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1.
Y. Thomas He Arthur G. Fitzmaurice Azra Bilgin Sunkyung Choi Peggy O’Day John Horst James Harrington H. James Reisinger David R. Burris Janet G. Hering 《Applied Geochemistry》2010
The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes. 相似文献
2.
Estimation of Rock Cuttability from Shore Hardness and Compressive Strength Properties 总被引：6，自引：1，他引：6
Summary Shore hardness has been used to estimate some mechanical and physical properties of rocks for many years. This study differs
from previous studies in a way that it is directly oriented to rock cuttability. Two Shore hardness values (SH
1 andSH
2) and a coefficient of deformation value (K) have been measured for 30 different rock samples. In the first stage of the study, optimum specific energy values for 16
different rock samples obtained from full-scale cutting tests were correlated with the Shore hardness values of the same rock
samples changingSH
1 values from 9 to 66 andSH
2 values from 25 to 83, with deformation coefficient values changing from 26 to 195. In the second stage, the performance of
a roadheader used in the Kü?üksu (Istanbul) tunnel was recorded in detail and the instantaneous cutting rate of the machine
was determined. Then, the relationship between Shore hardness values, deformation coefficient and the instantaneous cutting
rate of the machine was determined for different formations encountered. It is concluded that there is a relationship between
Shore hardness values, optimum specific energy and compressive strength, which may be used to estimate the rock cuttability
and the instantaneous cutting rates of roadheaders within certain limits of reliability. 相似文献
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Numerical studies of anchored sheet pile wall behavior constructed in cut and fill conditions 总被引：1，自引：0，他引：1
The construction of sheet pile walls may involve either excavation of soils in front or backfilling of soils behind the wall. These construction procedures generate different loading conditions in the soil and therefore different wall behavior should also be expected. The conventional methods, which are based on limit equilibrium approach, commonly used in the design of anchored sheet pile walls do not consider the method of construction. However, continuum mechanics numerical methods, such as finite element method, make it possible to incorporate the construction method during the analyses and design of sheet pile walls. The effect of wall construction type for varying soil conditions and wall heights were investigated using finite element modeling and analysis. The influence of construction method on soil behavior, wall deformations, wall bending moments, and anchor forces were investigated. The study results indicate that walls constructed by backfill method yield significantly higher bending moments and wall deformations. This paper presents the results of the numerical parametric study performed and comparative analyses of the anchored sheet pile walls constructed by different construction methods. 相似文献
5.
In order to characterize the seasonal, bathymetric, and spatial distribution of the species, Palaemon adspersus, Palaemon elegans, and Crangon crangon, shrimps were sampled with a beam trawl in four stations at depths between 1 and 30 m from February 2002 to January 2004 on the Sinop Peninsula coasts of the southern Black Sea. One-way analysis of similarity (ANOSIM) results demonstrated that the caridean composition was significantly different (p < 0.001) between seasons and between sampling areas. No significant relationship of the caridean composition was evident between depth zones ranging from 1 to 30 m. These three carideans occurred together in 28.5% of the sampling occasions. Different seasonal migration pattern was evident for all the three species. Palaemon adspersus migrated inshore during relatively higher water temperatures, whereas C. crangon density decreased in the shallow waters during the same period, and P. elegans population was mostly observed at depth zones of 5–10 m and was only observed in the 30 m depth zone in winter. The abiotic factors that characterize the coexistence of these three carideans were primarily determined by the habitat types and bottom structures. 相似文献
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8.
Janet G. Hering Peggy A. O'Day Robert G. Ford Y. Thomas He Azra Bilgin H. James Reisinger David R. Burris 《Ground Water Monitoring & Remediation》2009,29(3):84-92
The potential application of monitored natural attenuation (MNA) as a remedy for ground water contaminated with arsenic (As) is examined for a subset of contaminated sites, specifically those where naturally occurring As has been mobilized due to localized anthropogenic organic carbon (OC) releases. This includes sites subject to petroleum releases, exposure to landfill leachates, and OC additions for biostimulation of reductive dechlorination of chlorinated solvents. The key characteristic of these sites is that, under conditions prevailing before the anthropogenic OC introduction, the naturally occurring As in the subsurface was not mobile and did not adversely affect ground water quality. This suggests that, in the far-field (where background conditions are (re) established), As may be sequestered upon contact of the contaminated ground water with either or both the (uncontaminated) ambient ground water and the background aquifer minerals. The observed extents of elevated concentrations (or "footprints") of As and other chemical species, such as dissolved OC and iron (Fe), and related parameters, such as redox potential ( E h ) and dissolved oxygen, and their evolution over time can be used to assess the mobilization and sequestration of As and the potential feasibility of MNA as a remedial option. Ultimately, the capacity for As sequestration must be assessed in the context of the OC loading to the site, which may require "active" measures for source control. Monitoring is needed to confirm the continuing effectiveness of the MNA remedy or to indicate if contingency measures must be implemented. 相似文献
9.
