排序方式： 共有24条查询结果，搜索用时 640 毫秒
1.
Boris TagirovJacques Schott Jean-Claude HarrichourryStefano Salvi 《Geochimica et cosmochimica acta》2002,66(11):2013-2024
The solubility of the albite-paragonite-quartz mineral assemblage was measured as a function of NaCl and fluorine concentration at 400°C, 500 bars and at 450°C, 500 and 1000 bars. Decreasing Al concentrations with increasing NaCl molality in F-free fluids of low salinity (mNaCl < 0.01) demonstrates that Al(OH)4− dominates Al speciation and is formed according to the reaction 0.5 NaAl3Si3O12H2(cr)+2 H2O = 0.5 NaAlSi3O8(cr)+Al(OH)4−+H+. Log K results for this reaction are −11.28 ± 0.10 and −10.59 ± 0.10 at 400°C, 500 bars and 450°C, 1000 bars, respectively. Upon further salinity increase, Al concentration becomes constant (at 400°C, 500 bars) or even rises (at 450°C, 1000 bars). The observed Al behavior can be explained by the formation of NaAl(OH)40(aq) or NaAl(OH)3Cl(aq)0. The calculated constant for the reaction Al(OH)4−+Na+=NaAl(OH)40(aq) expressed in log units is equal to 2.46 and 2.04 at 400°C, 500 bars and 450°C, 1000 bars, respectively. These values are in good agreement with the predictions given in Diakonov et al. (1996). Addition of fluoride at m(NaCl) = const = 0.5 caused a sharp increase in Al concentration in equilibrium with the albite-paragonite-quartz mineral assemblage. As fluid pH was also constant, this solubility increase indicates strong aluminum-fluoride complexation with the formation of NaAl(OH)3F(aq)0 and NaAl(OH)2F20(aq), according to 0.5 NaAl3Si3O12H2(cr)+Na++HF(aq)0+H2O = 0.5 NaAlSi3O8(cr)+ NaAl(OH)3F(aq)0+H+, log K = −5.17 and −5.23 at 400°C and 450°C, 500 bars, respectively, and 0.5 NaAl3Si3O12H2(cr)+Na++2 HF(aq)0 = 0.5 NaAlSi3O8(cr)+NaAl(OH)2F20(aq)+H+, log K = −2.19 and −1.64 at the same P-T conditions. It was found that temperature increase and pressure decrease promote the formation of Na-Al-OH-F species. Stability of NaAl(OH)2F20(aq) in low-density fluids also increases relative to NaAl(OH)3F(aq)0. These complexes, together with Al(OH)2F(aq)0 and AlOHF20(aq), whose stability constants were calculated from the corundum solubility measured by Soboleva and Zaraisky (1990) and Zaraisky (1994), are likely to dominate Al speciation in metamorphic fluids containing several ppm of fluorine. 相似文献
2.
Salvi S. Quattrocchi F. Brunori C. A. Doumaz F. Angelone M. Billi A. Buongiorno F. Funiciello R. Guerra M. Mele G. Pizzino L. Salvini F. 《Natural Hazards》1999,20(2-3):255-278
A priority task for correct environmental planningis to evaluate Natural Hazards, especially inhighly populated areas. In particular, thoroughinvestigations based on different Earth Sciencetechniques must be addressed for the Seismic HazardAssessment (SHA) in tectonically active areas. Notonly the management but also the multidisciplinaryanalysis of all the SHA-related data sets is bestperformed using a Geographic Information System. In this paper we show how a research-oriented GIS isbuilt and used in a practical case. The GeochemicalGeographic Information System (G2IS) wasdeveloped and applied to the Gargano promontory(southern Italy) in the framework of an EC researchproject, the Geochemical Seismic Zonation (GSZ)Project. This multidisciplinary – multiscalingpowerful tool is described in its structure, updatingprocedures and manipulation techniques. Preliminaryresults are presented on the detection of geochemically active fault zones and theircorrelation with remote sensing data and otherevidences of seismogenic structures. 相似文献
3.
Boris R. Tagirov Stefano Salvi Nina N. Baranova 《Geochimica et cosmochimica acta》2005,69(8):2119-2132
The solubility of gold was measured in KCl solutions (0.001-0.1 m) at near-neutral to weakly acidic pH in the presence of the K-feldspar-muscovite-quartz, andalusite-muscovite-quartz, and pyrite-pyrrhotite-magnetite buffers at temperatures 350 to 500°C and pressures 0.5 and 1 kbar. These mineral buffers were used to simultaneously constrain pH, f(S2), and f(H2). The experiments were performed using a CORETEST flexible Ti-cell rocking hydrothermal reactor enabling solution sampling at experimental conditions. Measured log m(Au) (mol/kg H2O) ranges from −7.5 at weakly acid pH to −5.9 in near-neutral solutions, and increases slightly with temperature. Gold solubility in weakly basic and near-neutral solutions decreases with decreasing pH at all temperatures, which implies that Au(HS)2 is the dominant Au species in solution. In more acidic solutions, solubility is independent of pH. Comparison of the experimentally measured solubilities with literature values for Au hydrolysis constants demonstrates that at 350°C dominates Au aqueous speciation at the weakly acidic pH and f(S2)/f(H2) conditions imposed by the pyrite-pyrrhotite-magnetite buffer. In contrast, at temperatures >400°C becomes less important and predominates in weakly acid solutions. Solubility data collected in this study were used to calculate the following equilibrium reaction constants:
4.
