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This study focuses on the performance of nanostructured banana peels in lanthanide-laden mine water treatment. Specifically, nanostructure formation via mechanical milling, characterization in detail and application of this sorbent media in rare earth elements (REEs) removal from synthetic and real mine water are thoroughly investigated. The sorbent samples were characterized by transmission electron microscopy, Brunauer–Emmett–Teller, X-ray diffraction and Fourier transform infrared analyses, while the amount of REEs adsorbed was analysed using inductively coupled plasma optical emission spectroscopy. Results revealed that the particle and crystallite sizes were reduced from <65,000 to <25 nm and 108 to 12 nm, respectively, as the milling progressed. Furthermore, the fracture of particles resulted in a surface area increment from 1.07 to 4.55 m2 g?1. Through Fourier transform infrared analysis, the functional groups responsible for the coordination and removal of metal ions were found to be carboxylic group (at absorption bands of 1730 cm?1) and amine groups (889 cm?1). The Langmuir maximum adsorption capacity was 47.8 mg g?1 for lanthanum and 52.6 mg g?1 for gadolinium. Meanwhile, results revealed that banana peels have a high affinity for Sm, Eu, Nd, Pr, Gd, Tb and Lu compared to other lanthanides present in the mine water samples. The results obtained so far indicate that nanostructured banana peel is a potential adsorbent for REEs removal from mine water. However, for any application, the water matrix to be treated substantially influences the choice of the sorbent material.  相似文献   
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Geotechnical and Geological Engineering - Crown pillars provide regional and local support by isolating the ground surface from underground mine workings. Topography above the underground mine may...  相似文献   
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The aquatic weed Eichhornia crassipes [Mart.]Solms was introduced in Lake Victoria from Rwanda via the Kagera River by the activities of man. After originally infesting Lake Victoria (Uganda), it eventually spread into the Winam gulf, where its proliferation was spectacular, resulting in an enormous public outcry. The aim of this study was to find out how a beach/bay covered by a weed carpet affected the life of a lakeshore community, if there were any seasonal changes in carpet sizes and to establish if the water hyacinth is a friend or an enemy. Surveys were conducted in selected beaches between June 1995 and November 1999. When surveys were complete, it became clear that this weed is nomadic, except in lagoons and beaches that had little external interference. The open waters remained generally clear due to constant wave action. Interviews conducted on selected beaches/bays indicated that weed carpets impacted both positively and negatively, i.e. they disrupted fishing activities, transport, irrigation, water treatment, enhanced breeding grounds for vectors of human diseases, impacted on biodiversity and had become a source of raw materials for making furniture, paper and artefacts. After successful biological control by the Kenya Agricultural Research Institute (KARI), resurgence and succession were observed. The impact of water hyacinth on the life of the lakeshore communities in the Winam gulf is serious and needs to be quantified. Further research is necessary to establish whether this weed is an enemy or a friend of the lakeshore communities.  相似文献   
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