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1.
In order to evaluate analytically the ITZ volume fraction (fITZ) in concrete, a three phase model is proposed for the random concrete microstructure using the Voronoï tessellation. Within this model, the ITZ local thickness is a statistical variable depending on the local paste thickness available between each couple of neighbouring aggregates. The fITZ is found to not exceed 7% for typical concretes. Then, the concrete Young's modulus is predicted analytically using a four‐phase generalized self consistent model but in which the proposed fITZ is considered. It is found that the concrete Young's modulus increases when increasing aggregates volume fraction, aggregates maximum size and the proportion of coarse aggregates and when decreasing the ITZ thickness and Young's modulus. Finally, the validity of the proposed model is discussed based on a comparison between its predictions and three sets of experimental results related to normal and high strength concretes taken from literature. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
2.
An off-line solid-phase extraction procedure followed by high-performance liquid chromatography with ultraviolet detection for the determination of 16 priority polycyclic aromatic hydrocarbon pollutants in aqueous matrices was described. Diverse aspects determining extraction efficiency such as packing type (disk or cartridge), elution solvents and addition of organic modifiers to the sample were evaluated. Elution with acetonitrile yields the highest recoveries. Rinsing the sample bottle with acetonitrile and combining the rinse with the sample extract avoids the adsorption of polycyclic aromatic hydrocarbons on the walls of the water containers. The use of isopropanol or methanol 10 % (V/V) was the most appropriate amount for the enrichment of 2- to 6-ring aromatic compounds only on C18 cartridge. The recoveries for all studied polycyclic aromatic hydrocarbons are ranged from 71.4 to 95.2 % for a treated water samples of 500 mL. The proposed method gives very low detection limits (subnanograms per liter) and it has been applied to drinking water, surface water and industrial effluent (oil refinery) samples with good results.  相似文献   
3.
In order to protect infrastructures against rockfalls, civil-engineered mitigation measures are widely used. Flexible metallic fences are particularly well suited to stop the propagation of blocks of rock whose kinetic energy can reach 5000?kJ before impact. This paper focuses on the design of highly flexible rockfall fences under the new European guideline ETAG027. The experimental testing and the numerical modeling using the discrete element method (DEM) of a new metallic rockfall fence are presented. Several scales of study were considered; the mesh, the net and the entire structure. The calibration of the DEM models is described and a parametrical study is proposed. The latter aims to underline the type of information that can be obtained from numerical simulations of such a system to enhance its design.  相似文献   
4.

A study of thirteen geothermal springs located in the geothermal field of Guelma, northeastern Algeria, was conducted. Samples were collected during the period between January 2014 and February 2016. Geochemical processes responsible for the chemical composition of thermal and mineralized water were evaluated. The hydrochemical analysis shows that the thermal waters are characterized by the presence of two different chemical facies, the first type SO4–Ca in the east, west and south of Guelma, the second type HCO3–Ca in the south. This analysis also attributed to sodium, chlorides, and sulfates to an evaporitic terrigenous origin by the molar ratio Sr2+/Ca2+. The thermal spring waters from Guelma geothermal system have a meteoric origin, and all samples are immature with strong mixing between hot and shallow waters with 19–38.5% rate of mixing. The silica geothermometer shows that these thermal waters have a temperature varying from 84 to 122 °C and that the water came from a depth of 2100–3000 m through a fault system that limits the pull-apart basin of Guelma. Potential environmental effluent from thermal spas could pollute in both the irrigation and drinking waters, and which imposes danger on the health of the inhabitants of the region.

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5.
This paper presents a numerical study of high strength concrete microstructure effects on its uniaxial and biaxial compressive strengths. Concrete is first represented as a set of angular aggregates interacting within a cement paste matrix. Then, a yield design kinematic approach is conducted at the mesoscopic scale in order to determine the concrete compressive strength for a given loading path. The proposed model, having a low computational cost, is able to capture the main microstructure effects already observed in literature on concrete uniaxial compressive strength, in particular, the aggregates volume fraction and maximal size effects. Finally, the proposed model also predicts the biaxial failure envelope of high strength concrete and confirms some experimental trends observed in literature.  相似文献   
6.
