Geomorphic effectiveness: a linear concept in a non‐linear world          下载免费PDF全文

Peyton E. Lisenby  Jacky Croke  Kirstie A. Fryirs 《地球表面变化过程与地形》2018,43(1):4-20

Geomorphic effectiveness has been an influential concept in geomorphology since its introduction by Reds Wolman and John Miller in 1960. It provided a much needed framework to assess the significance of an event by comparing event magnitude to the resultant geomorphic effects. Initially, this concept was applied primarily in river channels, under the linear assumption that geomorphic responses to similarly sized flood events will be consistent. Numerous authors have since attempted to quantify a direct, proportional relationship between event magnitude and different forms of geomorphic response in a variety of geomorphic settings. In doing so, these investigations applied an array of metrics that were difficult to compare across different spatiotemporal scales, and physiographic and geomorphic environments. Critically, the emergence of other geomorphic concepts such as sensitivity, connectivity, thresholds, and recovery has shown that relationships between causes (events) and geomorphic effects (responses) are often complex and non‐linear. This paper disentangles the complex historical development of the geomorphic effectiveness concept and reviews the utility of various metrics for quantifying effectiveness. We propose that total energy (joules) is the most appropriate metric to use for quantifying the magnitude of disturbance events (cause) and volumetric sediment flux associated with landform modification is the most appropriate metric for quantifying geomorphic effects. While both metrics are difficult to quantify, they are the only ones which facilitate comparison across a range of spatiotemporal scales (comparability) in a variety of geomorphic environments (flexibility). The geomorphic effectiveness concept can continue to be useful provided that geomorphologists use flexible and comparable metrics. Today, geomorphologists are better prepared to consider the influence of non‐linear processes on determinations of geomorphic effectiveness, allowing investigators to not only determine if a disturbance event was effective but also to explain why or why not. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

High-pressure single-crystal X-ray diffraction study of jadeite and kosmochlor     

Esther S. Posner  Przemyslaw Dera  Robert T. Downs  John D. Lazarz  Peyton Irmen 《Physics and Chemistry of Minerals》2014,41(9):695-707

The crystal structures of natural jadeite, NaAlSi₂O₆, and synthetic kosmochlor, NaCrSi₂O₆, were studied at room temperature, under hydrostatic conditions, up to pressures of 30.4 (1) and 40.2 (1) GPa, respectively, using single-crystal synchrotron X-ray diffraction. Pressure–volume data have been fit to a third-order Birch–Murnaghan equation of state yielding V ₀ = 402.5 (4) Å³, K ₀ = 136 (3) GPa, and K ₀ ^′  = 3.3 (2) for jadeite and V ₀ = 420.0 (3) Å³, K ₀ = 123 (2) GPa and K ₀ ^′  = 3.61 (9) for kosmochlor. Both phases exhibit anisotropic compression with unit-strain axial ratios of 1.00:1.95:2.09 for jadeite at 30.4 (1) GPa and 1:00:2.15:2.43 for kosmochlor at 40.2 (1) GPa. Analysis of procrystal electron density distribution shows that the coordination of Na changes from 6 to 8 between 9.28 (Origlieri et al. in Am Mineral 88:1025–1032, 2003) and 18.5 (1) GPa in kosmochlor, which is also marked by a decrease in unit-strain anisotropy. Na in jadeite remains six-coordinated at 21.5 (1) GPa. Structure refinements indicate a change in the compression mechanism of kosmochlor at about 31 GPa in both the kinking of SiO₄ tetrahedral chains and rate of tetrahedral compression. Below 31 GPa, the O3–O3–O3 chain extension angle and Si tetrahedral volume in kosmochlor decrease linearly with pressure, whereas above 31 GPa the kinking ceases and the rate of Si tetrahedral compression increases by greater than a factor of two. No evidence of phase transitions was observed over the studied pressure ranges.  相似文献   

