Coastal Upwelling Activity on the Pacific Shelf of the Baja California Peninsula     

Oleg Zaytsev  Rafael Cervantes-Duarte  Orzo Montante  Artemio Gallegos-Garcia 《Journal of Oceanography》2003,59(4):489-502

High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m³/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters into the lagoon system. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Formation conditions of copper porphyry mineralization in the Kadica-Bukovik ore district,eastern Macedonia     

A. V. Volkov  G. Tasev  V. Yu. Prokof’ev  T. Serafimovski  I. N. Tomson  A. A. Sidorov 《Doklady Earth Sciences》2008,421(1):769-773

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Disseminated ores of the Darasun gold deposit (Eastern Transbaikalia) and their genesis     

V. Yu. Prokof’ev  N. S. Bortnikov  A. V. Volkov  I. A. Baksheev  L. D. Zorina 《Doklady Earth Sciences》2008,422(1):1025-1027

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Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

Tectonic position of the Alshar Au-As-Sb-Tl deposit, Macedonia     

N. T. Kochneva  A. V. Volkov  T. Serafimovski  G. Tasev  I. N. Tomson 《Doklady Earth Sciences》2006,407(2):175-178

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Managanese and iron in the White Sea: Sedimentation and diagenesis     

A. G. Rozanov  I. I. Volkov  N. M. Kokryatskaya  M. V. Yudin 《Lithology and Mineral Resources》2006,41(5):483-501

Iron and manganese in bottom sediments studied along the sublatitudinal transect from Kandalaksha to Arkhangelsk are characterized by various contents and forms depending on sedimentation environments, grain size of sediments, and diagenetic processes. The latter include redistribution of reactive forms leading to enrichment in Fe and Mn of the surface sediments, formation of films, incrustations, and ferromanganese nodules. Variations in the total Fe content (2–8%) are accompanied by changes in the concentration of its reactive forms (acid extraction) and the concentration of dissolved Fe in the interstitial water (1–14 μM). Variations in the Mn content in sediments (0.03–3.7%) and the interstitial water (up to 500 μM) correspond to a high diagenetic mobility of this element. Changes in the valence of chemical elements results in the redox stratification of sediment strata with maximum concentrations of Fe, Mn, and sulfides. Organic matter of sediments with a considerable terrestrial constituent is oxidized by bottom water oxygen mainly at the sediment surface or in anaerobic conditions within the sediment strata. The role of inorganic components in organic matter oxidation changes from surface sediments, where manganese oxyhydroxide dominates among oxidants, to deeper layers, where sulfate of interstitial water serves as the main oxidant. Differences in river runoff and hydrodynamics are responsible for geochemical asymmetry of the transect. The deep Kandalaksha Bay serves as a sediment trap for manganese (Mn content in sediments varies within 0.5–0.7%), whereas the sedimentary environment in the Dvina Bay promotes its removal from sediments (Mn 0.05%).  相似文献   

An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution     

Gleb S Pokrovski  Jacques SchottJean-Louis Hazemann  François Farges  Oleg S Pokrovsky 《Geochimica et cosmochimica acta》2002,66(24):4203-4222

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.  相似文献   

Siberian river run-off and Late Quaternary glaciation in the southern Kara Sea, Arctic Ocean: preliminary results   总被引：3，自引：0，他引：3  

Ruediger Stein  Frank Niessen  Klaus Dittmers  Michael Levitan  Frank Schoster  Johannes Simstich  Tatjana Steinke  Oleg V. Stepanets 《Polar research》2002,21(2):315-322

The extent of the Barents-Kara Ice Sheet during the eastern Last Glacial Maximum (LGM) is not yet fully known. A detailed echo-sounding survey performed during the Boris Petrov Expedition 2001 permitted the detailed mapping of part of it. Based on the profiling results, a southern connection between the LGM Barents-Kara Ice Sheet and a local ice sheet on Taymyr Peninsula appears to be unlikely. Based on sediment core data and profiling results, most of the terrigenous river-derived material accumulated in the estuaries during late Holocene times, whereas during early Holocene times of lowered sea level major amounts were transported further offshore and accumulated on the shelf. During the post-glacial sea level rise, the main depocentre migrated southward, reaching its present position no earlier than about 6 cal. Ky BP (or 5.2 Kya). Future studies of accelerator mass spectrometry (AMS) ¹⁴C-dated sediment cores will allow a detailed reconstruction of the variability of fluvial sediment discharge and the history of glaciation in the Kara Sea during late Quaternary times.  相似文献   

Phenomenon of the Formation of Very Thick Coal Beds     

Volkov  V. N. 《Lithology and Mineral Resources》2003,38(3):223-232

Peculiarities of the distribution, morphological features, geological localization, and formation conditions have been considered for unique coal beds (thickness more than 50–100 m). It has been revealed that the genesis of such beds is related to extremely long-term (tens to hundreds of thousand years) stabilization periods of formation conditions of primary peat deposits. A significant role of the peat self-compaction is demonstrated. Principal types of coalfields with very thick beds are distinguished. Localization criteria (position in the section along with paleotectonic and paleogeographic controls) are presented for the most widespread types.  相似文献   

Time-domain electromagnetic migration in the solution of inverse problems   总被引：5，自引：0，他引：5  

Michael S. Zhdanov  Oleg Portniaguine 《Geophysical Journal International》1997,131(2):293-309

Time-domain electromagnetic (TDEM) migration is based on downward extrapolation of the observed field in reverse time. In fact, the migrated EM field is the solution of the boundary-value problem for the adjoint Maxwell's equations. The important question is how this imaging technique can be related to the solution of the geoelectrical inverse problem. In this paper we introduce a new formulation of the inverse problem, based on the minimization of the residual-field energy flow through the surface or profile of observations. We demonstrate that TDEM migration can be interpreted as the first step in the solution of this specially formulated TDEM inverse problem. However, in many practical situations this first step produces a very efficient approximation to the geoelectrical model, which makes electromagnetic migration so attractive for practical applications. We demonstrate the effectiveness of this approach in inverting synthetic and practical TDEM data.  相似文献