Three vulnerability index models were applied to assess the pollution potential of Nabeul-Hammamet shallow aquifer, Tunisia: DRASTIC, Pesticide DRASTIC and the Susceptibility Index (SI). An output map layer of each one was obtained using a geographic information system (GIS). The SI layer was overlain with DRASTIC and Pesticide DRASTIC and the percentage areas of agreement and divergence in vulnerability categories were extracted. DRASTIC results suggest the aquifer has mostly low vulnerability. Pesticide DRASTIC and SI identify three vulnerability categories (low, moderate, high) in the aquifer. Published data on current chemical groundwater composition indicate that parts of the aquifer are highly contaminated, revealing that DRASTIC underestimates the risk of pollution; Pesticide DRASTIC and SI reflect this risk better. Agreement in vulnerability categories between the two last models is found for 64 % of the aquifer area. To help manage land-use allocation and prevent Nabeul-Hammamet-aquifer contamination, DRASTIC is not recommended. Pesticide DRASTIC and SI are recommended but for slightly different applications. SI helps in the monitoring of current vulnerable areas and, thus, in contamination prevention. Pesticide DRASTIC could better intervene as a criterion in a multi-criteria analysis to select the best sites for specific on-the-ground practice or future land use.  相似文献   
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8.
The thermal evolution around shear zones is controlled by three major thermal processes: diffusion, advection and shear heating. We present a dimensional analysis to quantify, to first‐order, the relative contributions of these three processes to the thermal evolution around lithospheric‐scale shear zones. We consider 11 parameters that control the kinematics, the three‐dimensional (3‐D) geometry, the initial thermal structure and the average strength of the shear zone. Three dimensionless parameters are presented to quantify the relative contributions of the three thermal processes. We validate the dimensional analysis with 2‐D thermo‐kinematic numerical models. The applicability of the dimensional analysis to any kind of shear zone (i.e. thrust, normal‐slip and strike‐slip shear zones) makes it a useful tool that is complementary to previous numerical and analytical studies. Finally, thrust‐type shear zones are used to illustrate how the three thermal processes control the thermal evolution.  相似文献   
9.
10.
This research aims at optimizing the effects of processing conditions, salts, natural organic materials, and water matrices quality on the effectiveness of the Fe(II)/K2S2O8/hydroxylamine process in the degradation of pararosaniline. Assisting the Fe(II)/KPS (potassium persulfate) treatment with protonated hydroxylamine (H3NOH+) increases the degradation rate of pararosaniline by more than 100%. Radical scavenger experiments show that the SO4●− radical dominates pararosaniline degradation in the Fe(II)/KPS system, whereas OH is the dominant reactive species in the presence of H3NOH+. The disparity in pararosaniline removal effectiveness upon the Fe(II)/KPS/H3NOH+ and Fe(II)/KPS systems gets more significant with increasing reactants doses (i.e., H3NOH+, H2O2, Fe(II)) and solution pH (2–7). Interestingly, H3NOH+ increased the working pH to 6 instead of pH 4 for the Fe(II)/KPS process. Moreover, mineral anions such as Cl, NO3, NO2, and SO4 (up to 10 × 10−3 m ) do not affect the efficiency of the Fe(II)/KPS/H3NOH+ process. In contrast, acid humic decreases the performance of the process by ≈20%. In natural mineral water, treated wastewater, and river water samples, the Fe(II)/KPS/H3NOH+ process maintains higher degradation performance (≈95%), whereas the process efficiency is greatly amortized in seawater. The efficiency of the Fe(II)/KPS process was drastically decreased in the various water matrices.  相似文献   
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