, the volume of quartz in the leucosome must reflect the remaining melt fraction with resultant positive correlation between Si and K in the leucosomes. No such correlation exists in the BQ leucosomes and in similar leucosomes from elsewhere. Consequently, we suggest disequilibrium congruent melting of plagioclase in the source and consequential crystallization of peritectic plagioclase in the melt transfer and accumulation structures rather than at the sites of biotite melting. This induces co‐precipitation of quartz in the structures by increasing SiO2 content of the melt. This process is characterized by an absence of plagioclase‐induced fractionation of Eu on melting, and the formation of Eu‐enriched, quartz + plagioclase + garnet leucosomes. From these findings, we argue that melt leaves the source rapidly and that the leucosomes form incrementally as melt or magma leaving the source dumps its disequilibrium Ca load, as well as quartz and entrained ferromagnesian peritectic minerals, in sites of magma accumulation and escape. This is consistent with evidence from S‐type granites suggesting rapid magma transfer from source to high level plutons. These findings also suggest that leucosomes of this type should be regarded as constituting part of the residuum from partial melting.  相似文献   
3.
Within individual plutons, the trace element concentrations in S-type granites generally increase with maficity (total iron and magnesium content and expressed as atomic Fe + Mg in this study); the degree of variability in trace element concentration also expands markedly with the same parameter. The strongly peraluminous, high-level S-type granites of the Peninsular Pluton (Cape Granite Suite, South Africa) are the product of biotite incongruent melting of a metasedimentary source near the base of the crust. Leucogranites within the suite represent close to pure melts from the anatectic source and more mafic varieties represent mixtures of melt and peritectic garnet and ilmenite. Trace elements such as Rb, Ba, Sr and Eu, that are concentrated in reactant minerals in the melting process, show considerable scatter within the granites. This is interpreted to reflect compositional variation in the source. In contrast, elements such as LREE, Zr and Hf, which are concentrated within refractory accessory phases (zircon and monazite), show well-defined negative correlations with increasing SiO2 and increase linearly with increasing maficity. This is interpreted to reflect coupled co-entrainment of accessory minerals and peritectic phases to the melt: leucocratic rocks cannot have evolved from the more mafic compositions in the suite by a process of fractional crystallisation because in this case they would have inherited the zircon-saturated character of this hypothetical earlier magma. Trace element behaviour of granites from the Peninsular Pluton has been modelled via both equilibrium and disequilibrium trace element melting. In the disequilibrium case, melts are modelled as leaving the source with variable proportions of entrained peritectic phases and accessory minerals, but before the melt has dissolved any accessory minerals. Thus, the trace element signature of the melt is largely inherited from the reactants in the melting reaction, with no contribution from zircon and monazite dissolution. In the equilibrium case, melt leaves the source with entrained crystals, after reaching zircon and monazite saturation. A significant proportion of the rocks of the Peninsular Pluton have trace element concentrations below those predicted by zircon and monazite saturation. In the case of the most leucocratic rocks all compositions are zircon undersaturated; whilst the majority of the most mafic compositions are zircon oversaturated. However, in both cases, zircon is commonly xenocrystic. Thus, the leucocratic rocks represent close to pure melts, which escaped their sources rapidly enough that some very closely match the trace element disequilibrium melting model applied in this study. Zircon dissolution rates allow the residency time for the melt in the source to be conservatively estimated at less than 500 years.  相似文献   
4.
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5.
International Journal of Earth Sciences - The late stages of the Variscan orogeny are characterized by middle to lower crustal melting and intrusion of voluminous granitoids throughout the belt,...  相似文献   
6.
