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Ondrej Ledvinka Anna Lamacova 《Stochastic Environmental Research and Risk Assessment (SERRA)》2015,29(5):1463-1484
Trend analysis is a frequently used tool in hydrology and climatology for the identification of long-term changes. However, studies are usually only oriented on local trends. This paper rather focuses on the spatial application of trend analysis in groundwater data. For this purpose, a modification of the Mann-Kendall test was developed, based on the trend-free pre-whitening approach. This method was successfully tested on 157 series of yields from headwater springs collected in Czechia during the 1971–2007 period. The analysis was done separately for year, each season and each month. Field significant trends in spring yields were identified in hydrogeological regions. The results showed that the field significant trends are outnumbered when cross-correlation is not taken into account. In the case of annual series, 4 of 18 hydrogeological regions investigated showed a significant decreasing trend after corrections for cross-correlation, compared to 12 regions with field significant trend when not considering cross-correlation. 相似文献
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Alexandre V. Andronikov Martin Novak Pavel Kram Ondrej Sebek Irina E. Andronikova Marketa Stepanova Hyacinta Vitkova Elena Antalova Arnost Komarek 《水文研究》2021,35(12):e14434
One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ53Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ53Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ53Cr value of bulk silicate Earth (BSE). Positive mean δ53Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ53Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ53Cr values of runoff, compared to arithmetic mean δ53Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ53Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering. 相似文献
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Understanding the role of forests on snowmelt processes enables better estimates of snow storages at a catchment scale and contributes to a higher accuracy of spring flood forecasting. A coniferous forest modifies the snowpack energy balance by reducing the total amount of solar shortwave radiation (SWR) and enhancing the role of longwave radiation (LWR) emitted by trees. This study focuses on changes in SWR and LWR at three sites with different canopy structure (Bohemian Forest, Czechia), including one site affected by the bark beetle (Ips typographus). Measurements of incoming and outgoing SWR and LWR were performed at all sites equipped with CNR4 Net Radiometers for three cold seasons. In addition to SWR and LWR, sensible and latent heat, and ground heat and energy supplied by liquid precipitation were calculated. The results showed that net SWR at the healthy forest site represented only 7% of the amount at the open site due to the shading effect of trees. In contrast, net LWR represented a positive component of the snowpack energy balance at the healthy forest site and thus contributed the most to snowmelt. However, the modelled snowmelt rates were significantly lower in the forest than in the open area since the higher LWR in the forest did not compensated for the lower SWR. The progressive decay of disturbed forest caused the decrease in mean net LWR from −3.1 W/m2 to −12.9 W/m2 and the increase in mean net SWR from 31.6 W/m2 to 96.2 W/m2 during the study period. These changes caused an increase in modelled snowmelt rates by 50% in the disturbed forest, compared to the healthy forest site, during the study period. Our findings have important implications for runoff from areas affected by land cover changes due to either human activity or climate change. 相似文献
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Norma Tombesi Karla Pozo Andrés Arias Mónica Alvarez Petra Pribylova Ondrej Audy Jana Klánová 《Environmental Earth Sciences》2018,77(11):403
