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Vinícius dos SANTOS Peter MARSHALL FLEMING Luís HENRIQUE MANCINI Stela DALVA SANTOS COTA Graziele Beatriz de LIMA Rafaela RODRIGUES GOMES Roberto Eduardo KIRCHHEIM Ricardo SANCHéZ-MURILLO Didier GASTMANS 《大气科学进展》2022,39(10):1693-1708
Precipitation isotope ratios (O and H) record the history of water phase transitions and fractionation processes during moisture transport and rainfall formation. Here, we evaluated the isotopic composition of precipitation over the central-southeastern region of Brazil at different timescales. Monthly isotopic compositions were associated with classical effects (rainfall amount, seasonality, and continentality), demonstrating the importance of vapor recirculation processes and different regional atmospheric systems (South American Convergence Zone-SACZ and Cold Fronts-CF). While moisture recycling and regional atmospheric processes may also be observed on a daily timescale, classical effects such as the amount effect were not strongly correlated (δ18O-precipitation rate r ≤ –0.37). Daily variability revealed specific climatic features, such as δ18O depleted values (~ –6‰ to –8‰) during the wet season were associated with strong convective activity and large moisture availability. Daily isotopic analysis revealed the role of different moisture sources and transport effects. Isotope ratios combined with d-excess explain how atmospheric recirculation processes interact with convective activity during rainfall formation processes. Our findings provide a new understanding of rainfall sampling timescales and highlight the importance of water isotopes to decipher key hydrometeorological processes in a complex spatial and temporal context in central-southeastern Brazil. 相似文献
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NIALL FLEMING 《Geology Today》1993,9(6):223-225
Much effort has been expended in recent years on determining the factors influencing calcite cementation of sandstones, partly out of academic curiosity and partly because of the important influence these cements have on production from hydrocarbon reservoirs. Calcite cementation may occur pervasively throughout a sandstone sequence or be concentrated in certain horizons within which growth may be as concretions. We are only now beginning to understand the factors governing the growth and distribution of carbonate concretions in sandstones. 相似文献
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Abstract In regional metamorphic rocks, the partitioning of deformation into progressive shearing and progressive shortening components results in strain and strain-rate gradients across the boundaries between the partitioned zones. These generate dislocation density gradients and hence chemical potential gradients that drive dissolution and solution transfer. Phyllosilicates and graphite are well adapted to accommodating progressive shearing without necessarily building up large dislocation density gradients within a grain, because of their uniquely layered crystal structure. However, most silicates and oxides cannot accommodate strain transitions within grains without associated dislocation density gradients, and hence are susceptible to dissolution and solution transfer. As a consequence, zones of progressive shearing become zones of dissolution of most minerals, and of concentration of phyllosilicates and graphite. Exceptions are mylonites, where strain-rates are commonly high enough for plastic deformation to dominate over diffusion rates and therefore over dissolution and solution transfer. Porphyroblastic minerals cannot nucleate and grow in zones of active progressive shearing, as they would be dissolved by the effects of shearing strain on their boundaries. However, they can nucleate and grow in zones of progressive shortening and this is aided by the propensity for microfracturing in these zones, which allows rapid access of fluids carrying the material presumed to be necessary for nucleation and growth. Zones of progessive shortening also have a number of characteristics that help to lower the activation energy barrier for nucleation, this includes a build up of stored strain-energy relative to zones of progressive shearing, in which dissolution is occuring. Porphyroblast growth is generally syndeformational, and previously accepted criteria for static growth are not valid when the role of deformation partitioning is taken into account. Porphyroblasts in a contact aureole do not grow statically either, as microfracturing, associated with emplacement, allows access of fluids in a fashion that is similar to microfracturing in zones of progressive shortening. The criteria used for porphyroblast timing can be readily accommodated in terms of deformation partitioning, reactivation of deforming foliations, and a general lack of rotation of porphyroblasts, with the spectacular exception of genuinely spiralling garnet porphyroblasts. 相似文献
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SYNOPSIS The simulation of sediment transport processes in a watershed by means of a mathematical model on a digital computer, as developed by Negev (1) at Stanford University is considered, and the translation of this sediment model is presented in a commonly used, European computer programme language. 相似文献
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