The metamorphic history of the Southern Marginal Zone (SMZ) of the Limpopo Belt, South Africa, possibly provides insight into one of the oldest preserved continental collision zones. The SMZ consists of granitoid gneisses (the Baviaanskloof Gneiss) and subordinate, infolded metasedimentary, metamafic and meta‐ultramafic lithologies (the Bandelierkop Formation) and is regarded as the c. 2700 Ma granulite facies reworked equivalent of the Kaapvaal craton basement. The granulite facies metamorphism is proposed to have occurred in response to collision between the Kaapvaal and Zimbabwe cratons. Previous studies have proposed a wide variety of P–T loops for the granulites, with considerable discrepancy in both the shapes of the retrograde paths and the magnitude of the peak P–T conditions. To date, the form of the prograde path and the timing of the onset of metamorphism remain unknown. This study has used a range of different metasedimentary rocks from a large migmatitic quarry outcrop to better constrain the metamorphic history and the timing of metamorphism in the SMZ. Detrital zircon ages reveal that the protoliths to the metasedimentary rocks were deposited subsequent to 2733 ± 13 Ma. Peak metamorphic conditions of 852.5 ± 7.5 °C and 11.1 ± 1.3 kbar were attained at 2713 ± 8 Ma. The clockwise P–T path is characterized by heating in the sillimanite field along a P–T trajectory which approximately parallels the kyanite to sillimanite transition, followed by near‐isothermal decompression at peak temperature and near‐isobaric cooling at ~6.0 kbar. These results support several important conclusions. First, the sedimentary rocks from the Bandelierkop Formation are not the equivalent of any of the greenstone belt sedimentary successions on the Kaapvaal craton, as has been previously proposed. Rather, they post‐date the formation of the Dominion and Witwatersrand successions on the Kaapvaal craton. From the age distribution of detrital zircon, they appear to have received significant input from various origins. Consequently, at c. 2730 Ma, the Baviaanskloof Gneiss most likely acted as basement onto which the sedimentary succession represented by the Bandelierkop Formation metapelites was deposited. Second, the rocks of the SMZ underwent rapid evolution from sediment to granulite facies anatexis, with a burial rate of ~0.17 cm yr?1. Peak metamorphism was followed by an isothermal decompression to 787.5 ± 32.5 °C and 6.7 ± 0.5 kbar and isobaric cooling to amphibolite facies conditions, below 640 °C prior to 2680 ± 6 Ma. This age for the end of the high‐grade metamorphic event is marked by the intrusion of crosscutting, undeformed pegmatites that are within error the same age as the crosscutting Matok intrusion (2686 ± 7 Ma). Collectively, the burial rate of the sedimentary rocks, the shape of the P–T path, the burial of the rocks to in excess of 30 km depth and the post‐peak metamorphic rapid decompression argue strongly that the SMZ contains sediments deposited along an active margin during lateral convergence, and that the SMZ was metamorphosed as a consequence of continental collision along the northern margin of the Kaapvaal craton at c. 2700 Ma.  相似文献   
7.
Earth's continental crust is stabilized by crustal differentiation that is driven by partial melting and melt loss: Magmas segregate from their residuum and migrate into the upper crust, leaving the deep crust refractory. Thus, compositional change is an integral part of the metamorphic evolution of anatectic granulites. Current thermodynamic modelling techniques have limited abilities to handle changing bulk composition. New software is developed (Rcrust) that via a path‐dependent iteration approach enables pressure, temperature and bulk composition to act as simultaneous variables. Path‐dependence allows phase additions or extractions that will alter the effective bulk composition of the system. This new methodology leads to a host of additional investigative tools. Singular paths within pressure–temperature–bulk composition (P–T–X) space give details of changing phase proportions and compositions during the anatectic process, while compilations of paths create path‐dependent P–T mode diagrams. A case study is used to investigate the effects of melt loss in an open system for a pelite starting bulk composition. The study is expanded upon by considering multiple P–T paths and considering the effects of a lower melt threshold. It is found that, for the pelite starting composition under investigation, open systems produce less melt than closed systems, and that melt loss prior to decompression drastically reduces the ability of the system to form melt upon decompression.  相似文献   
8.
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