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1.
Abstract— Clasts of alkaline (the second find in meteorites) and subalkaline rocks were found in the Kaidun meteorite. One of them (#d4A) is a large crystal of albite with inclusions of fluorapatite, arfvedsonite, aenigmatite, and wilkinsonite. The two latter minerals were previously unknown in meteorites. Another clast (#d[3–5]D) has a melt crystallization texture of mainly feldspar (oligoclase) composition and contains relict grains of both high‐Ca and low‐Ca pyroxene and fluorapatite. The mineralogical characteristics of these clasts suggest a genetic relationship and an origin from the same parent body. The textural and mineralogical characteristics of the clasts indicate origin by extensive igneous differentiation. Such processes most likely took place in a rather large differentiated body. The material of clast #d(3–5)D is similar in some mineralogical respects to basaltic shergottites.  相似文献   
2.
Field observations of tidally driven stratified flow in the sill area of Knight Inlet (British Columbia) revealed a very complicated structure, which includes solitary waves, upstream bifurcation, hydraulic jump and mixing processes. Recent observations suggest that the flow instabilities on the plunging pycnocline at the lee side of the sill may contribute to solitary wave generation through a subharmonic interaction. The present study reports on a series of numerical experiments of stratified tidal flow in Knight Inlet performed with the help of a fine resolution fully non-linear non-hydrostatic numerical model. The model reproduces all important stages of the baroclinic tidal dynamics observed in Knight Inlet. Results demonstrate that solitary waves are generated apart from the area of hydrodynamic instability. Accelerating tidal flux forms a baroclinic hydraulic jump just above the top of the sill, whereas the bifurcations and zones of shear instabilities are formed downstream of the sill. The first baroclinic mode having the largest velocity escapes from the generation area and propagates upstream, disintegrating further into a packet of solitary waves reviling the classical “non-subharmonic” mechanism of generation. The remaining part of the disturbance (slow baroclinic modes) is arrested by tidal flow and carried away to the lee side of the obstacle, where shear instability, billows and mixing processes are developed. Some sensitivity runs were performed for different value of tidal velocity.  相似文献   
3.
It is well established that the fractionation of Li–F granitic magmas at depth leads to the accumulation of flux elements such as F and Li, and metal cations such as Ta and Nb in residual melts. However, it remains to be determined whether magmatic fractionation is sufficient to concentrate Nb and Ta into economically significant quantities, and what role hydrothermal–metasomatic processes play in the formation of such ore deposits. In the literature, reliable data about the solubility of Ta and Nb in hydrothermal solutions is missing or incomplete. This study provides a quantitative experimental estimation of the possible contribution from hydrothermal processes in Ta enrichment in cupolas of albitized and greisenized Li–F granite. Experimental studies of Ta2O5 and columbite–tantalite (Mn,Fe)(Nb,Ta)2O6 solubility were carried out in fluoride solutions consisting of HF, NaF, KF, and LiF. At low fluoride concentrations (0.01 and 0.1 m), Ta2O5 solubility at 550°C and 100 MPa under Co–CoO oxidizing conditions is low (near 10?5–10?4 m) in all fluoride solutions (HF, NaF, KF, LiF). At high fluoride concentrations (1 and 2 m) the highest Ta2O5 concentrations (10?1 m) were detected in HF solutions. In KF, NaF, and LiF solutions, the Ta2O5 solubility is also high (10?3–10?2 m). The dependence of columbite–tantalite (Nb2O5-59 wt. %, Ta2O5-18 wt. %) solubility as a function of solution composition, T, and P has also been investigated. Tantalum and Nb concentrations have the highest values in HF solutions at reduced conditions (up to 10?3 to 10?2 m Ta in 1 m HF). In 1 m NaF solutions, the concentrations of Nb and Ta are, respectively, 2.5 and 3 orders of magnitude less than those in the 1 m HF solutions. Solubility of Ta and Nb in KF solutions has intermediate values. It is established that in NaF and KF solutions the dependence of solubility on pressure is distinctly negative. The Nb and Ta contents increase with increasing concentrations of HF and KF in solution, however, they do not change with increasing NaF concentration. In NaHCO3, Na2CO3, and HCl solutions columbite–tantalite solubility is low. Even in 1 m chloride solutions the content is within the limits of 10?5 m for Nb and 10?6 to 10?8 m for Ta. We conclude that hydrothermal transport of Ta and Nb is possible only in concentrated fluoride solutions.  相似文献   
4.