The present study fills a gap in the knowledge in regards to the occurrence of banned pesticides at both coastal and inland locations at the Southwest Buenos Aires region, Argentina. Superficial sediment and soil samples were collected from different sites along the Bahia Blanca Estuary and surrounding sites to assess the concentration levels and spatial distribution of 12 selected organochlorine pesticides (OCs); 13 spatial locations including inland and shore-coast were sampled to evaluate occurrence and concentration levels of hexachlorocyclohexanes α-HCH, β-HCH, δ-HCH, γ-HCH, dichlorodiphenyltrichloroethane and its degradation products (DDXs: p,p′-DDT, o,p′-DDT, p,p′-DDE, o,p′-DDE, p,p′-DDD, o,p′-DDD) and the polychlorobenzenes PeCB (pentachlorobenzene) and HCB (hexachlorobenzene). After cleaning and extractions steps, samples were analyzed by means of gas chromatography/mass spectrometry. ∑OCs (sum of all studied compounds) ranged between 0.206 and 1040 ng g?1 dw (mean?=?82.4 and SD?=?277 ng g?1 dw). Total HCHs (sum of α-HCH, β-HCH, γ-HCH and δ-HCH) ranged from 0.0858 to 0.876 ng g?1 dw (mean?=?0.43 and SD?=?0.23 ng g?1 dw), DDXs (sum of p,p′and o,p′ isomers) from 0.080 to 1040 ng g?1 dw (mean?=?81.3 and SD?=?277 ng g?1 dw). Lower concentrations were found for PeCB (mean?=?0.095 and SD 0.17 ng g?1 dw) and HCB (mean?=?0.56 and SD 1.7 ng g?1 dw). Principal component analysis (PCA) permitted the extraction of underlying information about common factors, providing an overview of the distribution of pesticides and allowing the characterization of sites in regards to the major pesticide signature. 相似文献
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Martin Novak Alexandre Andronikov Pavel Kram Jan Curik Frantisek Veselovsky Marketa Stepanova Eva Prechova Ondrej Sebek Leona Bohdalkova 《水文研究》2021,35(4):e14116
Data on temporal variability in Mg isotope ratios of atmospheric deposition and runoff are critical for decreasing the uncertainty associated with construction of isotope mass balances in headwater catchments, and statistical evaluation of isotope differences among Mg pools and fluxes. Such evaluations, in turn, are needed to distinguish between biotic and abiotic contributions to Mg2+ in catchment runoff. We report the first annual time-series of δ26Mg values simultaneously determined for rainfall, canopy throughfall, soil water and runoff. The studied 55-ha catchment, situated in western Czech Republic, is underlain by Mg-rich amphibolite and covered by mature spruce stands. Between 1970 and 1996, the site received extremely high amounts of acid deposition and fly ash form nearby coal-burning power plants. The δ26Mg values of open-area precipitation (median of −0.79‰) at our study site were statistically indistinguishable from the δ26Mg values of throughfall (−0.73‰), but significantly different from the δ26Mg values of soil water (−0.55‰) and runoff (−0.55‰). The range of δ26Mg values during the observation period decreased in the order: open-area precipitation (0.57‰) > throughfall (0.27‰) > runoff (0.21‰) > soil water (0.16‰). The decreasing variability in δ26Mg values of Mg2+ from precipitation to soil water and runoff reflected an increasing homogenization of atmospheric Mg in the catchment and its mixing with geogenic Mg. In addition to atmospheric Mg, runoff also contained Mg mobilized from the three major solid Mg pools, bedrock (δ26Mg of −0.32‰), soil (−0.28‰), and vegetation (−0.31‰). The drought of summer 2019 did not affect the nearly constant δ26Mg value of runoff. Collectively, our data show that within-catchment processes buffer the Mg isotope variability of the atmospheric input. 相似文献
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Petra Maierová Ond?ej ?adek Ondrej Lexa Karel Schulmann 《Studia Geophysica et Geodaetica》2012,56(2):595-619
We present a numerical model of the main phase (370?C335 Ma) of the Variscan orogeny in the central part of the Bohemian Massif. The crustal deformation in our model is driven by radiogenic heating in the felsic lower crust, the lateral contraction of the Moldanubian domain due to convergence with the Saxothuringian plate (in the early stage of orogeny), and the indentation of the Brunovistulian basement into the weakened orogenic root (in the late stage). Our model explains the main geological events inferred from the geological record in the Moldanubian domain: formation of the orogenic plateau and onset of sedimentation at about 345 Ma, rapid exhumation of the orogenic lower crust at about 340 Ma and subsurface flow of crustal material (?? 335 Ma and later). The results of our modeling suggest that delamination of the lithosphere, often invoked to explain the high temperature metamorphism in the orogenic lower crust of the Bohemian Massif, is not the only physical mechanism which can transfer a sufficient amount of heat to the crust to trigger its overturn. 相似文献
