Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics     

Dumańska-Słowik  Magdalena  Pieczka  Adam  Natkaniec-Nowak  Lucyna  Kunecki  Piotr  Gaweł  Adam  Heflik  Wiesław  Smoliński  Wojciech  Kozub-Budzyń  Gabriela 《Mineralogy and Petrology》2018,112(3):381-392

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...  相似文献   

Lattice deformation of blue halite from Zechstein evaporite basin: Kłodawa Salt Mine,Central Poland     

Sylwia M. Zelek  Katarzyna M. Stadnicka  Tomasz Toboła  Lucyna Natkaniec-Nowak 《Mineralogy and Petrology》2014,108(5):619-631

Outcrops of natural blue and purple halite crystals have been found in K?odawa (Poland) salt deposit originating from the Permian (Zechstein) salt formation within tectonic zones. Field works carried out on various levels of K?odawa Salt Mine indicated differences both in intensity of the hue and in the size of the outcrops. Their occurrence was connected with the presence of epigenetic sediments rich in potassium. For the samples of blue halite, an optical anisotropy (birefringence) was observed for both standard mineralogical thin sections and thick plates, indicating a deviation from cubic symmetry. The blue colouration of the halites, described by ultraviolet–visible spectroscopy, is due to the presence of colour centres. The colour centres have been recently identified as: F, R₁ (F₃), R₂ (F₃), M and plasmons (Wese?ucha-Birczyńska et al., Vib Spectrosc 60:124–128, 2012). The trace amount of impurities detected in the blue halites by means of scanning electron microscopy–energy dispersive X-ray spectroscopy and micro-X-ray fluorescence techniques were connected mainly with solid inclusions such as K _x Na_(1???x)Cl, KMgCl₃·6H₂O, KCl, orthorhombic sulphur, quartz and some other phases like pyrite. Crystallographic data obtained by X-ray diffraction experiments for the single crystals of the halite from K?odawa with different saturation of blue or purple colours, as well as for natural colourless halite, revealed lowering of space-group symmetry to monoclinic, orthorhombic, trigonal, tetragonal or even triclinic systems while the space group typical for pure NaCl is Fm-3m.  相似文献