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Zebra dolomitization as a result of focused fluid flow in the Rocky Mountains Fold and Thrust Belt, Canada 总被引：4，自引：0，他引：4
VEERLE VANDEGINSTE RUDY SWENNEN SARAH A. GLEESON† ROB M. ELLAM‡ KIRK OSADETZ§ FRANÇOIS ROURE¶ 《Sedimentology》2005,52(5):1067-1095
Discordant zebra dolomite bodies occur locally in the Middle Cambrian Cathedral and Eldon Formations of the Main Ranges of the Canadian Rocky Mountains Fold and Thrust Belt. They are characterized by alternating dark grey (a) and white (b) bands, forming an ‘abba’ diagenetic cyclicity. These bands developed parallel to both bedding and cleavage. Dark grey (a) bands consist of fine (< 300 μm) non-planar crystalline impure dolomite. The white (b) bands are composed of coarse (up to several millimetres) milky-white pure saddle dolomites (b1) which are often covered by pore-lining zoned dolomite (b2). The b phases often possess a saddle-shaped morphology. In contrast to the replacement origin of the a dolomite, the zoned b2 dolomite rims are interpreted as a cement formed in open cavities. The b1 dolomite is interpreted as the result of recrystallization with diagenetic leaching of non-carbonate components. All the zebra dolomites studied are (nearly) stoichiometric and are characterized by enriched Na and depleted Sr concentrations. Fe and Mn concentrations in these dolomites differ depending on the sample locality. Fluid inclusion data indicate that the dolomites formed from relatively hot (TH = 130–200 °C), saline (20–23 wt% CaCl2 eq.) fluids. A diagenetic high temperature origin is also supported by depleted δ18O values (−20 to −14‰ VPDB). A contribution of 87Sr-enriched fluids is reflected in the 87Sr/86Sr values (0·7091–0·7123). Zebra dolomite development is explained by focused fluid flow, which exploited areas of structural weaknesses (e.g. basin-platform, rim areas, faults, etc.). Expulsion of hot basinal brines in a tectonically active regime generated overpressures, which explains the development of secondary porosity during zebra dolomitization as well as the intra-zebra fracturing at decimetre to micrometre scale. 相似文献
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The effect of peak shifts on the performance of a Kalman filter multicomponent analysis algorithm hasbeen investigated.A series of Gaussian test systems were employed to characterize the concentrationestimation errors and the morphology of the on-line residuals(the innovations sequence).Both forwardand reverse filters were used in the generation of the innovations sequences.It was found that thedifference between the forward and reverse innovations sequences gave an accurate indication of thedirection and magnitude of the peak shift.A series of overlapped two-component systems were alsoinvestigated.Again,a correlation between the difference innovations and the degree of the responseshift was observed.The behavior of the Katman filter in fitting the shifted fluorescence emissionspectrum of benzo[a]pyrene was also examined.The response for henzo[a]pyrene in cyclohexanesolution was compared to that obtained on the surface of a reversed phase thin layer chromatographyplate.A red shift of 4 nm was detected for the surface spectrum by observing the difference innovationssequence.This approach holds promise for correction of response shifts in multicomponent systems. 相似文献
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FERRY JOHN M.; RUMBLE DOUGLAS III; WING BOSWELL A.; PENNISTON-DORLAND SARAH C. 《Journal of Petrology》2005,46(8):1725-1746
Progress () of the infiltration-driven reaction, 4olivine +5CO2 + H2O = talc + 5magnesite, that occurred during Barrovianregional metamorphism, varies at the cm-scale by a factor of3·5 within an 3 m3 volume of rock. Mineral and stableisotope compositions record that XCO2, 18Ofluid, and 13Cfluidwere uniform within error of measurement in the same rock volume.The conventional interpretation of small-scale variations in in terms of channelized fluid flow cannot explain the uniformityin fluid composition. Small-scale variations in resulted insteadbecause (a) reactant olivine was a solid solution, (b) initiallythere were small-scale variations in the amount and compositionof olivine, and (c) fluid composition was completely homogenizedover the same scale by diffusion–dispersion during infiltrationand subsequent reaction. Assuming isochemical reaction, spatialvariations in image variations in the (Mg + Fe)/Si of the parentrock rather than the geometry of metamorphic fluid flow. Ifinfiltration-driven reactions involve minerals fixed in composition,on the other hand, spatial variations in do directly imagefluid flow paths. The geometry of fluid flow can never be determinedfrom geochemical tracers over a distance smaller than the oneover which fluid composition is completely homogenized by diffusion–dispersion. KEY WORDS: Alpine Barrovian metamorphism; diffusion; metamorphic fluid composition; metamorphic fluid flow; reaction progress 相似文献
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SARAH M. SPRINGMAN LUKAS U. ARENSON YUKO YAMAMOTO HANSRUEDI MAURER ANDREW KOS THOMAS BUCHLI GUIDO DERUNGS 《Geografiska Annaler: Series A, Physical Geography》2012,94(2):215-243
