新西兰奥塔戈东部马可罗斯地区石墨片岩中变质...     

Mcke.  SA 王文珍 《世界地质》1992,11(1):108-117

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Kinetics of peptide hydrolysis and amino acid decomposition at high temperature     

Qian Y  Engel MH  Macko SA  Carpenter S  Deming JW 《Geochimica et cosmochimica acta》1993,57(14):3281-3293

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.  相似文献   

H2 in interstellar and extragalactic ices: infrared characteristics, ultraviolet production, and implications     

Sandford SA  Allamandola LJ 《The Astrophysical journal》1993,409(2):L65-L68

H2 is the most abundant molecule in the universe. We demonstrate that this molecule may be an important component of interstellar and possibly intergalactic ices, both because it can be formed in situ, within the ices, and because gas phase H2 can freeze out onto dust grains in some astrophysical environments. The condensation-sublimation and infrared spectral properties of ices containing H2 are presented. We show that solid H2 in H20-rich ices can be detected by an infrared absorption band at 4137 cm-1 (2.417 micrometers). The surface binding energy of H2 to H2O ice was measured to the delta Hs/k = 555 +/- 35 K. Surface binding energies can be used to calculate the residence times of H2 on grain surfaces as a function of temperature. Some of the implications of these results are considered.  相似文献   

The condensation and vaporization behavior of ices containing SO2, H2S, and CO2: implications for Io     

Sandford SA  Allamandola LJ 《Icarus》1993,106(2):478-488

In an extension of previously reported work on ices containing CO, CO2, H2O, CH3OH, NH3, and H2, measurements of the physical and infrared spectral properties of ices containing molecules relevant to Jupiter's moon Io are presented. These include studies on ice systems containing SO2, H2S, and CO2. The condensation and sublimation behaviors of each ice system and surface binding energies of their components are discussed. The surface binding energies can be used to calculate the residence times of the molecules on a surface as a function of temperature and thus represent important parameters for any calculation that attempts to model the transport of these molecules on Io's surface. The derived values indicate that SO2 frosts on Io are likely to anneal rapidly, resulting in less fluffy, "glassy" ices and that H2S can be trapped in the SO2 ices of Io during night-time hours provided that SO2 deposition rates are on the order of 5 micrometers/hr or larger.  相似文献   

非饱和土中水平入渗方程显式求解     

李纪伟  林法力  韦昌富  汪华斌  陈盼  朱赞成  刘子振 《岩土力学》2021,(1):203-210

在求解非饱和态土中水分入渗问题时,水力函数是体积含水率或者吸力的函数,致使其控制方程呈现出强非线性的特征,进而使得其求解变得十分困难。基于水分在土体介质中流动耗时取极值路径的选择这一假定,引入时间泛函,基于变分法原理将水平入渗问题转化为泛函极值问题。通过求解Euler–Lagrange方程,结合边界条件,得到非线性瞬态水平入渗问题的显式解析解。结合Brooks-Corey型水力函数,显式地求解出该类型非饱和态土的体积含水率发展分布规律。通过计算4种不同类型土体的水平入渗规律,将求解结果与已有结果以及数值结果进行对比,验证了该方法的有效性。结果表明:体积含水率分布与位置距离和湿润峰距离比值呈幂函数关系,指数取决于土-水特征曲线的形状参数;初始条件与边界条件会对体积含水率分布造成不同程度的影响。  相似文献   

新西兰东奥塔戈麦克里斯石墨片岩中变质金钨矿床的物质来源和成矿作用     

Mcke.  SA 阎卫东 《国外地质与勘测》1990,(2):17-25

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中澳大利亚Arunta地块上地壳波速变化的层析成象重建     

Gree.  SA 林锦南 《世界地震译丛》1991,(5):23-28

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中国多重ScS震相衰减和走时的区域变化     

Sipk.  SA 吴忠良 《世界地震译丛》1994,(5):10-23,78

用中国数字地震台网（ＣＤＳＮ）记录到的来自中国周边地区中深源地震的长周期多重ＳｃＳ波形，使用频域分析（相位归一和叠加）及时域分析（波形反演）技术，估算了多重ＳｃＳ的衰减算子和走时差。理论计算和使用合成数据进行的数字实验表明，在大陆地区，频域分析可以得到比时域分析更稳定的关于整个地幔衰减（ＱＳｃＳ）的结果，而时域分析对于整个地幔走时（ＴＳｃＳ）的模拟效果更好。将这两者结合起来，可以得到关于大陆传播路  相似文献   

巴基斯坦卡拉奇—海得拉巴区域地震危险性预测     

Khan  SA 《地震研究》1995,18(3):306-316

本文讨论了巴基斯坦的地震构造，潜在震源和历史与现代地震，并在此基础上使用确定性和概率性两种方法计算了各发展断层５０年内最大可能的地震在卡拉奇和海得拉巴两城市将引起的地面峰值加速度以及５０年内超越概率为１４％的等加速度区划图。  相似文献   

Levels of organochlorine pesticide residues in some organs of the Ganges perch, Lates calcarifer, from the Ganges-Brahmaputra-Meghna Estuary, Bangladesh     

Jabber SA  Khan YS  Rahman MS 《Marine pollution bulletin》2001,42(12):1291-1296

Levels of organochlorine pesticide residues (p,p′ DDT, DDD, DDE, Aldrin, Dieldrin, Lindane, Heptachlor and BHC) were analysed in the dry and wet seasons in four organs (muscle, liver, gut and egg samples) of Ganges Perch, Lates calcarifer, collected during October–November–December, 1996 and May–June–July, 1997 from the Ganges–Brahmaputtra–Meghna estuary. The residues were analysed by using gas-chromatography (GC) in electron capture detector (ECD) mode and were verified by thin layer chromatography (TLC). Among the four organs analysed, the residues were found in the order egg > gut > muscle > liver. The pesticide residues were found in the order ∑DDT > Heptachlor >Dieldrin > Aldrin. Higher levels of residues were found during the dry season due to high lipid content in fishes. A positive correlation was observed between the pesticide residues (∑DDT and ∑OCs) and lipid contents of fish, and the correlation was found to be linear. The concentrations of pesticide residues in muscle, liver and gut were below the FAO/WHO (1993) recommended permissible limit except in eggs.  相似文献