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1.
Manzoor Ahmad Badar Safdar Hussain Shanawer Niaz Saif ur Rehman 《Arabian Journal of Geosciences》2016,9(9):545
The optical anomalies, and surface and lamellar textures of a birefringent grossular garnet crystal from the Eden Mills, Belvidere Mountain, Vermont, USA, have been investigated by optical polarizing microscope, electron-probe micro-analyzer, back-scattered electron imaging, infrared spectroscopy, and single-crystal X-ray diffractometer from the standpoint of crystal growth. This grossular shows one-to-one correlation between natural surface features and its internal textures under crossed polarizers. Electron-probe micro-analyzer (EPMA) gave average chemical composition in (110) thin section, of bright lamella {Ca2.97Mn0.06}∑3.03 [Al1.59Fe0.37Ti0.01]∑1.97(Si3.00)∑3.00 (Gros79.5And18.9Sps1.6) and of dark host {Ca2.99Mn 0.06}∑3.05 [Al1.73Fe0.26 Ti0.01]∑2.00(Si2.97OH0.03)∑3.00 (Gros85.4And13Sps1.6). The correspondence of surface features and the internal textures with spiral or pyramidal growth mechanism suggest that the internal textures of the Eden Mills grossular are formed during growth process. The optical vibrational orientations and the growth steps inclination along [001] and \( \left[\overset{-}{1}10\right] \) directions predict monoclinic symmetry. With X-ray diffractometer (XRD) method, pseudocubic parameters are a = 11.839(2) Å, b = 11.855(1) Å, and c = 11.868(2) Å with interaxial angles α = 90.00(1)°, β = 89.99(1)°, and γ = 90.02(2)° that show orthorhombic symmetry of this crystal. Lamellar texture of Al3+-rich host with Fe3+-rich lamella infers cation ordering at octahedral site of the garnet structure. IR data favors the non-cubic orientation of [(OH) 4] at tetrahedral position in this grossular structure. 相似文献
2.
Shamim A. Dar K. F. Khan Saif A. Khan Akhtar R. Mir H. Wani V. Balaram 《Arabian Journal of Geosciences》2014,7(6):2237-2248
The paper presents the uranium (U) concentration and distribution pattern in the Paleoproterozoic phosphorites of Lalitpur district of Uttar Pradesh. The study of thin sections, SEM and XRD reveal that apatite is the essential phosphate mineral while quartz and feldspars are the dominant gangue in the phosphorites of the investigated area. The collophane is observed to be mostly oolitic in form and microspherulitic in texture. The major element geochemistry indicated that the phosphorite samples are rich in P2O5, CaO, SiO2 and Fe2O3 whereas depletion of MgO, MnO, K2O and Al2O3 was observed. The CaO/P2O5 ratio ranges from 1.13 to 1.46 which is slightly lower than that of cations and anions substituted francolite (1.621) and close to that of carbonate-fluorapatite (1.318). The trace element geochemistry indicates that the phosphorites of Lalitpur have the significant range of U concentration (1.67 to 129.67 μg/g) which is more than that of Th (0.69 to 0.09 μg/g) among the analysed trace elements in the phosphorite samples of the area. The positive correlation of U with P2O5, CaO and U/P2O5 indicates a close association of U with phosphate minerals like collophane (apatite), whereas negative correlation of U with SiO2 and Fe2O3 may be due to mutual replacement. The antipathetic relationship of U with Ni may be an indication of high oxidizing conditions, whereas sympathetic relationship of U with K2O points towards higher alkaline conditions of the basin of deposition during phosphatization. The variable concentration of U and its relationship with significant major and trace elements in most of the phosphorite samples lead one to believe that the deposition of these phosphorites might have taken place in highly alkaline medium during fairly oxidizing to weakly reducing environmental conditions of geosynclinal basin. 相似文献
3.
No baseline existed for the radionuclides in Kuwait territorial water. With changing trend in the region to embrace nuclear energy, the baseline study is imperative to create a reference and to record the influence-functioning of upcoming power plants. The first one in Bushehr, Iran is ready to start and several more are likely to come-up in UAE, Saudi Arabia and Kuwait. The present baseline concentration of the four considered radionuclide's show low concentration of tritium, polonium, strontium and cesium; their concentration is comparable to most oceanic waters. 相似文献
4.
M. Saif Ur Rehman J.-I. Han 《International Journal of Environmental Science and Technology》2013,10(4):865-870
The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R 2 = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R 2 = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater. 相似文献
5.
The litho-units of the area between Chawand to Kotra across the Aravalli-Delhi Fold Belt are referable to Bhilwara, Aravalli and and Delhi Supergroups. Earlier workers considered the sequence as progressively younger toward west across the Avavalli Orographic axis. Two-dimensional trend mapping of the planar tectonic anisotropy was carried out to map lineaments from landsat TM Image. Ground checks of the lineament along Chawand-Kotra section suggest that lineaments are tectonic dislocations, morphotectonically controlled by thrusts and ductile shears within the Aravalli-Delhi Fold Belt. The recognition of thrust bounded litho-tectonic units from interpretation of satellite remotely sensed data may necessitate reassessment of the Precambrian lithostraligraphy of the Aravalli and Delhi supergroups in the study area. The paper reports thrust tectonics from Aravalli-Delhi Fold Bell. The Antalia Schuppean Belt is possible duplex; imbricate thrusts are connected with base thrust and continuity with roof thrust has been punctuated by transverse faulting and erosion. 相似文献
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7.
