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1.
This study defines the source area, sub-aerial weathering, and sedimentary cycle level, as well as heavy metal content and origin, of the Çoruh River bed sediments. The studied sediments are geochemically classified as litharenite based on the ratio of the major element contents. Relative to the Upper Continental Crust (UCC), trace elements Rb, Sr, Ba, Th, U, Zr, Hf, Y, Nb, and Pb are generally depleted; Co, Ni, Cu, Sc, and V are generally enriched; and Au is depleted in some places and enriched in other places. The rare earth element (REE) distributions of the samples exhibit a trend similar to that of the upper continental crust (UCC); however, low to moderate depletion occurs in the bed sediments in UCC. The analyzed samples exhibit low Chemical Index of Alteration (CIA) values, Plagioclase Index of Alteration (PIA) values (<50), CIA/WIP (Weathering Index ratios <1), and substantially high Index of Compositional Variability values (ICV) (>1). Thus, the samples are not chemically mature and are mainly derived from non-altered sources and were exposed the simple cycling history. REEs are depleted in the river bed sediments, unlike the world river average silt, world river average clay, and suspended sediment in world rivers. Minor enrichment of Zn, Sn, and Sc contents, low-to-moderate enrichment of Cu content, very severe enrichment of as content, and extremely severe enrichment of Ni content of the analyzed samples are observed. Consequently, stream bed sediments are derived from intermediate sources close to mid-continental crust rather than felsic sources Low-to-moderate degrees of chemical weathering of these sediments indicate increased tectonic activity, increased erosion, and rapid sedimentation in semiarid to arid conditions in the source regions over time. Thus, the sediments are chemically immature. These sediments are exposed to lithogenic and anthropogenic contamination. 相似文献
2.
Mahdi Zoorabadi Serkan Saydam Wendy Timms Bruce Hebblewhite 《Geomechanics and Geoengineering》2016,11(3):189-200
Roughness on rock joints produces a variable aperture across the joints and increases the flow path length. These conditions should be taken into account for a good approximation from cubic law. In this paper, the concept of local true aperture and tortuosity is applied to assumed joints where surfaces are matched to each other and correspond with standard Joint Roughness Coefficient (JRC) profiles. Furthermore, the hydraulic behaviour of JRC profiles is studied by a new laboratory experiment setup. The analytical approach provides new insights into the effects of roughness on hydraulic properties of rock joints. The results indicate that for a constant mechanical aperture, both the minimum local aperture and hydraulic aperture decrease with increasing JRC. Furthermore, tortuosity and standard deviation of local true aperture increase with JRC increment. The trend obtained between different parameters and JRC shows an obvious fluctuation for JRC lower than 10. On one hand, the results of this study along with a critical review of previous studies demonstrate that JRC profiles cannot present a precise roughness increment when JRC is less than 10. A new laboratory setup was designed to study the flow behaviour of JRC profiles. The results obtained from laboratory experiments under linear flow conditions validate the accuracy of the applied analytical method. 相似文献
3.
Cigdem Saydam Eker Ferkan Sipahi Abdullah Kaygusuz 《Chemie der Erde / Geochemistry》2012,72(2):167-177
Trace elements and rare earth elements (REEs) of Lias-aged cherts in the Gumushane area were studied in order to understand their origin and depositional environment. Twenty three chert samples from five stratigraphic sections were analysed by inductively coupled plasma-mass spectrometry, X-ray diffraction, and mineralogical investigation. Lias cherts in the study area are microcrystalline, cryptocrystalline quartz, and megaquartz depending on mineralogical content. Trace elements of the cherts were compared with PAAS, Co, Y, and Th had stronger depletions in the five sections, whereas V, Ni, Zr, Nb, and Hf had smaller depletions. The distribution of Zr, Hf, and Ta yields Zr/Hf, Zr/Ta and Hf/Ta ratios (25/645, 37/665, and 0.18/3, respectively) that differ from those of chondrites and average upper continental crust, suggesting that these elements are likely non-detrital but are sourced from seawater. Th/U ratios range from 0.04 to 0.45 and are lower than those of the upper continental crust (average: 3.9). Lias-aged cherts have low total REE abundances and stronger depletions in five sections of the PAAS and chondrite-normalised plots. The cherts are characterised by a positive Eu anomaly (average: 4.9) and LREE-enrichment (LaN/YbN = average: 3.5). In addition, about one-half of the cherts exhibit positive Ce anomaly (range: 0.25–2.58), chondritic Y/Ho values (range: 3.3–60), and low (La/Ce)N values (average: 1.8). REE and trace element abundance in Lias cherts indicate that these elements were likely derived from hydrothermal solutions, terrigenous sources, and seawater. The REE patterns of the cherts show that they were probably deposited close to a continental margin. 相似文献
4.
Mahdi Zoorabadi Serkan Saydam Bruce Hebblewhite 《Geotechnical and Geological Engineering》2013,31(2):783-791
Penetration rate prediction of Tunnel Boring Machine (TBM) is the first step to advance prediction process of mechanized tunnelling. In this research, influence of effective parameters on TBM penetration rate is investigated by sensitivity analysis of three main TBM performance prediction methods; Norwegian University of Science and Technology (NTNU), rock mass index (RMi) and QTBM. Based on these analyses, it is shown that applied thrust per disc and joint spacing in NTNU and RMi models have more influence on penetration rate. In QTBM model, Q value, applied thrust per disc and induced biaxial stress are more effective. 相似文献
5.
