Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters   总被引：2，自引：0，他引：2  

Jacinta Enzweiler  Maria Aparecida Vendemiatto 《Geostandards and Geoanalytical Research》2004,28(1):103-112

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.  相似文献   

Using a regional numerical weather prediction model for GNSS positioning over Brazil     

Daniele Barroca Marra Alves  Luiz Fernando Sapucci  Haroldo Antonio Marques  Eniuce Menezes de Souza  Tayná Aparecida Ferreira Gouveia  Jackes Akira Magário 《GPS Solutions》2016,20(4):677-685

The global navigation satellite system (GNSS) can provide centimeter positioning accuracy at low costs. However, in order to obtain the desired high accuracy, it is necessary to use high-quality atmospheric models. We focus on the troposphere, which is an important topic of research in Brazil where the tropospheric characteristics are unique, both spatially and temporally. There are dry regions, which lie mainly in the central part of the country. However, the most interesting area for the investigation of tropospheric models is the wet region which is located in the Amazon forest. This region substantially affects the variability of humidity over other regions of Brazil. It provides a large quantity of water vapor through the humidity convergence zone, especially for the southeast region. The interconnection and large fluxes of water vapor can generate serious deficiencies in tropospheric modeling. The CPTEC/INPE (Center for Weather Forecasting and Climate Studies/Brazilian Institute for Space Research) has been providing since July 2012 a numerical weather prediction (NWP) model for South America, known as Eta. It has yield excellent results in weather prediction but has not been used in GNSS positioning. This NWP model was evaluated in precise point positioning (PPP) and network-based positioning. Concerning PPP, the best positioning results were obtained for the station SAGA, located in Amazon region. Using the NWP model, the 3D RMS are less than 10 cm for all 24 h of data, whereas the values reach approximately 60 cm for the Hopfield model. For network-based positioning, the best results were obtained mainly when the tropospheric characteristics are critical, in which case an improvement of up to 7.2 % was obtained in 3D RMS using NWP models.  相似文献   

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

Relationship between visible and heritable chromosome damage in trout cells and embryos     

R.M. Kocan  D.B. Powell  V.M. Liguori 《Marine environmental research》1985,17(2-4)

The disruption of chromosome segregation which is detected visually by the anaphase aberration (aa) test suggests that unequal amounts of DNA are distributed to daughter cells and possibly to subsequent cell generations. To investigate this possibility trout cell cultures and trout embryos (blastodisc) were exposed to benzo[a]pyrene (B[a]P) and the nitrosamide, MNNG, respectively. They were then examined by flow cytometry to determine if anaphase damage resulted in unequal DNA distribution to daughter cells. Both B[a]P and MNNG produced a significant increase (P < 0·01) in aa in cultured cells after 48 h exposure. These values returned to normal by 10 days in the absence of the genotoxic agents, except for the highest concentration (0·5 μg/ml MNNG), which showed only a 50% recovery by that time. Likewise, the coefficient of variation (CV) of nuclear DNA content of the cells also rose significantly after treatment and remained elevated for as long as 14 days following exposure. Experiments with rainbow trout embryos also showed a significant increase in both aa and CV following exposure to MNNG. Flow cytometric analysis of DNA content of trout cells and embryos following exposure to mutagens showed an unequal distribution of DNA that was transmissible through several cell generations. These findings indicate that visible anaphase aberrations could predict heritable genetic defects such as those associated with aneuploidy.  相似文献   

Probabilistic radar rainfall nowcasts using empirical and theoretical uncertainty models          下载免费PDF全文

Qiang Dai  Miguel A. Rico‐Ramirez  Dawei Han  Tanvir Islam  Sara Liguori 《水文研究》2015,29(1):66-79

Weather radar has a potential to provide accurate short‐term (0–3 h) forecasts of rainfall (i.e. radar nowcasts), which are of great importance in warnings and risk management for hydro‐meteorological events. However, radar nowcasts are affected by large uncertainties, which are not only linked to limitations in the forecast method but also because of errors in the radar rainfall measurement. The probabilistic quantitative precipitation nowcasting approach attempts to quantify these uncertainties by delivering the forecasts in a probabilistic form. This study implements two forms of probabilistic quantitative precipitation nowcasting for a hilly area in the south of Manchester, namely, the theoretically based scheme [ensemble rainfall forecasts (ERF)‐TN] and the empirically based scheme (ERF‐EM), and explores which one exhibits higher predictive skill. The ERF‐TN scheme generates ensemble forecasts of rainfall in which each ensemble member is determined by the stochastic realisation of a theoretical noise component. The so‐called ERF‐EM scheme proposed and applied for the first time in this study, aims to use an empirically based error model to measure and quantify the combined effect of all the error sources in the radar rainfall forecasts. The essence of the error model is formulated into an empirical relation between the radar rainfall forecasts and the corresponding ‘ground truth’ represented by the rainfall field from rain gauges measurements. The ensemble members generated by the two schemes have been compared with the rain gauge rainfall. The hit rate and the false alarm rate statistics have been computed and combined into relative operating characteristic curves. The comparison of the performance scores for the two schemes shows that the ERF‐EM achieves better performance than the ERF‐TN at 1‐h lead time. The predictive skills of both schemes are almost identical when the lead time increases to 2 h. In addition, the relation between uncertainty in the radar rainfall forecasts and lead time is also investigated by computing the dispersion of the generated ensemble members. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Fluid-inclusion microthermometry and the Zr-in-rutile thermometer for hydrothermal rutile     