This paper recognizes the contribution of Professor Wilfried Haeberli for his inspiration and leadership in the field of permafrost science and his generous encouragement, both direct and indirect, to the ETH Researchers who have, through him, endeavoured to contribute to this fascinating research area. The multidisciplinary investigations described in this paper have focused on three rock glaciers, Muragl, Murtèl‐Corvatsch and Furggwanghorn, all of which have been subject to a varying degree of prior study, and which are continuing to attract new generations of researchers to understand and explain the processes and predict future behaviour. This paper marks a stage at which it is possible to summarize some advances in the state of the art and associated innovations that can be attributed to early motivation by Wilfried Haeberli and offers a tribute as well as gratitude for his ongoing feedback and advice. Some thoughts on the development of thermokarst due to water ponding and flow, and a conceptual model of geotechnical mechanisms that aim to explain some aspects of rock glacier kinematics, are also introduced. 相似文献
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SARAH T. GILLE 《Marine Geodesy》2013,36(1-2):47-57
The Kolmogorov-Smirnov (K-S) test is used to compare probability density functions (PDFs) of geostrophic velocities measured by the TOPEX, Poseidon, and Jason altimeters. Velocity PDFs are computed in 2.5° by 2.5° boxes for regions equatorward of 60° latitude. Although velocities measured by the TOPEX and Jason altimeters can differ, on the basis of the K-S test the velocities are statistically equivalent during the ～200 day period when the satellites followed the same orbit. Full records from TOPEX, Poseidon, and Jason show less agreement, which can be attributed to temporal variability in ocean surface velocities and differing levels of measurement noise. 相似文献
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Research on the Upper Campanian (Upper Cretaceous) Negev phosphorites (Mishash Formation), based on microprobe analyses, Fourier Transform Infrared spectroscopy, wet chemistry, microtextural (Scanning Electron Microscopy) studies and mineralogical analyses, together with quantified rates of sedimentation and P accumulation, enables the chemistry of these rocks to be better constrained across the Negev area and allows their suitability for the manufacture of P fertilizers to be better determined. Two phosphorite facies are differentiated: (i) a pristine phosphorite facies of low P content, more typical of basinal sections and (ii) a reworked, granular phosphorite facies commonly enriched in P, found predominantly near palaeo‐highs and forming most of the economic phosphates. The distribution of F/P2O5, CO2/F, U(IV), Cd, Zn and other trace metals (Mo, Ni, Cr, Cu, V and Y), rare‐earth elements concentration, Ce and Eu anomalies and heavy rare earth elements enrichment, are controlled by these two facies. F/P2O5 in carbonate‐fluorapatite is much lower (0·090 to 0·107) in the pristine than in the reworked facies (0·107 to 0·120); in addition, the lower F/P2O5 in the pristine facies is coupled with: (i) higher Cd, Zn, Mo, Ni, Cr, Cu and V concentrations; (ii) a considerably reduced (< 10%) U(IV) fraction of total U; (iii) lower rare earth elements/P2O5 and Y/P2O5 ratios; (iv) less negative Ce and Eu anomalies and lower heavy rare earth elements (Lu/La) enrichment; (v) an increase in Fe‐rich smectites in the clay fraction; and (vi) presence of OH in the carbonate‐fluorapatite structure. Sedimentary reworking of previously formed pristine phosphate, together with its redeposition near structural highs in more oxic bottom conditions, results in considerable diagenetic changes in the chemistry of the phosphorites, making them more suitable for economic exploitation. The results presented here provide geochemical criteria for identifying pristine phosphate in other phosphorite sequences and may help to better locate phosphate strata chemically suitable for the phosphate industry elsewhere. 相似文献
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The increase in the number of mountain bikers world‐wide has raised a number of issues associated with impacts and appropriate management strategies. Studies in the USA, UK and New Zealand have indicated a growing concern with environmental impacts, demonstrated attitudes of other recreationalists to mountain bikers and identified a number of management issues. This article presents the findings from field research conducted during the southern summer of 1997/8. The research was carried out in association with the Palmerston North City Council (PNCC) and the Manawatu Mountain Bike Club. The aims of the research were to investigate the demographics of mountain bikers and related management issues. Key findings of the field research were that: access to mountain biking opportunities was a problem; information provision was poor; there was conflict between user groups; there was a lack of agreement on whether there should be dedicated or multi‐use tracks. The article discusses how the research findings have been used to assist in the creation of an outdoor recreation and tourism strategy for Palmerston North. A model for managing recreation /tourism activities is also suggested. 相似文献