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The uranium LIII-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg−1 were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U LIII-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   
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Zusammenfassung Nach einer kurzen Diskussion der theoretischen Grundlagen für die Berechnung der Ausbreitung von schädlichen Beimengungen der Luft auf Grund der Gesetzmäßigkeiten der turbulenten Diffusion wird mit Hilfe der vonPasquill angegebenen empirischen Beziehungen zwischen Streuungsmaßen und Quelldistanz die Formel für die Immissionskonzentration am Boden abgeleitet. An Hand einer Reihe von Beispielen wird das Bodenkonzentrationsfeld relativ zu dem Punkt maximaler Immissionskonzentration berechnet, wobei eine feste Schornsteinhöhe von 40 m und eine für mittlere Emittenten zutreffende Auswurfmenge an schädlichen Gasen vorausgesetzt wird. Die Abbildungen zeigen die starke Modifikation des Konzentrationsfeldes durch die meteorologischen Verhältnisse, je nachdem, ob ein stabiler, indifferenter oder labiler Ausbreitungstyp vorliegt.
Summary After a short discussion of the theoretical background for the calculation of the spreading of the noxious pollutants of the air based on the laws of turbulent diffusion a formula is derived for the concentration of the immisison on the ground with help of the empirical relations between the dispersion measures and the distance from the source given byPasquill. In some examples the concentration field at the ground relative to the point of maximum immission is calculated, considering a fixed height of the funnel of 40 m and a quantity of noxious gases as usually found with average emittents. The figures show a strong modification of the concentration field by the meteorological situation according to whether the spreading type is stable, indifferent or unstable.

Résumé On discute tout d'abord brièvement les fondements théoriques permettant de calculer la propagation des pollutions atmosphériques; pour ce faire, on se base sur les lois de la diffusion turbulente. On en tire ensuite une formule de calcul de la concentration des immissions à l'aide des relations empiriques dePasquill, relations existant entre les quantités répandues et la distance de la source. On calcule au moyen d'une série d'exemples le champ des concentrations au sol par rapport au point de concentration maximum; pour ce faire, on admet und chemineé fixe de 40 mètres de hauteur et une quantité de gaz nocifs correspondant à une moyenne de polluants. Les figures montrent la forte modification que subit la répartition des concentrations selon les conditions météorologiques, en d'autres termes si l'on a affaire à un type de propagation stable, indifférent ou instable.


Mit 5 Textabbildungen  相似文献   
5.
Summary Theoretical considerations are put forward for identifying the Dynamic and Static Methods of Diffusion measurements of aerosol particles. On the basic of this equality the Exhaustion Method of Diffusion developed byPollak andMetnieks for the size-frequency resolution of a heterogeneous aerosol by Dynamic Diffusion Methods should be applicable to Static Methods. This hypothesis is tested using a Pollak-Nolan nucleus counter as decay vessel. It is shown that turbulence in the counter is the most serious obstacle against this type of approach to finding the size components of an aerosol. The time involved, the high humidity in the counter and a hypothetical nucleus-free zone are other major difficulties for relatively large Aitken nuclei. It is established, however, that for particles whose diffusion coefficient is of the order of 10–3 cm2 sec–1, the proposed method should be quite workable.  相似文献   
6.
Sperm whales are notable squid-eaters. They feed mainly on medium to large-sized cephalopods at midwater levels and defecate near the surface. This suggests the existence of an upward transport of60Co by sperm whales from the mesopelagic zone (150–1,200 m). To elucidate this squid-whale route for this artificial radionuclide,60Co content was determined in squid and in predator whales captured by commercial whaling. In the Cephalopoda livers60Co levels of 30–500 mBq kg–1 wet were found and in the viscera of Odontoceti (toothed whales) 15–40 mBq kg–1 wet. About 0.3% of80Co ingested was estimated to be retained in a 23-year-old male sperm whale. In the livers of Bryde's whales,60Co levels of 40–80 mBq kg–1 wet were detected, but not in euphausiids and sardines, their possible prey. The level of Co in sperm whales was nearly the same as in Bryde's whales. Specific radioactivity60Co/59Co in mBq µg–1 was several times higher in sperm whale (1.1–1.6) than in cephalopods (0.19–0.77). Eating prey with a high content of60Co in the 1960's may have contributed to the present body burden in sperm whales with a long-life span. However, the origin of60Co in Bryde's whales is unknown.  相似文献   
7.
Near inertial motion excited by wind change in a margin of the Typhoon 9019   总被引:1,自引:0,他引:1  
An excitation of inertial oscillation in the upper layer east of course of Typhoon 9019 was fortuitously observed at three surface buoys deployed during the Ocean Mixed Layer Experiment (OMLET). The observed inertial oscillation was compared with wind fluctuation measured at Ocean Weather Station T (29°N, 135°E) which was placed at the center of a triangle with three vertexes occupied by the respective surface buoys. Inertial oscillation is effectively excited in the mixed layer at the eastern margin of the typhoon by a rapid decrease of wind rather than by prevailing strong wind. It is shown by means of a least square deviation that the inertial oscillation observed in the mixed layer has a period of 23.9 hours shorter than the local inertial period of 24.7 hours. This shorter period suggests that the inertial oscillation has the finite velocities of phase and group as an inertial internal wave. A theoretically obtained ratio of vertical component of group velocity to that of phase velocity, approximately agrees with observed value. The inertial internal wave is excited by fluctuation of divergence with near inertial period in the mixed layer.  相似文献   
8.
In accordance with the similarity between breaking waves and hydraulic jumps, the expressions for estimating wave decay and wave energy dissipation in the surf zone are derived based on the fundamental equations of fluid mechanics. Using the numerical solution of cnoidal wave theory, the various kinematic properties of waves in the surf zone, including the relative wave crest height, wave energy, and radiation stress are discussed. The values calculated with the method proposed in this paper are in good agreement with the experimental data gained by other researchers. The present expressions can be used in the studies of sediment transport on gently sloping beaches, especially on muddy beaches.  相似文献   
9.
This paper reveals that the long-period statistic distribution of the characteristic heights of deep-water waves assumes the lognormal distribution. Thereafter, the largest wave-height which may occur in the service life of coastal structures is derived in this paper.  相似文献   
10.
Based on the 2nd order cnoidal wave theory, the characters of shallow water standing waves and their action on vertical walls are studied in this paper. The theoretical expressions of the wave surface elevation in front of and the wave pressure on the vertical wall are obtained. In order to verify the theoretical results, model tests were made in the State Key Laboratory of Coastal and Offshore Engineering at DUT. For the wave surface elevation in front of the wall and the wave forces on the wall at the moment when the wave surface at the wall surface goes down to the bottom of the wave trough, the calculated results coincide quite well with the experimental results. For the wave forces on the wall at the moment when the wave surface at the wall surface goes up to the top of the wave crest, the theoretical expressions are modified by the experimental results. For the convenience of practical use, calculations are made for the wave conditions which usually occur in enginering practice by use of the inves  相似文献   
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