Application of Mineral‐Based Amendments for Enhancing Phytostabilization in Lolium perenne L. Cultivation 
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下载免费PDF全文 An experimental investigation is conducted to explore the suitability of Lolium perenne L., diatomite, chalcedonite, dolomite, and limestone for the phytostabilization of Ni and Cu in contaminated soil. A controlled greenhouse study is conducted. The soil is enriched with rising dose of Cu and Ni, that is, (0, 150, 250, and 350 mg kg?1) and (0, 150, 300, and 450 mg kg?1), respectively. The phytostabilization potential of perennial ryegrass is evaluated using a bioaccumulation coefficient and translocation factor. Pseudo‐total and available metal content (0.01 M CaCl2) in soils and bioaccumulated content in plants are defined in laboratory experiments using spectrophotometry experimental technique. L. perenne is adequate in phytostabilization aided programs, simultaneously, diatomite, chalcedonite, dolomite, and limestone used as modifiers are effective in reducing the accessibility and mobility of metals in Cu‐ and Ni‐polluted soils. The finding of the present study suggests that the studied element in the roots and above‐ground parts of L. perenne differs significantly upon applying mineral‐based modifications to the soil, synchronously the effect of increasing Cu and Ni levels. Application of dolomite and limestone to the soil cause the highest percentage of the above‐ground biomass. Diatomite along with limestone cause a significant boost of Cu and Ni absorption in the roots. Limestone causes an increase in the contents of K, Na, and Ca, as well as a reduction in P in the above‐ground parts of L. perenne. Limestone and chalcedonite leads to the highest decrease in available Cu and Ni. 相似文献
10.
Geochemical and hydrologic controls on the mobilization of arsenic derived from herbicide application 总被引：1，自引：0，他引：1
Arthur G. Fitzmaurice A. Azra Bilgin Peggy A. O&#x;Day Virginia Illera David R. Burris H. James Reisinger Janet G. Hering 《Applied Geochemistry》2009,24(11):2152-2162
The fate and transport of As was examined at an industrial site where soil- and groundwater contamination are derived from the application of As2O3 as a herbicide. Application of arsenical herbicides was discontinued in the 1970s and soils in the source area were partially excavated in 2003. Arsenic contamination (up to 280 mg/kg) remains in the source area soils and a plume of As-contaminated groundwater persists in the surficial aquifer downgradient of the source area with maximum observed As concentrations of 1200 μg/L near the source area. The spatial extent of As contamination as defined by the 10 μg/L contour appears to have remained relatively stable over the period 1996–2006; the boundary of the 1000 μg/L contour has retreated over the same time period indicating a decrease in total As mass in the surficial groundwater.In column experiments conducted with source area soil, the As concentrations in the column effluent were comparable to those observed in groundwater near the source area. A substantial fraction of the As could be leached from the source area soil with ammonium sulfate and ammonium phosphate. Exhaustive extraction with background groundwater removed most of the total As. These results indicate that As in the source area soils is geochemically labile. Source area soils are low in extractable Fe, Mn and Al, and characterization by X-ray absorption spectroscopy and electron microscopy indicated that As is present primarily as arsenate sorbed to (alumino)silicate minerals. Batch sorption experiments showed much less sorption on surficial aquifer sediments than on sediments from the Jackson Bluff Formation (JBF), a presumed confining layer. This limited capacity of the surficial aquifer sediments for As sorption is consistent with the similar As contents observed for these sediments within and upgradient of the As plume. The apparent stability of the As plume cannot be explained by sequestration of As within the surficial aquifer. Sorption to JBF sediments may contribute to As sequestration, but As enrichment in JBF sediments within the plume (i.e., as compared with JBF sediments upgradient) was not observed. These results indicate that neither the persistence of As in the source area soils or the apparent stability of the plume of As-contaminated groundwater at this site can be explained by geochemical controls on As mobility. The absence of demonstrable geochemical bases for such observations suggests that possible hydrologic controls should be further investigated at this site. 相似文献