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Daniel D. Riemer Eric C. Apel John J. Orlando Geoffrey S. Tyndall William H. Brune Eric J. Williams William A. Lonneman James D. Neece 《Journal of Atmospheric Chemistry》2008,61(3):227-242
As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to
discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO)
and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day
experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~102 atoms cm−3 and 50 - 30 + 70 ×104 50_{ - 30}^{ + 70} \times {10^4} atoms cm−3. Cl concentration during all the episodes averaged 7.6 - 2.0 + 4.7 ×104 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm−3 and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation
chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in
the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the
Houston, Texas urban area. 相似文献
2.
Flocculation has an important impact on particle trapping in estuarine turbidity maximum (ETM) through associated increases in particle settling velocity. To quantify the importance of the flocculation processes, a size-resolved flocculation model is implemented into an ocean circulation model to simulate fine-grained particle trapping in an ETM. The model resolves the particle size from robust small flocs, about 30 μm, to very large flocs, over 1000 μm. An idealized two-dimensional model study is performed to simulate along-channel variations of suspended sediment concentrations driven by gravitational circulation and tidal currents. The results indicate that the flocculation processes play a key role in generating strong tidal asymmetrical variations in suspended sediment concentration and particle trapping. Comparison with observations suggests that the flocculation model produces realistic characteristics of an ETM. 相似文献
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Minimizing sampling disturbance using a new in situ device 总被引：1，自引：0，他引：1
Laboratory tests on soil samples usually underestimate the in situ dynamic soil stiffness. This has been primarily attributed to sampling disturbance. Studies suggest that among the various mechanisms, changes in the stress condition and the soil structure are the main two factors affecting the behavior of soil specimens obtained by conventional sampling methods. The objective of this paper is to investigate this issue, and to introduce the results of laboratory experiments to study the effect of conventional and newly developed sampling methods on dynamic soil properties. 相似文献
4.
Raith Johann G. Riemer née Schöner Nina Meisel Thomas 《Contributions to Mineralogy and Petrology》2004,147(1):91-109
Tourmaline rocks of previously unclear genesis and spatially associated with W- (Cu)-bearing calc-silicate rocks occur in Palaeoproterozoic supracrustal and felsic intrusive rocks in the Bonya Hills in the eastern Arunta Inlier, central Australia. Tourmalinisation of metapelitic host rocks postdates the peak of regional low-pressure metamorphism (M1/D1, ~500 °C, ~0.2 GPa), and occurred synkinematically between the two main deformation events D1 and D2, coeval with emplacement of Late Strangways (~1.73 Ga) tourmaline-bearing leucogranites and pegmatites. Tourmaline is classified as schorl to dravite in tourmaline–quartz rocks and surrounding tourmaline-rich alteration zones, and as Fe-rich schorl to foitite in the leucogranites. Boron metasomatism resulted in systematic depletion of K, Li, Rb, Cs, Mn and enrichment of B, and in some samples of Na and Ca, in the tourmaline rocks compared to unaltered metasedimentary host rocks. Whole-rock REE concentrations and patterns of unaltered schist, tourmalinised schist and tourmaline–quartz veins—the latter were the zones of influx of the boron-rich hydrothermal fluid—are comparable to those of post-Archaean shales. Thus, the whole-rock REE patterns of these rocks are mostly controlled by the metapelitic precursor. In contrast, REE concentrations of leucogranitic rocks are low (10 times chondritic), and their flat REE patterns with pronounced negative Eu anomalies are typical for fractionated granitic melts coexisting with a fluid phase. REE patterns for tourmalines separated from metapelite-hosted tourmaline–quartz veins and tourmaline-bearing granites are very different from one another but each tourmaline pattern mirrors the REE distribution of its immediate host rock. Tourmalines occurring in tourmaline–quartz veins within tourmalinised metasediments have LREE-enriched (LaN/YbN=6.3–55), shale-like patterns with higher REE (54–108 ppm). In contrast, those formed in evolved leucogranites exhibit flat REE patterns (LaN/YbN=1.0–5.6) with pronounced negative Eu anomalies and are lower in REE (5.6–30 ppm). We therefore conclude that REE concentrations and patterns of tourmaline from the different tourmaline rocks studied are controlled by the host rock and not by the hydrothermal fluid causing boron metasomatism. From the similarity of the REE pattern of separated tourmaline with the host rock, we further conclude that incorporation of REEs in tourmaline is not intrinsically controlled (i.e. by crystal chemical factors). Tourmaline does not preferentially fractionate specific REEs or groups of REEs during crystallisation from evolved boron- and fluid-rich granitic melts or during alteration of clastic metasediments by boron-rich magmatic-hydrothermal fluids.Editorial responsibility: J. Hoefs 相似文献
5.
