Pressure and temperature dependence of the viscosity of a NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript> melt     

Akio Suzuki  Eiji Ohtani  Hidenori Terasaki  Keisuke Nishida  Hiromi Hayashi  Tatsuya Sakamaki  Yuki Shibazaki  Takumi Kikegawa 《Physics and Chemistry of Minerals》2011,38(1):59-64

The viscosity of a silicate melt of composition NaAlSi₂O₆ was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi₂O₆ melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 10² and 3.7 ± 0.5 × 10² kJ/mol at 2.2 and 2.9 GPa, respectively.  相似文献   

Physical control of sediment carbon content in an estuarine tidal flat system (Nanakita River, Japan): A mechanistic case study     

Takashi Sakamaki  Osamu Nishimura 《Estuarine, Coastal and Shelf Science》2007,73(3-4):781-791

Temporal variations in sediment carbon content were tracked by sampling every 2 weeks for 6 to 33 months at 6 tidal flat stations with different carbon content levels (0.05–1.64%) in a single estuary. Three temporal series of current velocity at 5 cm above the sediment were also obtained. Non-cohesive and cohesive sediment stations differed in patterns of temporal variation in sediment carbon content, suggesting the difference in processes controlling sediment carbon content. In the stations of non-cohesive sandy sediment with relatively low carbon content (0.05–0.15%), sediment carbon content fluctuated within ranges specific to each station. In these stations, current velocity data suggested that frequency of sand resuspension washing out sediment carbon controls sediment carbon content level. In the stations of cohesive sediment with relatively high carbon content (0.77–1.64%), sediment carbon contents showed some unusual upward and downward peaks, recovered to usual levels specific to the stations, and was always kept higher than that in the non-cohesive sediment stations. We speculate that in the cohesive sediment stations, sand inputs may significantly control processes establishing the consolidated sediments with various carbon content levels. Spatial transitions from non-cohesive to cohesive sediments and from low to high sediment carbon contents likely occur as sand resuspension at spring tides become more irregular and less frequent. Based on these results, conceptual models describing physical processes controlling sediment carbon content at the studied stations were proposed.  相似文献   

Tidal time-scale variation in nutrient flux across the sediment–water interface of an estuarine tidal flat     

Takashi Sakamaki  Osamu Nishimura  Ruichi Sudo 《Estuarine, Coastal and Shelf Science》2006,67(4):653-663

We determined the range of the tidal variations in nutrient flux across the sediment–water interface and elucidated mechanisms of the flux variation in two estuarine intertidal flats (one sand, one mud) in northeastern Japan. Nutrient flux was measured using in situ light and dark chambers, which were incubated for 2 h, 2–6 times per day. Results showed that nutrient concentration in overlying water varied by tide and was also affected by sewage-treated water inflow. The nutrient fluxes responded quickly to the tidal variation in overlying water chemistry and the range of the variation in flux was as large as the seasonal-scale variation reported in previous studies. In the sand flat, salinity increase likely enhanced benthos respiration and led to increases in both O₂ consumption and PO₄³⁻ regeneration under low illumination, while benthic microalgae were likely to actively generate O₂, uptake PO₄³⁻ and suppress PO₄³⁻ release under high illumination (>900 μmol photons m⁻² s⁻¹). Also in the mud flat, PO₄³⁻ flux was related with O₂ flux, although the range of temporal variation in PO₄³⁻ flux was small. In both the flats, NH₄⁺ flux was always governed by NH₄⁺ concentration in the overlying water; either an increase in NH₄⁺ uptake or a decrease in NH₄⁺ release was observed as the NH₄⁺ concentration rose due to inflow of river water or input of sewage-treated water. Although NO₃⁻ tended to be released in both tidal flats when low NO₃⁻ concentration seawater dominated, their relationship was likely to be weakened under conditions of low oxygen consumption and suppressed denitrification. It is likely that tidal variation in nutrient flux is governed more by the nutrient concentration than other factors, such as benthic biological processes, particularly in the case where nutrient concentration in the overlying water is relatively high and with wide amplitude.  相似文献   

Effect of hydrogen on the melting temperature of FeS at high pressure: Implications for the core of Ganymede     

Yuki Shibazaki  Eiji Ohtani  Hidenori Terasaki  Ryuji Tateyama  Tatsuya Sakamaki  Taku Tsuchiya  Ken-ichi Funakoshi 《Earth and Planetary Science Letters》2011,301(1-2):153-158

We have carried out in situ X-ray diffraction experiments on the FeS–H system up to 16.5 GPa and 1723 K using a Kawai-type multianvil high-pressure apparatus employing synchrotron X-ray radiation. Hydrogen was supplied to FeS from the thermal decomposition of LiAlH₄, and FeSH_x was formed at high pressures and temperatures. The melting temperature and phase relationships of FeSH_x were determined based on in situ powder X-ray diffraction data. The melting temperature of FeSH_x was reduced by 150–250 K comparing with that of pure FeS. The hydrogen concentration in FeSH_x was determined to be x = 0.2–0.4 just before melting occurred between 3.0 and 16.5 GPa. It is considered that sulfur is the major light element in the core of Ganymede, one of the Galilean satellites of Jupiter. Although the interior of Ganymede is differentiated today, the silicate rock and the iron alloy mixed with H₂O, and the iron alloy could react with H₂O (as ice or water) or the hydrous silicate before the differentiation occurred in an early period, resulting in a formation of iron hydride. Therefore, Ganymede's core may be composed of an Fe–S–H system. According to our results, hydrogen dissolved in Ganymede's core lowers the melting temperature of the core composition, and so today, the core could have solid FeSH_x inner core and liquid FeH_x–FeSH_x outer core and the present core temperature is considered to be relatively low.  相似文献   

Effects of alkali and alkaline-earth cations on the high-pressure sound velocities of aluminosilicate glasses     

Aoki  Koji  Sakamaki  Tatsuya  Ohashi  Tomonori  Ikeda  Osamu  Suzuki  Akio 《Physics and Chemistry of Minerals》2020,47(6):1-9

Physics and Chemistry of Minerals - A black tourmaline sample from Seagull batholith (Yukon Territory, Canada) was established to be a schorl with concentrations of Fe2+ among the highest currently...  相似文献