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Alexander G. Sokol Galina A. Palyanova Yury N. Palyanov Anatoly A. Tomilenko Vasiliy N. Melenevsky 《Geochimica et cosmochimica acta》2009,73(19):5820-5834
The composition and potential diamond productivity of C–O–H fluids that could exist in the reduced regions of the Earth’s upper mantle and in the mantles of Uranus and Neptune were studied in experiments at 6.3 GPa and 1400–1600 °C and durations of 15–48 h. Hydrogen fugacity in the fluid phase was controlled by the Mo–MoO2 or Fe–FeO buffers, using a specially modified double-capsule method. The oxygen fugacity in the samples was controlled by adding different amounts of water, stearic acid, anthracene, and docosane to a graphite charge. At high P–T conditions, the degree of decomposition of the heavy hydrocarbons added to the charge was 99.9%. The composition of the fluids coexisting with graphite/diamond in the buffered experiments varied from H2O H2 > CH4 (at fO2 somewhat lower than the “water maximum”) to H2 > CH4 > (C2H4 + C2H6)>C3H8 (in C–H system). In the C–H system the maximum concentrations of major species in the synthesized fluid were: H2 = 79 mol.% and CH4 = 21 mol.%. The composition of the H2-rich fluids, which were synthesized at 6.3 GPa and 1400–1600 °C for the first time, differs considerably from that of the ultra-reduced CH4-rich fluids stable at 2.0–3.5 GPa and 1000–1300 °C. Thermodynamic calculations of the reduced C–O–H fluids at the P–T conditions of the experiments revealed CH4-rich compositions (CH4 H2 > (C2H4 + C2H6)>C3H8), which however drastically differed from the synthesized compositions. The rates of diamond nucleation and growth in the experiments depended on the fluid composition. Diamond crystallization had a maximum intensity in the pure aqueous fluids, while in the H2-rich fluids no diamond formation was observed. Only metastable graphite precipitated from the ultra-reduced fluids. The type of the initial hydrocarbon used for the fluid generation did not affect this process. 相似文献
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Geology of Ore Deposits - Abstract—Gold and silver are capable of forming stable natural compounds with different elements. For gold 36 minerals are known: 10 in the class “Native... 相似文献
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R. G. Kravtsova V. L. Tauson G. A. Palyanova A. S. Makshakov L. A. Pavlova 《Geology of Ore Deposits》2017,59(5):375-390
The first data on native silver from the Rogovik Au–Ag deposit in northeastern Russia are presented. The deposit is situated in central part of the Okhotsk–Chukchi Volcanic Belt (OCVB) in the territory of the Omsukchan Trough, unique in its silver resources. Native silver in the studied ore makes up finely dispersed inclusions no larger than 50 μm in size, which are hosted in quartz; fills microfractures and interstices in association with küstelite, electrum, acanthite, silver sulfosalts and selenides, argyrodite, and pyrite. It has been shown that the chemical composition of native silver, along with its typomorphic features, is a stable indication of the various stages of deposit formation and types of mineralization: gold–silver (Au–Ag), silver–base metal (Ag–Pb), and gold–silver–base metal (Au–Ag–Pb). The specificity of native silver is expressed in the amount of trace elements and their concentrations. In Au–Ag ore, the following trace elements have been established in native silver (wt %): up to 2.72 S, up to 1.86 Au, up to 1.70 Hg, up to 1.75 Sb, and up to 1.01 Se. Native silver in Ag–Pb ore is characterized by the absence of Au, high Hg concentrations (up to 12.62 wt %), and an increase in Sb, Se, and S contents; the appearance of Te, Cu, Zn, and Fe is notable. All previously established trace elements—Hg, Au, Sb, Se, Te, Cu, Zn, Fe, and S—are contained in native silver of Au–Ag–Pb ore. In addition, Pb appears, and silver and gold amalgams are widespread, as well as up to 24.61 wt % Hg and 11.02 wt % Au. Comparison of trace element concentrations in native silver at the Rogovik deposit with the literature data, based on their solubility in solid silver, shows that the content of chalcogenides (S, Se, Te) exceeds saturated concentrations. Possible mechanisms by which elevated concentrations of these elements are achieved in native silver are discussed. It is suggested that the appearance of silver amalgams, which is unusual for Au–Ag mineralization not only in the Omsukchan Trough, but also in OCVB as a whole, is caused by superposition of the younger Dogda–Erikit Hg-bearing belt on the older Ag-bearing Omsukchan Trough. In practice, the results can be used to determine the general line of prospecting and geological exploration at objects of this type. 相似文献
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G. A. Palyanova Yu. L. Mikhlin N. S. Karmanov K. A. Kokh Yu. V. Seryotkin 《Doklady Earth Sciences》2017,474(2):636-640
The forms of Au and Ag occurrence in the crystallization products of melts in the Fe–S–Ag–Au system depending on the proportions of Fe/S and Ag/Au have been studied at (Fe + S)/(Ag + Au) = 0.1. It is shown that the S-rich systems with S/Fe = 2 contain Au–Ag sulfides and Au–Ag alloys. The systems depleted in S with S/Fe = 1 contain only Au–Ag alloys. The results of XPS provide evidence for the sulfide and metallic components of Au and Ag among the crystallization products of melts in the system studied at S/Fe = 2 and a metallic component with S/Fe = 1. According to the data of electron microprobe analysis, the content of “invisible” forms of noble metals in pyrite and pyrrhotite is < 0.024 wt % for Au and <0.030 wt % for Ag; the contents of “invisible” Au and Ag in troilites are 0.040 ± 0.013 wt % Au and 0.079 ± 0.016 wt % Ag. 相似文献