In the design and assessment of structures, the aspects regarding the future performance are gaining increased attention. A wide range of performance measures is covered by ‘sustainability’ to reflect these aspects. There is the need for well established methods for quantifying the metrics of sustainability. In this paper, a framework for assessing the time‐variant sustainability of bridges associated with multiple hazards considering the effects of structural deterioration is presented. The approach accounts for the effects of flood‐induced scour on seismic fragility. Sustainability is quantified in terms of its social, environmental, and economic metrics. These include the expected downtime and number of fatalities, expected energy waste and carbon dioxide emissions, and the expected loss. The proposed approach is illustrated on a reinforced concrete bridge. The effects of corrosion on reinforcement bars and concrete cover spalling are accounted. The seismic fragility curves at different points in time are obtained through nonlinear finite element analyses. The variation of the metrics of sustainability in time is presented. The effects of flood‐induced scour on both seismic fragility and metrics are also investigated. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
6.
Precipitation samples collected at Erdemli, Turkey, during February 1996–June 1997 were analysed to determine iron content and speciation. The purpose of the measurements was to examine the atmospheric abundance of iron and to quantify its solubility in the region. Spectrophotometric analyses of Fe(II) and reducible Fe(III) in precipitation samples, along with measurements of pH, conductivity, filterable iron (Fefilt), particulate aluminium (Alpar) and particulateiron (Fepar) were performed to determine iron solubility, which principally affects its bioavailability. Backward trajectories corresponding to the sampling dates were analysed to determine the sources of atmospheric constituents arriving at the site. Among these, the mineral dust transported from the Great Sahara to the region is considered to be a rich source of iron. The concentration of Fe(II) varied from below detection limit (0.02 M) up to 0.42 M,while the maximum concentration of total reactive Fe (referred as Fe(II) + reducible Fe(III) = Fereac) was found to be 1.0 M in precipitation. A strong correlation was found between particulate Fe and Al fractions, both of crustal origin. No correlation was observed between the soluble and insoluble fractions of iron. The soluble iron fraction, Fe(II) concentration varied independently from the concentrations of reducible Fe(III), Fefilt, Fepar, and from the pH of the precipitation. The Fefilt fraction (size < 0.45 m), measuredby Atomic Absorption Spectrophotometer, and frequently interpreted to be the soluble iron fraction in the literature, was found to be significantly higher than the corresponding Fereac fraction inprecipitation samples, most likely due to the colloidal iron content of the Fefilt fraction passing through the 0.45 m pore size filter. The volume weighted mean Fefilt concentration of the precipitation samples collected during the episodic `red rain' events was found to be relatively higher. The geometric mean ratios of soluble Fe(II) and of Fereac to Total Fe (Fefilt + Fepar), werefound to be 1.6% and 2.1%, respectively, while the mean ratioof Fefilt to Total Fe was 9.6%. The flux of bioavailable iron (Fereac)fraction in most atmospheric wet deposition events was found to be sufficient for supporting the maximum primary production rates that are typical for the Eastern Mediterranean Sea. 相似文献
7.
Assessing the extent of local trace metal pollution in marine atmospheric particulates presents a number of difficulties, and one potential approach to the problem has been evaluated by reference to a series of aerosols from the lower troposphere over the Eastern Mediterranean. This region, which is less remote from the continents than open-ocean areas, has two significantly different atmospheric particulate catchments: being bordered in the north by nations having industrialized, semi-industrialized and rural economies, and in the south by the North African desert belt. The elemental chemistry of the particulates is illustrated in terms of the distributions of Fe and Pb, which are presented in the form of enrichment factor diagrams, and is shown to be essentially controlled by the dilution of a ‘European’ background material, common to ‘remote’ regions of the latitudinal belt, with crust-derived, desert components. Major local perturbations in the dilution relationship can occur when either crust-derived or pollutant components strongly dominate the total particulate population. The extent of these local perturbations can be tentatively assessed using appropriate enrichment factor diagrams, which offer a framework within which to interpret the elemental chemistry of marine atmospheric particulates providing sufficient data is available for their construction. By using such an EF diagram it is suggested that the Eastern Mediterranean atmospheric particulates have not suffered local pollution on a gross scale with respect to Pb. 相似文献
8.
Zoorabadi Mahdi Saydam Serkan Timms Wendy Hebblewhite Bruce 《Hydrogeology Journal》2022,30(1):111-119
Hydrogeology Journal - The hydraulic conductivity of jointed rocks is one of the main input parameters to predict water inflow to engineering structures that are located in the jointed rocks.... 相似文献
9.
Cigdem Saydam Eker 《Geochemistry International》2012,50(8):683-701
Subaerial weathering level, source area and tectonic environments were interpreted by using petrographic and geochemical characteristics of Eocene age sandstones found in the eastern Pontides. The thickness of Eocene age clastic rocks in the eastern Pontides ranges from 195 to 400 m. Mineralogical components of sandstones were mainly quartz, feldspar, rock fragments, and opaque and accessory minerals. Depending on their matrix and mineralogical content, Eocene age sandstones are identified as arkosic arenite-lithic arenite and feldspathic wacke-lithic wacke. CIA (Chemical Index of Alteration) values observed in the Eocene age sandstones (43–55) suggest that the source terrain of the sandstones was not affected by intense chemical weathering. Low CIW/CIA (Chemical Index of Weathering/Chemical Index of Alteration) values of the sandstones studied here suggest only slightly decomposed material and having undergone little transport until final deposition. Zr/Hf, Th/Sc, La/Sc and CIA ratios are low and demonstrate a mafic source; on the other hand, high LREE/HREE ratios and a slightly negative Eu anomaly indicate a subordinate fclsic source. Modal mineralogical and SiO2/Al2O3 and K2O/Na2O and Th, Zr, Co, Sc of Eocene age sandstone contents indicate that they are probably magmatic arc originated and deposited in the back arc basin. 相似文献
10.