Alexandre Raphael Cabral  Francisco Javier Rios  Lucilia Aparecida Ramos de Oliveira  Francisco Robério de Abreu  Bernd Lehmann  Thomas Zack  František Laufek 《International Journal of Earth Sciences》2015,104(2):513-519

  相似文献   

Adsorption of methylene blue and crystal violet on low-cost adsorbent: waste fruits of <Emphasis Type="Italic">Rapanea ferruginea</Emphasis> (ethanol-treated and H<Subscript>2</Subscript>SO<Subscript>4</Subscript>-treated)     

Tamiris Chahm  Bruna Aparecida Martins  Clovis Antonio Rodrigues 《Environmental Earth Sciences》2018,77(13):508

This study assesses the ability of two low-cost adsorbents made from waste of Rapanea ferruginea treated with ethanol (WRf) and its H₂SO₄-treated analog (WRf/H₂SO₄) for the removal of two cationic dyes methylene blue (MB) and crystal violet (CV) from aqueous solutions. The adsorbent was characterized by scanning electron microscopy, Fourier transform infrared spectrometry, thermogravimetric analysis, point of zero charge (pH_pzc), specific surface, and functional groups. The adsorption of dye onto the adsorbents was studied as a function of pH solution (2–12), contact time (up to 120 min) and initial concentration (20–120 mg/L), and temperature (25, 35, and 55 °C). The influence of these parameters on adsorption capacity was studied using the batch process. The response surface methodology (RSM) was used in the experimental design, modeling of the process, and optimizing of the variables and was optimized by the response involving Box–Behnken factorial design (15 runs). The results show that the data correlated well with the Sips isotherm. The maximum adsorption capacities of MB and CV onto WRf were found to be 69 and 106 mg/g, and onto WRf/H₂SO₄, the adsorption capacities were 33 and 125 mg/g, respectively. The kinetic data revealed that adsorption of cationic dyes onto the adsorbents closely follows the pseudo-second-order kinetic model. Regression analysis showed good fit of the experimental data to the second-order polynomial model, with coefficient of determination (R²) values for MB (R²?=?0.9685) and MB (R²?=?0.9832) for WRf and CV (R²?=?0.9685) and CV (R²?=?0.9832) for WRf/H₂SO₄ indicated that regression analysis is able to give a good prediction of response for the adsorption process in the range studied. The results revealed that waste from R. ferruginea is potentially an efficient and low-cost adsorbent for adsorption of MB and CV.  相似文献   

The causes of land-use and land-cover change: moving beyond the myths   总被引：39，自引：0，他引：39  

Eric F. Lambin  B. L. Turner  Helmut J. Geist  Samuel B. Agbola  Arild Angelsen  John W. Bruce  Oliver T. Coomes  Rodolfo Dirzo  Günther Fischer  Carl Folke  P. S. George  Katherine Homewood  Jacques Imbernon  Rik Leemans  Xiubin Li  Emilio F. Moran  Michael Mortimore  P. S. Ramakrishnan  John F. Richards  Helle Sknes  Will Steffen  Glenn D. Stone  Uno Svedin  Tom A. Veldkamp  Coleen Vogel  Jianchu Xu 《Global Environmental Change》2001,11(4)

Common understanding of the causes of land-use and land-cover change is dominated by simplifications which, in turn, underlie many environment-development policies. This article tracks some of the major myths on driving forces of land-cover change and proposes alternative pathways of change that are better supported by case study evidence. Cases reviewed support the conclusion that neither population nor poverty alone constitute the sole and major underlying causes of land-cover change worldwide. Rather, peoples’ responses to economic opportunities, as mediated by institutional factors, drive land-cover changes. Opportunities and constraints for new land uses are created by local as well as national markets and policies. Global forces become the main determinants of land-use change, as they amplify or attenuate local factors.  相似文献   

Comparing quantitative precipitation forecast methods for prediction of sewer flows in a small urban area     

Alma Schellart  Sara Liguori  Stefan Krämer  Adrian Saul  Miguel A. Rico-Ramirez 《水文科学杂志》2014,59(7):1418-1436

Abstract

Due to the relatively small spatial scale, as well as rapid response, of urban drainage systems, the use of quantitative rainfall forecasts for providing quantitative flow and depth predictions is a challenging task. Such predictions are important when consideration is given to urban pluvial flooding and receiving water quality, and it is worthwhile to investigate the potential for improved forecasting. In this study, three quantitative precipitation forecast methods of increasing complexity were compared and used to create quantitative forecasts of sewer flows 0–3 h ahead in the centre of a small town in the north of England. The HyRaTrac radar nowcast model was employed, as well as two different versions of the more complex STEPS model. The STEPS model was used as a deterministic nowcasting system, and was also blended with the Numerical Weather Prediction (NWP) model MM5 to investigate the potential of increasing forecast lead-times (LTs) using high-resolution NWP. Predictive LTs between 15 and 90 min gave acceptable results, but were a function of the event type. It was concluded that higher resolution rainfall estimation as well as nowcasts are needed for prediction of both local pluvial flooding and combined sewer overflow spill events.