Prosper Rakotovao Andrianjakavah Stefano Salvi Didier Béziat Michel Rakotondrazafy Gaston Giuliani 《Mineralium Deposita》2009,44(7):817-835
The Ianapera emerald deposit is located in the Neoproterozoic Vohibory Block of southern Madagascar. The local geology consists
of intercalated migmatitic gneissic units and calcareous metasedimentary rocks, containing boudinaged metamorphosed mafic/ultramafic
lenses, all intruded by pegmatite veins. These units occur near the hinge of the tightly folded Ianapera antiform, within
a few kilometers of the Ampanihy shear zone. Emerald mineralization is hosted by metasomatic phlogopite veins, and bodies
developed within the mafic/ultramafic rocks. Based on field and textural relationships, we distinguish proximal and distal
styles of mineralization. Proximal mineralization occurs at the contact of pegmatite veins with mafic/ultramafic units; in
the distal style, pegmatites are not observed. Three types of emeralds could be distinguished, mainly on the basis of color
and mineral zoning. Some of these emeralds have the most Al-depleted and Cr-rich composition ever recorded. Another characteristic
feature to the Ianapera deposit and, to our knowledge, yet unreported, is the association of some emeralds with scapolite
in metasomatised mafic rocks. Mineral inclusions are common in most emeralds and include phlogopite, carbonates, barite, K-feldspar,
quartz, pyrite, zircon, monazite, bastnaesite, phenakite, plus Fe and Cr oxides. However, feldspar and rare earth element-bearing
minerals occur predominantly in proximal emeralds, which also have a more incompatible trace-element signature than distal
emeralds. We propose a model related to syn- to post-tectonic magmatic-hydrothermal activity. Pegmatitic bodies intruded units
of the Ianapera antiform probably during tectonic relaxation. Exsolution of fluids rich in halogens and incompatible elements
from the cooling pegmatites caused hydrothermal metasomatism of Cr-bearing mafic/ultramafic rocks in direct contact with the
pegmatites. Local fracturing favored fluid infiltration, permitting the formation of distal mineralization. Emerald composition
was controlled by the chemistry of the host rock. The presence of carbonate mineral inclusions in the emeralds and the high
F-activity indicated by elevated F-contents in newly formed minerals suggest transport of Be as a fluoride-carbonate complex.
It seems likely that beryl formation was triggered by precipitation of F-rich phlogopite, which removed the complexing ligand
from the fluid. 相似文献
5.
German Velásquez Anastassia Y. Borisova Stefano Salvi Didier Béziat 《Geostandards and Geoanalytical Research》2012,36(3):315-324
Gold and copper concentrations were determined in natural pyrite by near‐infrared femtosecond LA‐ICP‐QMS, using both sulfide reference materials (pyrrhotite Po‐726 and in‐house natural chalcopyrite Cpy‐RM) and NIST SRM 610 as external calibrators. Firstly, using NIST SRM 610 as the external calibrator, we calculated the Au concentration in Po‐726 and the Cu concentration in Cpy‐RM. The calculated concentration averages for Au and Cu were similar to the values published for Po‐726 and Cpy‐RM, respectively. Secondly, we calculated Au and Cu concentrations taking NIST SRM 610 as an unknown sample and using Po‐726 and Cpy‐RM as external calibrators. Again, the average values obtained closely reflected the preferred concentrations for NIST SRM 610. Finally, we calculated Au and Cu concentrations in natural pyrite using sulfide and silicate reference materials as external calibrators. In both cases, calculated concentrations were very similar, independent of the external calibrator used. The aforementioned data, plus the fact that we obtained very small differences in relative sensitivity values (percentage differences are between 5% and 17% for 57Fe, 63Cu and 197Au) on analyses of silicate and sulfide RMs, indicate that there were no matrix effects related to the differences in material composition. Thus, it is possible to determine Au and Cu in natural sulfides using NIST silicate glasses as an external calibrator. 相似文献
6.
S·Atzori I·Hunstad M·Chini S·Salvi C·Tolomei C·Bignami S·Stramondo E·Trasatti A·Antonioli E·Boschi 李晶 《世界地震译丛》2009,(4):30-36
根据环境卫星Envisat和COSMO—SkyMed模型（为同震位错研究而首次设计的X波段反演干涉图）的DInSAR干涉图,确定了2009年4月6日阿奎拉Mw=6．3级地震时激发的断层几何形状及运动特征。我们的主震最佳拟合解为一个约16km长、12km宽的正断层,存在小的右旋分量,向西南倾斜47°,最大滑动约90cm。虽然地震位错可能只有1km深,但是断层面的上倾投影与标绘的帕加尼卡-南德米特里奥断层的北段相符合,在现场观察到了该断层地表破裂的迹线。该断层在现有震源目录中的缺失表明,需要对具体的地表和地下进行进一步的地质和地球物理勘测,以便对局部规模的地震危险性做出更准确的评估。 相似文献
7.