Concurrent measurements of isoprene (2-methyl-1,3-butadiene) in seawater together with atmospheric concentrations in the Gulf Stream off the Florida coast were made. Florida Straits surface water concentrations of isoprene varied between 9.8 and 50.8 pmol 1−1. Surface water isoprene concentrations showed a positive correlation with measured chlorophyll fluorescence, consistent with the biogenic origin of this non-methane hydrocarbon. Depth profiles showed a maximum in isoprene concentration similar to that of biological productivity as indicated by chlorophyll fluorescence. Daytime atmospheric mixing ratios of isoprene were never above 11 parts-per-trillion (pptv) and eight of eleven samples taken were below the ˜ 5 pptv detection limit. Using an estimated value of the Henry's law constant (KH ˜ 3.1) a supersaturation of surface seawater of 2 to 3 orders of magnitude is estimated.Laboratory grown monocultures of several common phytoplankton species showed production of isoprene. Processes controlling the isoprene concentration in the photic zone of the ocean and the marine boundary layer are discussed. A calculation using a simple time dependent photochemical box model confirmed that isoprene is rapidly consumed by its reaction with the OH radical in the marine atmosphere. 相似文献
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The transport of fine-grained particles in estuarine and coastal waters is influenced by flocculation processes (aggregation and floc breakup). As a consequence, the particle size varies with time in the water column, and can be orders of magnitude larger than those of primary particles. In this study the variations in floc size is simulated using a size-resolved method, which approximates the real size distribution of particles by a range of size bins and solves a mass balance equation for each bin. To predict the size distribution both aggregation and breakup processes are included. The conventional rectilinear aggregation kernel is used which considers both turbulent shear and differential settling. The breakup kernel accounts for the fractal dimension of the flocs. A flocculation simulation is compared to the settling column lab experiments of Winterwerp [1998. A simple model for turbulence induced flocculation of cohesive sediment, Journal of Hydraulic Research, 36, 309–326], and a one-dimensional sediment transport model is verified with the observed variations in floc size and concentration over tidal cycles in a laboratory flume experiment of Bale et al. [2002. Direct observation of the formation and break-up of aggregates in an annular flume using laser reflectance particle sizing. In: Winterwerp, J.C., Kranenburg, C. (Eds.), Fine Sediment Dynamics in the Marine Environment. Elsevier, pp. 189–201]. The numerical simulations compare qualitatively and quantitatively well with the laboratory measurements, and the analysis of the two simulation results indicates that the median floc size can be correlated to the sediment concentration and Kolmogorov microscale. Sensitivity studies are conducted to explore the role of settling velocity and erosion rate. The results are not sensitive towards the formulation of settling velocity, but the parameterization of erosion flux is important. The studies show that for predicting the sediment deposition flux it is crucial to include flocculation processes. 相似文献
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F. Heuze R. Archuleta F. Bonilla S. Day M. Doroudian A. Elgamal S. Gonzales M. Hoehler T. Lai D. Lavallee B. Lawrence P. -C. Liu A. Martin L. Matesic B. Minster R. Mellors D. Oglesby S. Park M. Riemer J. Steidl F. Vernon M. Vucetic J. Wagoner Z. Yang 《Soil Dynamics and Earthquake Engineering》2004,24(3):199-223
The Campus Earthquake Program (CEP) of the University of California (UC) started in March 1996, and involved a partnership among seven campuses of the UC—Berkeley, Davis, Los Angeles, Riverside, San Diego, Santa Barbara, Santa Cruz—and the Lawrence Livermore National Laboratory (LLNL). The aim of the CEP was to provide University campuses with site-specific assessments of their earthquake strong motion exposure, to complement estimates they obtain from consultants according to the state-of-the-practice (SOP), i.e. Building Codes (UBC 97, IBC 2000), and Probabilistic Seismic Hazard Analysis (PSHA). The Building Codes are highly simplified tools, while the more sophisticated PSHA is still somewhat generic in its approach because it usually draws from many earthquakes not necessarily related to the faults threatening the site under study.Between 1996 and 2001, the site-specific studies focused on three campuses: Riverside, San Diego, and Santa Barbara. Each campus selected 1–3 sites to demonstrate the methods and procedures used by the CEP: Rivera Library and Parking Lots (PL) 13 and 16 at UCR, Thornton Hospital, the Cancer Center, and PL 601 at UCSD, and Engineering I building at UCSB. The project provided an estimate of strong ground motions at each selected site, for selected earthquake scenarios. These estimates were obtained by using an integrated geological, seismological, geophysical, and geotechnical approach, that brings together the capabilities of campus and laboratory personnel. Most of the site-specific results are also applicable to risk evaluation of other sites on the respective campuses.The CEP studies have provided a critical assessment of whether existing campus seismic design bases are appropriate. Generally speaking, the current assumptions are not acknowledging the severity of the majority of expected motions. Eventually, both the results from the SOP and from the CEP should be analyzed, to arrive at decisions concerning the design-basis for buildings on UC campuses. 相似文献
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Endorheic basins, filled by a rhythmic stratification of fluvio-lacustrine sediments, are useful archives for studying the interaction of palaeoenvironment and prehistoric development. Archaeological evidence indicates an occupational maximum during the Early to Mid-Holocene humid phase that can be linked to geochronological dates. A wadi has cut these sediments and a wadi profile of about 6 m was sampled for luminescence dating.
Palaeodose estimates are based on single aliquot measurements of the sand-sized quartz fraction using the regenerative dose technique. The comparison of equivalent dose results from different aliquot sizes (<100 and >1000 grains) provides interesting insights into heterogeneous degrees of bleaching. Problems arising from substantial variations in environmental dose rates of such heterogeneous sediments are discussed.
The luminescence ages indicate two major phases of deposition, both of Holocene age. The lower 2 m of sediments were deposited about 9400 years ago. The sedimentation of the upper 2 m started about 7200 and terminated around 6300 years ago. Radiocarbon ages of charcoals contained in the upper part of the section disagree with that OSL dating. This discrepancy is explained by re-deposition of the charcoal fragments. 相似文献
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