We study in some detail one-dimensional NLTE effects in solar Fei lines. The lines selected are frequently used in solar polarimetry, and also in studies of line asymmetries and for abundance determinations. Our model atom for Fei–Feii–Feiii is realistic: it takes account of multiplet structure and it includes over 200 bound–bound and bound–free transitions in detail. We use very efficient iterative methods for the self-consistent solution of the kinetic and radiative transfer equations (Auer, Fabiani Bendicho, and Trujillo Bueno, 1994). We have applied these fast methods of solution because they are suitable for the investigation of 2D and 3D NLTE transfer effects with multilevel atoms, which constitutes the next step of our ongoing research project on the iron line formation problem.  相似文献   
5.
The processes of formation and distribution of the resources of fresh groundwater and surface water in the territory of Crimea Peninsula are considered. Water availability in the natural–historic and administrative regions of the republic is characterized. The proportions between different categories of groundwater resources are shown with their role in water supply to Crimea taken into account. The presentday development of groundwater resources is analyzed and the possible increase in water consumption meeting geoecological requirements is substantiated.  相似文献   
6.
Water Resources - The present-day conditions of the formation and distribution of the water resources and chemistry under global warming during the recent decades have been considered. The...  相似文献   
7.
Water Resources - The space–time variations in the Oka basin water chemistry have been considered. The specific features in the river water and groundwater pollution along the Oka channel and...  相似文献   
8.
Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.  相似文献   
9.
In previous work, we presented a method for estimation and correction of non-linear mathematical model structures, within a Bayesian framework, by merging uncertain knowledge about process physics with uncertain and incomplete observations of dynamical input-state-output behavior. The resulting uncertainty in the model input-state-output mapping is expressed as a weighted combination of an uncertain conceptual model prior and a data-derived probability density function, with weights depending on the conditional data density. Our algorithm is based on the use of iterative data assimilation to update a conceptual model prior using observed system data, and thereby construct a posterior estimate of the model structure (the mathematical form of the equation itself, not just its parameters) that is consistent with both physically based prior knowledge and with the information in the data. An important aspect of the approach is that it facilitates a clear differentiation between the influences of different types of uncertainties (initial condition, input, and mapping structure) on the model prediction. Further, if some prior assumptions regarding the structural (mathematical) forms of the model equations exist, the procedure can help reveal errors in those forms and how they should be corrected. This paper examines the properties of the approach by investigating two case studies in considerable detail. The results show how, and to what degree, the structure of a dynamical hydrological model can be estimated without little or no prior knowledge (or under conditions of incorrect prior information) regarding the functional forms of the storage–streamflow and storage–evapotranspiration relationships. The importance and implications of careful specification of the model prior are illustrated and discussed.  相似文献   
10.
The results of studying the composition of hydrocarbon gases (C1–C5) and organic matter in bottom sediments of the Ivankovo Reservoir in 1995, 2004, and 2005 are given. The methods used in the study include vapor-phase gas chromatography, instrumental pyrolysis gas chromatography, and mass-spectrometry for determining organic carbon δ 13Corg. The gas field of bottom sediments in different regions of the reservoir varies widely in terms of gas saturation and the spectrum of hydrocarbon gases. This suggests the heterogeneous composition of organic matter in the sediments and different conditions of its input and transformation processes. The gases were found to contain saturated hydrocarbons from methane to pentane C1–C5, including isomers i-C4 and i-C5 and unsaturated compounds C2–C4. A correlation was found to exist between methane distribution and the distribution of its more high-molecular homologues, which confirms their genetic relationship in bottom sediments. The obtained results show an increase in the rate of microbiological processes and organic matter transformation for most regions in the Ivankovo Reservoir. The only exceptions are the zones of Moshkovichskii Bay and the sections at Gorodnya and Konakovo, where technogenic organic matter is being accumulated. The high information value of hydrocarbon gases as biogeochemical markers of the sources of organic matter and the rates of its transformation is demonstrated. The isotopic composition of organic-matter carbon in the bottom sediments of the Ivankovo Reservoir δ 13C varies from ?26.21 to ?30.86‰.  相似文献   
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