S. Salvi S. Stramondo M. Cocco M. Tesauro I. Hunstad M. Anzidei P. Briole P. Baldi E. Sansosti G. Fornaro R. Lanari F. Doumaz A. Pesci A. Galvani 《Journal of Seismology》2000,4(4):479-499
In this study we analyse coseismic GPS displacements and DInSAR data to constrain a dislocation model for the three largest earthquakes of the 1997 Umbria-Marche seismic sequence. The first two events, which occurred on September 26 at 00:33 GMT (Mw 5.7) and 09:40 GMT (Mw 6.0) respectively, are investigated using both GPS displacements and DInSAR interferograms. We discuss and compare the results of previous studies which separately modeled a smaller subset of geodetic data. We provide a dislocation model for these two earthquakes which fits well both GPS and DInSAR data and agrees with the results of seismological and geological investigations. The first event consists of a unilateral rupture towards the southeast with a uniform dislocation. The strike, rake and dip angles are those resulting from the CMT solution. The second event consists of an unilateral rupture towards the northwest and a variable slip distribution on the fault plane. The strike and the rake are consistent with the CMT solution, but the dip angle has been slightly modified to improve the simultaneous fit of GPS and DInSAR data. While the second rupture (09:40 GMT) arrived very close to the surface, the fit to geodetic data shows that the first rupture (00:33 GMT) is deeper (2 km), despite the more evident surface geological effects. The analysis of new SAR interferograms allows the identification of a 5–6 cm additional displacement caused by the October 3 (Mw 5.2) and 6 (Mw 5.4) seismic events.We use data from a new DInSAR interferogram to model the displacement field of the Sellano earthquake of October 14, 1997. For this event significant GPS measurements were not available. We tested two different fault plane geometries: a blind, planar fault (top depth = 2.4 km), and a curved (listric) fault reaching the surface. The two models provide a generally similar fit to the data, and show that most of the slip was released at depths greater than 2.4 km along a gently dipping (40°–45°) fault surface. They also show that a unilateral rupture does not allow fitting the interferometric fringes since there is evident surface deformation to the northwest of the hypocenter. Moreover, we suggest that the concentration of high residuals in the southern part of our uniform slip model may in fact indicate a certain slip variability in this area.We conclude that, despite the moderate magnitudes and the lack of significant surface faulting, the space geodetic data allowed to constrain dislocation models giving new insights in the rupture process of the three largest events of the sequence. 相似文献
8.
Bogdan Wszolek Konrad Rudnicki Silvia Masi Paolo De Bernardis Antonio Salvi 《Astrophysics and Space Science》1989,152(1):29-34
We used theIRAS All Sky Maps in order to search for infrared emission in the direction of the Okroy Cloud (R.A.=12h50m, =22°). An enhancement of 100 m diffuse emission is evident in such a region, with an anomalous value of the ratioI
v (100 m)/A
v
; hydrogen 21 cm emission is also present with low radial speed, thus suggesting that the cloud could be a satellite of our Galaxy. 相似文献
9.
Trace element geochemistry by laser ablation ICP-MS of micas associated with Ta mineralization in the Tanco pegmatite,Manitoba, Canada 总被引：3，自引：0，他引：3
Marieke Van Lichtervelde Michel Grégoire Robert L. Linnen Didier Béziat Stefano Salvi 《Contributions to Mineralogy and Petrology》2008,155(6):791-806
In the Tanco pegmatite, one of the world’s major Ta deposits, tantalum mineralization shows a complexity that reflects the
complex petrogenesis of its host pegmatite. Micas are common in most of the pegmatite units and are intimately associated
with the successive stages of Ta mineralization, from the wall zone to the central zones where micaceous replacement is pervasive.
Different generations of micas, both primary and secondary, associated with Ta oxides, were selected for electron microprobe
and laser ablation ICP-MS investigation. Their chemical trends are used to constrain the magmatic versus hydrothermal processes
that played a role in their crystallization and their associated Ta mineralization. Micas range from dioctahedral muscovite
to trioctahedral lepidolite through Al↔Li substitution. Unexpectedly, the most evolved compositions (low K/Rb ratios and high
Li contents) occur in the wall zone; they are interpreted to reflect nonequilibrium crystallization from an undercooled melt,
with or without boundary layer effects. In the central zones, the fine-grained mica–quartz assemblage hosts some coarser-grained
Li-muscovite, which has the highest Ta contents (up to 400 ppm). These Li–F–a-rich micas are interpreted to originate from
a magmatic metasomatic event, which was also at the origin of the MQM-style Ta mineralization at Tanco. However, the Li–Ta-poor,
muscovite end-member compositions of fine-grained alteration micas suggest crystallization from an aqueous fluid, during a
metasomatic (hydrothermal) event involving late pegmatitic fluids. The low Ta concentrations (around 50 ppm) of this fine-grained
muscovite suggest that this fluid transported at least small amounts of Ta. 相似文献
10.