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Orthopyroxene-rich olivine websterite xenoliths (OWB2) in Palaeogene basanites in East Serbia are mostly composed of tabular low-Al2O3 orthopyroxene (> 70 vol.%, Mg# 85–87) containing tiny Cr spinel inclusions. Orthopyroxene shows a slightly U-shaped primitive mantle-normalized trace element pattern with strong peaks at U and Pb, similar to that of orthopyroxene from normal regional peridotitic mantle. In between the orthopyroxenes are interstitial spaces composed of partially altered olivine (Mg# 85–87), clinopyroxene, Ti-rich spinel, Mg-bearing calcite, K-feldspar, apatite, ilmenite and relicts of a hydrous mineral. Clinopyroxene appears as selvages around orthopyroxene and as coarser euhedral crystals. Trace element patterns of the clinopyroxene selvages resemble those of adjacent orthopyroxene, whereas the coarser ones have flatter and more LREE- and LILE-enriched patterns, similar to that of metasomatic clinopyroxene. The OWB2 xenoliths are interpreted as having formed in two stages. During Stage I orthopyroxene crystallized, along with some spinel, olivine and probably hydrous phase(s). This original OWB2 lithology was a hydrous olivine-bearing orthopyroxenite that crystallised from subduction-related SiO2-saturated, boninite-like magmas. During Stage II the interstitial minerals formed due to infiltration of a low-SiO2, high-CaO and CO2-rich external melt, accompanied by decomposition of original H2O-bearing minerals. The calculated composition of the infiltrating liquid corresponds to a mafic alkaline melt similar to the basanitic host but more enriched in CO2, LREE and LILE. Metasomatism is interpreted in terms of small degree melts related to the Palaeogene mafic alkaline magmatism.  相似文献   
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We present the results of a study on a posteriori error control strategies for finite volume element approximations of second order elliptic differential equations. Finite volume methods ensure local mass conservation and, combined with some up-wind strategies, give monotone solutions. We adapt the local refinement techniques known from the finite element method to the finite volume discretizations of various boundary value problems for steady-state convection–diffusion–reaction equations. In this paper we derive and study a residual type error estimator and illustrate its practical performance on a series of computational tests in 2 and 3 dimensions. Our tests show that the discussed locally conservative approximation methods with a posteriori error control can be used successfully in numerical simulation of fluid flow and transport in porous media.  相似文献   
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Mantle xenoliths from Paleogene basanites of East Serbia were studied using EMP and LA-ICP-MS techniques in order to better understand mantle characteristics in this region. Five different mantle lithologies have been distinguished: a dunite/harzburgite/lherzolite (D/HZ/L) group, clinopyroxene-rich lherzolites (Cpx-L), clinopyroxene megacrysts (Cpx-M), spinel-rich olivine websterites (OWB1) and spinel-poor olivine websterites (OWB2). D/HZ/L xenoliths are the most common and represent normal mantle composed of typical anhydrous spinel peridotites with well equilibrated, unzoned silicates characterized by high Mg# s. Negative correlations between Mg# and TiO2, Al2O3 and CaO wt% in clinopyroxenes (cpx) and orthopyroxenes (opx) and the Cr–Al trend in spinel (sp) suggest depletion via extraction of basaltic melts. The modal composition of D/HZ/L xenoliths and unusual low-Al opx suggest that the lithospheric mantle underneath East Serbia is more depleted than normal European lithosphere. D/HZ/L xenoliths contain numerous pockets and veins filled by Cr-rich cpx, Ti-rich spinel, altered glass, apatite and rare ilmenite and phlogopite. Petrographic observations, supported by major element contents in sp and cpx, and modelling using trace element contents in cpx, indicate that the pockets and veins formed from infiltration of alkaline melts and reaction with peridotite wall-rock causing opx and spinel replacement. The same alkaline melt-related metasomatism gave rise to the Cpx-L and OWB1 mantle xenoliths and Cpx-M xenocrysts. Trace element contents of cpx in these xenoliths show a distinctively concave downwards REE pattern with a HFSE depletion, very similar to cpx megacrysts from the Pannonian Basin and to vein cpx from Eifel. In contrast, the OWB2 xenoliths show evidence of precipitation from subduction-related mafic to ultramafic melts, as inferred from their opx-rich lithology and unusual Cr-rich spinels. They are probably related to subduction magmatism during the Late Cretaceous.Milivoje Jovanovi: deceased in April 2004  相似文献   
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A suite of highly depleted peridotite xenoliths in East Serbian Palaeogene basanites represents the lithospheric mantle beneath the Balkan Peninsula. The xenoliths are harzburgites, clinopyroxene-poor lherzolites and rare dunites. They contain mostly <5 vol.% of modal clinopyroxene and are characterized by high Mg# in silicates (>91), high Cr# in spinel (mostly 0.5–0.7), and by distinctively low Al2O3 contents in orthopyroxene (mostly 1–2 wt.%). They have experienced some mantle metasomatism which has slightly obscured their original composition. Nevertheless, the general characteristics of the xenoliths imply a composition which is significantly more depleted than most non-cratonic sub-continental mantle xenolith suites, as well as orogenic peridotites and abyssal peridotites. Geological and compositional evidence suggests that the xenoliths do not represent Archean mantle. The existence of Proterozoic mantle cannot be entirely excluded, although it is in disagreement with geological evidence. On the other hand, the studied xenoliths are compositionally very similar to peridotites of modern oceanic sub-arc settings. The existence of such a depleted lithospheric mantle segment is also inferred from the presence of rare orthopyroxene-rich xenoliths in the same suite. These are interpreted to have originated as lithospheric precipitates of high-Mg, SiO2-saturated magmas that require a highly depleted mantle source. Such source is typically required by boninitic-like magmas of intraoceanic suprasubduction settings. A proposed geodynamic model to explain these observations involves accretion or underplating of the lower parts of the Tethyan oceanic lithosphere during the Upper Jurassic closure of the eastern branch of the Vardar ocean.  相似文献   
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Numerical simulation of fluid flow in a hydrocarbon reservoir has to account for the presence of wells. The pressure of a grid cell containing a well is different from the average pressure in that cell and different from the bottom-hole pressure for the well [17]. This paper presents a study of grid pressures obtained from the simulation of single phase flow through an isotropic porous medium using different numerical methods. Well equations are proposed for Darcy flow with Galerkin finite elements and mixed finite elements. Furthermore, high velocity (non-Darcy) flow well equations are developed for cell-centered finite difference, Galerkin finite element and mixed finite element techniques.  相似文献   
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