Marine-derived dolomite in the shallowly buried temperate Port Campbell Limestone (Miocene), Otway Basin, Australia     

STELIOS NICOLAIDES 《Sedimentology》1997,44(1):143-157

The Miocene Port Campbell Limestone in the Otway Basin (Port Campbell Embayment), south-eastern Australia, is a shallowly buried (<350 m), temperate carbonate grainstone which consists primarily of benthonic foraminifera, bryozoans, brachiopods, echinoids and planktonic foraminifera. Volumetrically insignificant calcite cements include scalenohedral, blocky and syntaxial overgrowths. Dolomite is present in variable amounts (1–25%), scattered throughout the unit as euhedral rhombs, usually comprising <2% of the whole rock volume. The dolomite post-dates the calcite cements and is mainly an interparticle cement with crystal size varying between 10 and 150 μm (mean 50 μm). Under cathodoluminescence the dolomite rhombs have a dull core and a nonluminescent outer rim. The dolomite is nonstoichiometric, Ca-rich (Ca_54–62Mg_38–46), with high trace element concentrations. The Mn concentrations range from 0 to 310 p.p.m. in the crystal cores (mean 140 p.p.m.) and 80–240 p.p.m. in the crystal rims (mean 140 p.p.m.). The Fe concentrations increase from the crystal cores (range 640–5690 p.p.m.; mean 2030 p.p.m.) to the crystal rims (range 2840–9440 p.p.m.; mean 6040 p.p.m.), whereas the Sr concentrations decrease from the crystal cores (range 690–1510 p.p.m.; mean 1280 p.p.m.) to the crystal rims (620–1240 p.p.m.; mean 930 p.p.m.). The δ₁₃C_PDB values of the dolomite range between +2.5 and +2.6%, whereas the δ₁₈O_PDB values range from +0.3% to+0.6%. This dolomite occurrence supports the idea that marine or near-marine dolomite can form not only syndepositionally, but also in the shallow subsurface of temperate units, soon after sediment deposition, under reducing conditions. The fine-grained, low-permeability nature of the Port Campbell Limestone contributed to the reducing conditions at shallow depth, the high trace element concentrations of the dolomite (especially in Fe) and the near marine composition of the dolomitizing fluids, as large volumes of meteoric water were inhibited.  相似文献   

Origin and modification of Cambrian dolomites (Red Heart Dolomite and Arthur Creek Formation), Georgina Basin, central Australia     

STELIOS NICOLAIDES 《Sedimentology》1995,42(2):249-266

The Early to Middle Cambrian Red Heart Dolomite and lower Arthur Creek Formation of the southern portion of the Georgina Basin, Australia, is an entirely dolomitized succession of shallow-water evaporitic mudflat and deeper-water subtidal lithologies. Three types of dolomite have been identified and are interpreted as: (1) syndepositional dolomite; (2) regional replacement dolomite; and (3) void-filling dolomite (cement). Syndepositional dolomite, derived from saline pore fluids developed in a sabkha environment, is a minor dolomite type with very fine crystal mosaics and has a mottled, non-zoned cathodoluminescence. The widespread regional replacement dolomite ranges from fine- to medium-crystalline forming mainly planar-s and non-planar-a crystal mosaics, and displays blotchy, mottled, non-zoned cathodoluminescence. Void-filling dolomite commonly forms planar-s to planar-e, medium to very coarse crystal mosaics. Rare non-planar-c, very coarsely crystalline saddle dolomite also exists. Void-filling dolomite has a successively zoned cathodoluminescence pattern from non-, to brightly, to dully luminescent. Geochemically, the syndepositional dolomite has δ¹⁸O (PDB) values ranging between ? 5.3 and ? 8.6%_o. Regional replacement dolomites exhibit a wide range of δ¹⁸O values from ? 3.3 to ? 10.9%_o whereas void-filling dolomite has δ¹⁸O values ranging from ? 10.8 to ? 14.3%_o. All three dolomite types have similar δ¹³C (PDB) values, in the range between +1.7 and ?1.7%_o. Three initial dolomitization episodes are interpreted: (1) a sabkha stage, forming the syndepositional dolomite and dolomitizing the evaporitic mudflat lithologies; (2) a brine-reflux stage, replacing the subtidal lithologies; and (3) a burial stage, forming the void-filling dolomite type. Final dolomite stabilization occurred during burial, at elevated temperatures, in the presence of basinal fluids, resulting in progressive recrystallization and stabilization of the earlier-formed syndepositional and replacement dolomites. Both textural and geochemical evolution should be taken into account when studying the origin of dolomites, based on their present geochemical composition. Sulphates are represented by very fine-crystalline syndepositional anhydrite in association with the syndepositional dolomite, and coarse to very coarse anhydrite cement. Evaportic mudflat (sabkha) and burial environments are inferred for the origin of the former and the latter anhydrite types, respectively. Evaporite dissolution breccias, indicative of the former presence of evaporites, are common throughout the succession.  相似文献   

The GAVDOS Mean Sea Level and Altimeter Calibration Facility: Results for Jason-1     

ERRICOS C. PAVLIS  STELIOS P. MERTIKAS 《Marine Geodesy》2013,36(3-4):631-655

The location of the GAVDOS facility is under a crossing point of the original ground-tracks of TOPEX/Poseidon and the present ones for Jason-1, and adjacent to an ENVISAT pass, about 50 km south of Crete, Greece. Ground observations and altimetry comparisons over cycles 70 to 90, indicate that a preliminary estimate of the absolute measurement bias for the Jason-1 altimeter is 144.7 ± 15 mm. Comparison of Jason microwave radiometer data from cycles 37 and 62, with locally collected water vapor radiometer and solar spectrometer observations indicate a 1–2 mm agreement.  相似文献