‘Out with the Old?’ Why coarse spatial datasets are still useful for catchment‐scale investigations of sediment (dis)connectivity          下载免费PDF全文

Peyton E. Lisenby  Kirstie A. Fryirs 《地球表面变化过程与地形》2017,42(10):1588-1596

The increasing popularity of remote sensing techniques has created numerous options for researchers seeking spatial datasets, especially digital elevation models (DEMs), for geomorphic investigations. This yields an important question regarding what DEM resolution is most appropriate when answering questions of geomorphic significance. The highest possible resolution is not always the best choice for a particular research aim, and DEM resolution should be tailored to fit both the scale of investigation and the simplicity/complexity of modelling processes applied to the dataset. We find that DEM resolution has a significant effect on a simple model of bed load sediment connectivity in the Lockyer Valley, Queensland. We apply a simple bed load transport threshold to catchment DEMs at three different resolutions – 1 m, 5 m, and 25 m. We find that using a 1 m resolution DEM generates numerous disconnections along tributary channel networks that underestimates the sediment contributing area, i.e. effective catchment area (ECA), of seven tributary basins of Lockyer Creek. Utilizing a coarser (lower‐resolution) DEM helps eliminate erroneous disconnections, but can reduce the detail of stream network definition. We find that the 25 m resolution DEM provides the best measure of ECA for comparing sediment connectivity between tributary catchments. The utility of simple models and coarse‐resolution datasets is important for undertaking large, catchment‐scale geomorphic investigations. As catchment‐scale investigations are becoming increasingly entwined with river management and rehabilitation efforts, scientists need not embrace an ‘out with the old’ philosophy. Simple models and coarse‐resolution datasets can help better integrate geomorphic research with management strategies and provide inexpensive and quick first‐order insights into catchment‐scale processes that can help focus future management efforts. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Biogeochemical reactive–diffusive transport of heavy metals in Lake Coeur d’Alene sediments     

S. Sevin engr  Nicolas F. Spycher  Timothy R. Ginn  Rajesh K. Sani  Brent Peyton 《Applied Geochemistry》2007,22(12):2569-2594

Decades of runoff from precious-metal mining operations in the Lake Coeur d’Alene Basin, Idaho, have left the sediments in this lake heavily enriched with toxic metals, most notably Zn, Pb and Cu, together with As. The bioavailability, fate and transport of these metals in the sediments are governed by complex biogeochemical processes. In particular, indigenous microbes are capable of catalyzing reactions that detoxify their environments, and thus constitute an important driving component in the biogeochemical cycling of these metals. Here, the development of a quantitative model to evaluate the transport and fate of Zn, Pb and Cu in Lake Coeur d’Alene sediments is reported. The current focus is on the investigation and understanding of local-scale processes, rather than the larger-scale dynamics of sedimentation and diagenesis, with particular emphasis on metal transport through reductive dissolution of Fe hydroxides. The model includes 1-D inorganic diffusive transport coupled to a biotic reaction network including consortium biodegradation kinetics with multiple terminal electron acceptors and syntrophic consortium biotransformation dynamics of redox front. The model captures the mobilization of metals initially sorbed onto hydrous ferric oxides, through bacterial reduction of Fe(III) near the top of the sediment column, coupled with the precipitation of metal sulfides at depth due to biogenic sulfide production. Key chemical reactions involve the dissolution of ferrihydrite and precipitation of siderite and Fe sulfide. The relative rates of these reactions play an important role in the evolution of the sediment pore-water chemistry, notably pH, and directly depend on the relative activity of Fe and SO₄ reducers. The model captures fairly well the observed trends of increased alkalinity, sulfide, Fe and heavy metal concentrations below the sediment–water interface, together with decreasing terminal electron acceptor concentrations with depth, including the development of anoxic conditions within about a centimeter below the lake bottom. This effort provides insights on important biogeochemical processes affecting the cycling of metals in Lake Coeur d’Alene and similar metal-impacted lacustrine environments.  相似文献   

