Crystal chemical significance of chemical zoning in dissakisite-(Ce)     

Mihoko Hoshino  Mitsuyoshi Kimata  Norimasa Nishida  Masahiro Shimizu 《Physics and Chemistry of Minerals》2008,35(2):59-70

Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types. Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F ₀| > 4σF ₀] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal, where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified as autoepitaxy.  相似文献   

High temperature heating of the Allende meteorite     

Kenji Notsu  Naoki Onuma  Norimasa Nishida  Hiroshi Nagasawa 《Geochimica et cosmochimica acta》1978,42(6):903-907

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Petrological constraints on the formation conditions and retrograde P–T path of the Kotsu eclogite unit, central Shikoku     

M. Matsumoto  S. Wallis  M. Aoya  M. Enami  J. Kawano  Y. Seto  N. Shimobayashi 《Journal of Metamorphic Geology》2003,21(4):363-376

A largely undocumented region of eclogite associated with a thick blueschist unit occurs in the Kotsu area of the Sanbagawa belt. The composition of coexisting garnet and omphacite suggests that the Kotsu eclogite formed at peak temperatures of around 600 °C synchronous with a penetrative deformation (D1). There are local significant differences in oxygen fugacity of the eclogite reflected in mineral chemistries. The peak pressure is constrained to lie between 14 and 25 kbar by microstructural evidence for the stability of paragonite throughout the history recorded by the eclogite, and the composition of omphacite in associated eclogite facies pelitic schist. Application of garnet‐phengite‐omphacite geobarometry gives metamorphic pressures around 20 kbar. Retrograde metamorphism associated with penetrative deformation (D2) is in the greenschist facies. The composition of syn‐D2 amphibole in hematite‐bearing basic schist and the nature of the calcium carbonate phase suggest that the retrograde P–T path was not associated with a significant increase or decrease in the ratio of P–T conditions following the peak of metamorphism. This P–T path contrasts with the open clockwise path derived from eclogite of the Besshi area. The development of distinct P–T paths in different parts of the Sanbagawa belt shows the shape of the P–T path is not primarily controlled by tectonic setting, but by internal factors such as geometry of metamorphic units and exhumation rates.  相似文献   

Phase transition in Ca-poor clinopyroxenes     

Norimasa Shimobayashi  Masao Kitamura 《Physics and Chemistry of Minerals》1991,18(3):153-160

High(C2/c)-low(P2₁/c) phase transition in clinoenstatite and pigeonite was successfully observed in situ at high temperatures for the first time under a transmission electron microscope. The phase transition was revealed to possess the characteristics of a first-order transition, due to the coexistence of both phases separated by the sharp interfaces and the nucleation-growth process. The diffusionless and time-independent reaction suggests that the transition occurs athermal-martensitically. Furthermore, the small or even negative thermal hysteresis and the interface motion suggest that the transition is not a typical type but a thermoelastic type of the martensitic transformation. This type of the transformation, studied extensively in metallurgy in relation to shape memory effect, is first recognized in rock-forming minerals.  相似文献   

Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material     

Norimasa Nishiyama  Robert Paul Rapp  Tetsuo Irifune  Takeshi Sanehira  Daisuke Yamazaki  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2005,32(8-9):627-637

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.  相似文献   

P–V–T equation of state of Ca₃Al₂Si₃O₁₂ grossular garnet     

Steeve Gréaux  Yoshio Kono  Norimasa Nishiyama  Takehiro Kunimoto  Kouhei Wada  Tetsuo Irifune 《Physics and Chemistry of Minerals》2011,38(2):85-94

The thermoelastic parameters of synthetic Ca₃Al₂Si₃O₁₂ grossular garnet were examined in situ at high-pressure and high-temperature by energy dispersive X-ray diffraction, using a Kawai-type multi-anvil press apparatus coupled with synchrotron radiation. Measurements have been conducted at pressures up to 20 GPa and temperatures up to 1,650 K: this P, T range covered the entire high-P, T stability field of grossular garnet. The analysis of room temperature data yielded V _0,300 = 1,664 ± 2 ?³ and K ₀ = 166 ± 3 GPa for K^￠₀ K^{\prime}_{0} fixed to 4.0. Fitting of our P–V–T data by means of the high-temperature third order Birch–Murnaghan or the Mie–Grüneisen–Debye thermal equations of state, gives the thermoelastic parameters: (∂K _0,T /∂T) _P  = −0.019 ± 0.001 GPa K⁻¹ and α _0,T  = 2.62 ± 0.23 × 10⁻⁵ K⁻¹, or γ ₀ = 1.21 for fixed values q ₀ = 1.0 and θ ₀ = 823 (Isaak et al. Phys Chem Min19:106–120, 1992). From the comparison of fits from two different approaches, we propose to constrain the bulk modulus of grossular garnet and its pressure derivative to K _T0 = 166 GPa and K^￠_T0 K^{\prime}_{T0}  = 4.03–4.35. Present results are compared with previously determined thermoelastic properties of grossular-rich garnets.  相似文献   

<Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">V</Emphasis>–<Emphasis Type="Italic">T</Emphasis> equation of state of CaAl<Subscript>4</Subscript>Si<Subscript>2</Subscript>O<Subscript>11</Subscript> CAS phase     

Steeve?GréauxEmail author  Norimasa?Nishiyama  Yoshio?Kono  Tetsuo?Irifune  Laurent?Gautron 《Physics and Chemistry of Minerals》2011,38(8):581-590

The thermoelastic parameters of the CAS phase (CaAl₄Si₂O₁₁) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V _0,300 = 324.2 ± 0.2 Å³ and K _0,300 = 164 ± 6 GPa for K′ _0,300 = 6.2 ± 0.8. With K′ _0,300 fixed to 4.0, we obtained: V _0,300 = 324.0 ± 0.1 Å³ and K _0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V _0,300 = 324.2 ± 0.1 Å³, K _0,300 = 171 ± 5 GPa, K′ _0,300 = 5.1 ± 0.6 (?K _0,T /?T) _P  = ?0.023 ± 0.006 GPa K^?1, and α_0,T  = 3.09 ± 0.25 × 10^?5 K^?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl₄Si₂O₁₁. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone.  相似文献   

Prolonged impact of earthquake-induced landslides on sediment yield in a mountain watershed: The Tanzawa region, Japan   总被引：5，自引：0，他引：5  

Takashi Koi  Norifumi Hotta  Ituro Ishigaki  Norimasa Matuzaki  Yoshimi Uchiyama  Masakazu Suzuki 《Geomorphology》2008,101(4):692-702

To determine for how long a landslide affects sediment discharge, the sediment yields of 15 check-dam basins were compared with the time series of landslide distributions in a mountain basin in the Tanzawa region, central Japan. The distribution of sediment yield was quantitatively estimated from deposition in the sediment pools of check dams. The relationship between the landslide history and sediment discharge in the Nakagawa River basin was examined for an approximately 80-year period. Two major landslide events occurred during this period: the 1923 Kanto Earthquake and the 1972 disaster caused by heavy rainfall. The resulting trend in sediment discharge of the whole basin, estimated using reservoir sedimentation in the Miho Dam at its base, was nearly constant, with high sediment discharge (2897 m³ km^− 2 yr^− 1) in the intervening quarter-century, despite the recovery of vegetation on landslide areas in this period. Comparisons of the landslide distributions resulting from the two disasters, the sediment yields of check-dam basins, and the sediment discharge of the whole basin indicate that recent sediment discharge contains landslide debris that was originated by the Kanto Earthquake that occurred over 80 years ago. Thus, to understand high sediment discharge, it is essential to investigate not only the current basin condition and recent events, but also the landslide history of the basin for at least the previous 100 years.  相似文献   

Molecular dynamics simulations of the phase transition between low-temperature and high-temperature clinoenstatites     

N. Shimobayashi  A. Miyake  M. Kitamura  E. Miura 《Physics and Chemistry of Minerals》2001,28(9):591-599

 Phase transition between low-temperature clinoenstatite (LT-CEn) and high-temperature clinoenstatite (HT-CEn) was studied by using molecular dynamics (MD) simulations, based on empirical potential parameters. Starting from LT-CEn, the MD calculations were carried out at atmospheric pressure and at elevated pressures (1–6 GPa). At elevated temperatures the transformation from the starting LT-CEn to HT-CEn occurred at any pressure. It was confirmed that the HT-CEn has the same space group C2/c as diopside but the M2 site is six-coordinated, unlike diopside. A significant difference in the MD-simulated cell volumes between LT-CEn and HT-CEn was also observed, showing a first-order transition. In addition, there were some temperature ranges where LT-CEN and HT-CEn would be coexistent and very small thermal hystereses between increasing and decreasing temperatures during the transition. These behaviors are consistent with the characteristic of a thermoelastic-martensitic transformation. The phase boundary between LT-CEn and HT-CEn was determined for the first time. Its positive dT/dP slope strongly shows that the high-pressure clinoenstatite is a significantly distinct phase from HT-CEn although the both phases have the same space group, C2/c. Received: 8 November 2000 / Accepted: 28 April 2001  相似文献   

Determination of Nickel in GSJ Standard Rock Samples Using Secondary Ion Mass Spectrometry     

Hisayoshi YURIMOTO  Isao SAKAGUCHI  Norimasa NISHIDA  Shigeho SUENO 《Geostandards and Geoanalytical Research》1991,15(1):155-159

Trace level determination of nickel in silicate rock samples has been achieved using secondary ion mass spectrometry (SIMS) with kinetic energy filtering. Standard rock references, issued by the Geological Survey of Japan, were fused into glass and used as standards for the SIMS analysis. Due to interferences from the glass matrix, the secondary ion of mass 60 was only useful for Ni, although the secondary ion was interfered mainly by CaO+. The contributions of these molecular ions were deconvolved by a least squares regression. Good linear correlation between results after the deconvolution and the Ni concentration in the glass standards was obtained. The uncertainties of the SIMS analysis depend strongly on the degree of contribution of CaO+ molecular ion. Such a method of SIMS analysis is especially useful to study the detailed behavior of Ni on a micro-scale in Ca-poor materials.  相似文献