南海北部陆架和陆坡区小型底栖动物群落的比较研究 总被引：1，自引：0，他引：1
为了解南海北部陆架与陆坡区小型底栖动物的群落特征,以及影响群落特征的环境因素,2015年6月对南海北部海域(19.3°—21.4°N, 112.4°—115.1°E)7个站位的小型底栖动物及环境因子进行了采样,并对陆架和陆坡区小型底栖动物群落的丰度、生物量、类群组成和群落结构进行比较。结果表明,在陆架站位,小型底栖动物由13个类群组成,平均丰度为(132±130)ind./10cm2,平均生物量为(169±79)μgdwt/10cm2;在陆坡站位由8个类群组成,平均丰度为(33±14)ind./10cm2,平均生物量为(56±35)μgdwt/10cm2。单因素方差分析结果表明,陆坡区小型底栖动物的总丰度和总生物量以及线虫和多毛类的丰度均显著低于陆架区,但优势类群的相对丰度组成没有显著不同,海洋线虫占总丰度的83%,其次为多毛类和桡足类,分别占7%和3%。环境因子的主成分分析(Principal ComponentsAnalysis,PCA)将陆架和陆坡站位沿第一主分量轴分开,小型底栖生物丰度和生物量与沉积物叶绿素a和脱镁叶绿酸含量以及底层水温呈最大正相关,与水深呈负相关;聚类(Cluster)和排序(non-metric Multidimensional Scaling, MDS),以相似性系数65%将7个站位划分为2组,与按照水深划分的陆架和陆坡组基本吻合;单因素相似性分析(one-way ANOSIM)显示陆架和陆坡区小型底栖动物群落结构差异显著;生物-环境分析(Biota-Environment,BIOENV)表明影响群落结构的最佳环境因子组合为叶绿素a和底层水温。综上可知,随水深增加的食物减少和底层水温的下降是限制南海北部研究海域小型底栖动物丰度和生物量及影响群落组成和结构的主要因素。 相似文献
8.
Rehman Saif ur Umar Muhammad Ehsan Muhammad Irfan Munawar Muhammad Jawad Miraj Muhammad Armaghan Faisal Ullah Muhammad Fahad 《Doklady Earth Sciences》2023,507(3):S446-S456
Doklady Earth Sciences - The research work involves rock physics modeling and reservoir characterization of Suliman fold belt to sulamain fold depression. This area is a brighter zone for... 相似文献
9.
Ahmed Al-Futaisi Ahmad Jamrah Amer Al-Rawas Saif Al-Hanai 《Environmental Geology》2007,51(8):1317-1327
In this paper, Shuwaymiyah palygorskite in the Sultanate of Oman has been characterized mineralogically by X-ray diffraction
(XRD) and electron microscopy, chemically by oxide compositions, structural formulae, and cation exchange capacity (CEC),
and physically by specific surface area and adsorption isotherms. Batch adsorption studies were performed to evaluate the
adsorption performance of methylene blue (MB) basic dye on the local clay mineral. The quantitative XRD analysis indicates
that the purity of some selected samples of palygorskite clay is very high (about 70% of the clay minerals are palygorskite
and 30% kaolinite). The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images clearly support
this conclusion. The adsorption equilibrium revealed that Shuwaymiyah palygorskite clay can uptake up to 51 mg of MB per 1 g
mass of clay. MB adsorption is best fitted by Langmuir isotherm, and a pseudo-second-order kinetic model can be efficiently
used to predict the kinetic of adsorption of MB by the palygorskite. The results obtained from these laboratory-scale adsorption
tests indicate the promising adsorption capability of the Omani palygorskite. 相似文献
10.
Major, trace and rare earth elements of phosphatic rocks around Sonrai block of Paleo-Mesoproterozoic age having phosphatic breccia, quartzite, shale, sandstone, limestone and ironstone, have been determined to evaluate their correlation, relationship with the phosphorus content, the nature of possible substitution of various elements and regional distribution pattern over the area. The study indicates that the number of elements is substituted in the apatite structures; few of them are associated with phosphate and carbonate minerals. The variable concentration of major, trace and rare earth elements in the phosphatic rocks has been influenced by various physico-chemical processes involved during weathering and leaching of the source rocks. The distribution of the major, trace and rare earth elements is controlled by the environmental variations in the sediment water interface. The majority of trace elements were mainly influenced by the principle adsorbents like the phosphate minerals in addition to clay, iron oxides and silicate minerals. The PAAS normalized REE patterns of Sonrai block of phosphorites are characterized by negative Ce anomalies and Positive Eu anomalies. It is inferred from the distribution and interrelationship of major, trace and rare earth elements that the deposition of phosphate minerals might have occurred in highly oxidizing to slightly reducing conditions in supratidal to intertidal continental margins and shallow marine environment. The deposition was controlled by marine upwelling leading to excess charge of phosphate in certain zones of phosphogenic basins, lithologic facies variations in restricted circulations of basinal waters and electrochemical factors such as negative Eh, pH and other factors, which influenced the deposition of phosphates. The replacement, precipitation in voids and fissures and diagenesis were also important mechanisms of phosphate generation in Sonrai basin. The main source for various elements may be the minerals of cratonic mass of Bundelkhand Granitic Complex, a basement of Bijawar Basin, which also provided land derived phosphorus through weathering of the terrestrial cover. 相似文献