Evidence for multiple modes of uranium immobilization by an anaerobic bacterium     

Allison E. Ray  John R. Bargar  Alice C. Dohnalkova  Brent M. Peyton  Timothy S. Magnuson 《Geochimica et cosmochimica acta》2011,75(10):2684-6510

Microbial reduction of hexavalent uranium has been studied widely for its potential role in bioremediation and immobilization of soluble U(VI) in contaminated groundwater. More recently, some microorganisms have been examined for their role in immobilization of U(VI) via precipitation of uranyl phosphate minerals mediated by microbial phosphate release, alleviating the requirement for long-term redox control. Here, we investigated the mechanism of U(VI) removal mediated by an environmental isolate, strain UFO1, that is indigenous to the Field Research Center (FRC) in Oak Ridge, TN and has been detected in U(VI)-contaminated sediments. Changes in U(VI) speciation were examined in the presence and absence of the electron-shuttling moiety, anthraquinone-2,6-disulfonate (AQDS). Cell suspensions were capable of nearly complete removal of 100 μM U(VI) from solution within 48 h; U(VI) removal was not dependent on the presence of an exogenous electron donor or AQDS, although AQDS increased the rate of U(VI) removal. X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS) spectroscopic measurements indicated that U(IV) was the predominant oxidation state of uranium in cell suspensions in both the absence and presence of 100 μM AQDS. Interestingly, 17% of the cell-associated precipitates in a U(VI)-treated suspension that lacked AQDS had spectral characteristics consistent with a uranyl phosphate solid phase. The potential involvement of phosphate was consistent with observed increases in soluble phosphate concentrations over time in UFO1 cell suspensions, which suggested phosphate liberation from the cells. TEM-EDS confirmed the presence of uranyl phosphate with a U:P ratio consistent with autunite (1:1). EXAFS analyses further suggested that U(IV) was bound to low-Z neighbors such as C or P, inferred to be present as functional groups on biomass. These results suggest that strain UFO1 has the ability to facilitate U(VI) removal from solution via reductive and phosphate precipitation mechanisms. Both mechanisms offer potential for the remediation of U-contaminated sediments at the FRC or elsewhere.  相似文献   

Sedimentologically significant tributaries: catchment‐scale controls on sediment (dis)connectivity in the Lockyer Valley,SEQ, Australia          下载免费PDF全文

Peyton E. Lisenby  Kirstie A. Fryirs 《地球表面变化过程与地形》2017,42(10):1493-1504

The nature of catchment‐scale sediment (dis)connectivity is the primary influence on sediment delivery to trunk streams and controls the particle size distribution of channel bed sediments. Here, we examine the distribution of major sediment buffers (floodplains, terraces, alluvial fans, trapped tributary fills), barriers (weirs), and effective catchment area (i.e. sediment contributing area) to characterize the potential for coarse sediment (dis)connectivity in 20 tributaries of Lockyer Creek, in the Lockyer Valley, SEQ. We then analyse the distribution of trunk stream sedimentary links to determine how certain tributaries or disconnecting features (buffers and barriers) influence downstream patterns of bed sediment fining along Lockyer Creek. We find that buffering increases downstream in the Lockyer Valley, and that tributary position and shape influence the space available for sediment buffering. Correspondingly, the spatial extent of sediment buffers impacts the distribution of effective catchment area, which influences the sedimentological significance of individual tributaries. Tributary sediment connectivity, the extent of overbank flows (floodwater zones), and weir locations all exert an additional influence on the distribution of sediment links along the trunk stream. These controls are related to the physiographic and climatic setting of the Lockyer Valley, and anthropogenic influences in this system. We conclude that controls on sediment connectivity and bed load sediment characteristics are highly variable between catchments, and that sediment (dis)connectivity merits equal consideration with tributary basin/channel size when determining controls on tributary–trunk stream relationships and channel sediment regime. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献