First investigations on the quaternary system Na2O-K2O-CaO-SiO2: synthesis and crystal structure of the mixed alkali calcium silicate K1.08Na0.92Ca6Si4O15     

Kahlenberg  Volker  Mayerl  Michael Jean-Philippe  Schmidmair  Daniela  Krüger  Hannes  Tribus  Martina 《Mineralogy and Petrology》2018,112(2):219-228

Mineralogy and Petrology - In the course of an exploratory study on the quaternary system Na2O-K2O-CaO-SiO2 single crystals of the first anhydrous sodium potassium calcium silicate have been...  相似文献   

Ca2Mg(NO3)6×12H2O–structural investigations on a new compound retrieved from chimney deposits of a combined heat and power plant     

Volker Kahlenberg  Richard Tessadri  Martina Tribus  Daniela Schmidmair  Lukas Perfler  Udo Haefeker 《Mineralogy and Petrology》2014,108(5):633-643

Phase analysis of incrustations retrieved from chimney deposits of a combined heat and power plant in Malchow/Germany by X-ray powder diffraction gave evidence for the existence of a previously unknown hydrous calcium magnesium nitrate. Optical investigations of the sample showed the presence of colorless platy crystals with a maximum diameter of about 250 μm embedded in a partly polycrystalline and partly glassy matrix. Aided by EDX-analysis and Raman spectroscopy, a single-crystal diffraction study performed at ambient conditions demonstrated that the material represents a phase with composition Ca₂Mg(NO₃)₆×12H₂O. Basic crystallographic data are as follows: trigonal symmetry, space group type R \( \overline{3} \) , a?=?10.5583(5) Å, c?=?19.5351(10) Å, V?=?1885.97(16) ų, Z?=?3, (R(|F|) = 0.0248). The magnesium ions are coordinated by water molecules to form distorted Mg(H₂O)₆-octahedra. The calcium atoms are surrounded by nine ligands. The resulting CaO₉ tricapped trigonal prisms involve oxygen atoms from additional water moieties as well as from three different bidentate nitrate groups, respectively. Hydrogen bonds link one octahedron with two adjacent prisms into trimers. The trimers in turn are stacked in columns running parallel to [001]. Further hydrogen bonding between neighboring columns results in the formation of a three-dimensional network. To our best knowledge, Ca₂Mg(NO₃)₆×12H₂O represents a new structure type. However, column-like topologies with rods consisting of different types of polyhedra have been also observed in other trigonal hydrous nitrates. The structural relationships between these compounds are discussed. It is interesting to note that in previous phase equilibrium studies on the ternary system Ca(NO₃)₂-Mg(NO₃)₂-H₂O no other hydrous double salt has been described. Finally, the results of the structure analysis allowed a qualitative and quantitative phase analysis of the crystalline part of the chimney deposit by the Rietveld method.  相似文献