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Karel Schulmann Jiří Konopásek Vojtĕch Janoušek Ondrej Lexa Jean-Marc Lardeaux Jean-Bernard Edel Pavla Štípská Stanislav Ulrich 《Comptes Rendus Geoscience》2009,341(2-3):266-286
The geological inventory of the Variscan Bohemian Massif can be summarized as a result of Early Devonian subduction of the Saxothuringian ocean of unknown size underneath the eastern continental plate represented by the present-day Teplá-Barrandian and Moldanubian domains. During mid-Devonian, the Saxothuringian passive margin sequences and relics of Ordovician oceanic crust have been obducted over the Saxothuringian basement in conjunction with extrusion of the Teplá-Barrandian middle crust along the so-called Teplá suture zone. This event was connected with the development of the magmatic arc further east, together with a fore-arc basin on the Teplá-Barrandian crust. The back-arc region – the future Moldanubian zone – was affected by lithospheric thinning which marginally affected also the eastern Brunia continental crust. The subduction stage was followed by a collisional event caused by the arrival of the Saxothuringian continental crust that was associated with crustal thickening and the development of the orogenic root system in the magmatic arc and back-arc region of the orogen. The thickening was associated with depression of the Moho and the flux of the Saxothuringian felsic crust into the root area. Originally subhorizontal anisotropy in the root zone was subsequently folded by crustal-scale cusp folds in front of the Brunia backstop. During the Visean, the Brunia continent indented the thickened crustal root, resulting in the root's massive shortening causing vertical extrusion of the orogenic lower crust, which changed to a horizontal viscous channel flow of extruded lower crustal material in the mid- to supra-crustal levels. Hot orogenic lower crustal rocks were extruded: (1) in a narrow channel parallel to the former Teplá suture surface; (2) in the central part of the root zone in the form of large scale antiformal structure; and (3) in form of hot fold nappe over the Brunia promontory, where it produced Barrovian metamorphism and subsequent imbrications of its upper part. The extruded deeper parts of the orogenic root reached the surface, which soon thereafter resulted in the sedimentation of lower-crustal rocks pebbles in the thick foreland Culm basin on the stable part of the Brunia continent. Finally, during the Westfalian, the foreland Culm wedge was involved into imbricated nappe stack together with basement and orogenic channel flow nappes. 相似文献
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Laser Ablation and Solution ICP-MS Determination of Rare Earth Elements in USGS BIR-1G, BHVO-2G and BCR-2G Glass Reference Materials 总被引：2，自引：0，他引：2
Ladislav Strnad Martin Mihaljevic Ondrej Sebek 《Geostandards and Geoanalytical Research》2005,29(3):303-314
Data are reported for rare earth elements (REE) in three geological glass reference materials (BIR-1G, BHVO-2G and BCR-2G) using a UV (266 nm) laser ablation ICP-MS system and the classical (HF-HClO4 ) acid decomposition method, followed by conventional nebulisation ICP-MS. External calibration of laser ablation analyses was performed using NIST SRM reference materials with internal standardisation using 29 Si and 44 Ca. Replicate analyses of reference basaltic glasses yielded an analytical precision of 1-5% (RSD) for all the elements by solution ICP-MS and 1-8% (RSD) by laser ablation ICP-MS. The relative differences between the REE concentrations measured by solution and laser ablation ICP-MS compared with the reference values were generally less than 11 % for most elements. The largest deviations occurred for La determined by solution ICP-MS in BIR-1G. The results of both solution and laser ablation ICP-MS agreed well, generally better than 7%, with the exception of La, Pr and Sm in BIR-1G. The measured REE laser ablation data for BIR-1G, BHVO-2G and BCR-2G agreed with the previously published data on these basaltic reference glasses, within a range of 0-10% for most elements. No significant influences were observed for the predicted spectral interferences on some REE isotopes in the analysis of basaltic glasses. 相似文献
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