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G.A. Palyanova V.V. Murzin T.V. Zhuravkova D.A. Varlamov 《Russian Geology and Geophysics》2018,59(3):238-256
Gold-bearing albite-amphibole-pyroxene rodingites of the Agardag ultramafic massif (southern Tuva, Russia) are confined to the E-W striking serpentinite crush zone. A zone of gold-bearing nephritoids is localized at the contact of rodingites with serpentinites. Optical and scanning electron microscopy, electron probe microanalysis, and fluorescent, chemical, ICP MS, and X-ray phase analyses were applied to study Au-Cu-Ag mineralization in the serpentinites, rodingites, and nephritoids. Copper sulfides, chalcocite and digenite, are present in the serpentinites, whereas gold and silver minerals are absent. Copper impurity is found in antigorite, Cr-spinel, and magnetite (up to 0.1-0.3 wt.%) as well as parkerite (up to 1.2 wt.%) and millerite (up to 7.9 wt.%). A wide variety of native gold and copper minerals has been identified in the rodingites: (1) cuproauride and tetra-auricupride free of or containing silver impurities (0.1 to 1.2 wt.%); (2) electrum of composition Ag0.50-0.49Au0.50-0.51 (650-660%c) intergrown with AuCu, sometimes as exsolution structures; (3) electrum of composition Ag0.70-0.64Au0.30-0.36 (440-510%c), with inclusions of AuCu and copper sulfides (geerite and yarrowite); (4) high-fineness gold (750-990%c) as veinlets in electrum; and (5) native copper. The composition of copper sulfides varies from chalcocite to covellite. Submicron inclusions of hessite Ag2Te were found in chalcocite. The amount of copper, gold, and silver minerals in the nephritoids is much less than that in the rodingites. The nephritoids contain chalcocite, electrum of composition Ag0.64-0.63Au0.36-0.37 (530-540%c), cuproauride, and tetra-auricupride. The detected hypergene minerals are auricuzite, apachite, brochantite, high-fineness gold, native copper, and cuprite. The sequence of mineral formation in the Agardag ore occurrence has been established on the basis of mineral structures and mineral relations in the rodingites and nephritoids. It is proved that Au-Cu-Ag mineralization formed with the participation of Au- and Ag-bearing chloride-free low-sulfur carbon dioxide alkaline fluids in reducing conditions. 相似文献
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Murzin V. V. Palyanova G. A. Varlamov D. A. Shanina S. N. 《Geology of Ore Deposits》2020,62(3):204-224
Geology of Ore Deposits - The limited literature data on gold-bearing albite–pyroxene rodingites are summarized for the Agardag ultramafic massif in southern Tuva. These data are supplemented... 相似文献
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An experimental study on the origin of ferric and ferrous carbonate-silicate melts, which can be considered as the potential metasomatic oxidizing agents and diamond forming media, was performed in the (Ca,Mg)CO3-SiO2-Al2O3-(Mg,Fe)(Cr,Fe,Ti)O3 system, at 6.3 GPa and 1350–1650 °C. At 1350–1450 °C and ?O2 of FMQ + 2 log units, carbonate–silicate melt, coexisting with Fe3 +-bearing ilmenite, pyrope-almandine and rutile, contained up to 13 wt.% of Fe2O3. An increase in the degree of partial melting was accompanied by decarbonation and melt enrichment with CO2, up to 21 wt.%. At 1550–1650 °C excess CO2 segregated as a separate fluid phase. The restricted solubility of CO2 in the melt indicated that investigated system did not achieve the second critical point at 6.3 GPa. At 1350–1450 °C and ?O2 close to CCO buffer, Fe2 +-bearing carbonate–silicate melt was formed in association with pyrope-almandine and Fe3 +-bearing rutile. It was experimentally shown that CO2-rich ferrous carbonate-silicate melt can be an effective waterless medium for the diamond crystallization. It provides relatively high diamond growth rates (3–5 μm/h) at P,T-conditions, corresponding to the formation of most natural diamonds. 相似文献
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Yu. A. Kalinin G. A. Palyanova N. S. Bortnikov E. A. Naumov K. R. Kovalev 《Doklady Earth Sciences》2018,482(1):1193-1198
The supergene Au in weathering crusts of both the Suzdal and Raygorodok deposits is characterized by enhanced fineness, grain size, crystallinity, and the appearance of botryoidal aggregates of crystals. In the weathering crust of the Suzdal deposit, the exogenous Au is associated primarily with scorodite and carbonates; for Raygorodok, with chalcocite, bornite, hydrocarbonates and Cu hydrosulfates. The difference in the mineral associations of supergene Au at the deposits is determined by the occurrence of various mineral concentrators of Au in the primary endogenous substrate: arsenopyrite and pyrite at the Suzdal deposit and chalcopyrite with pyrite at the Raygorodok deposit. Due to the much greater mobility of Ag in the supergene zone, the weathering crusts are likely to contain submicron microinclusions of Ag minerals beyond the zones of Au concentration. 相似文献