Geochemistry of metabauxites in the Bergsträsser Odenwald (Mid German Crystalline Rise) and palaeoenvironmental implications     

C. I. Adusumalli  W. Schubert 《Mineralogy and Petrology》2001,72(1-3):45-62

Summary Pre- to early Variscan metamorphosed volcano-sedimentary series of the western (Bergstr?sser) Odenwald have been intruded by Variscan calc-alkaline magmatites with plate margin affinities. Within the NE-SW trending metabasic and metapelitic series, intercalations of anomalously aluminous- and iron-rich compositions representing former bauxites are distinguishable. Geochemical data indicate that the Al-, Fe-rich rocks are the metamorphic equivalents of a former bauxitic-ferralitic weathering profile, now comprising spinel fels (top) with relics of pisolitic structures, corundum-chlorite fels, corundum-cordierite-plagioclase gneiss, sillimanite-cordierite-plagioclase gneiss, cordierite-plagioclase gneiss and kinzigite (base) displaying a decrease of weathering in the order as listed. The evolution of such terrestrial sediments is related to specific climatic, environmental, and physico-chemical conditions similar to those of the present-day tropical to subtropical humid regions with high seasonal rains and intensive drainage. Comparison with palaeomagnetic and palaeoclimatic data indicate that the Odenwald metabauxites originally formed during the Lower to Mid-Devonian. Our results imply that, during this geological time span, parts of the precursors of the Mid-German Crystalline Rise not only transversed low latitudes but also were exposed to terrestrial weathering.

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Zusammenfassung Die Geochemie der Metabauxite im Bergstr?sser Odenwald (Mitteldeutsche Kristallinschwelle) und ihre Bedeutung für das Pal?omilieu Im westlichen (Bergstr?sser) Odenwald intrudierten variszische Plattenrand-Kalkalkali-Magmatite in pr?- bis früh-variszische, ehemalige vulkano-sediment?re Serien. Innerhalb der heute NE-SW streichenden Metabasit- und Metapelitzüge treten lokal Al-Fe-reiche Einschaltungen auf, die strukturell und geochemisch als metamorphe ?quivalente eines ehemaligen bauxitisch-ferralitischen Verwitterungsprofils klassifiziert werden k?nnen. Sie umfassen Spinellfelse mit erhaltenen, ehemaligen zonierten Pisolithen, Korund-Chloritfelse, Korund-Cordierit-Plagioklasgneise, Sillimanit-Cordierit-Plagioklasgneise, Cordierit-Plagioklasgneise und Kinzigite. Bauxite k?nnen als terrestrische Bildungen nur unter speziellen klimatischen und physiko-chemischen Bedingungen entstehen. Pal?omagnetische und pal?oklimatische Daten legen die Bildung der ehemaligen Bauxite im unteren bis mittleren Devon nahe. Daraus folgt, da? w?hrend dieser geologischen Zeitspanne die Vorl?ufer der mitteldeutschen Kristallinschwelle bei der Norddrift nicht nur ?quatorn?he passierten, sondern auch partiell ungest?rte, terrestrische, tropisch-subtropische Verwitterungsprozesse abliefen.

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Received June 10, 1999; revised version accepted October 30, 2000  相似文献   

Late-Quaternary supply of terrigenous organic matter to the Congo deep-sea fan (ODP site 1075): implications for equatorial African paleoclimate   总被引：3，自引：1，他引：3  

J. Holtvoeth  T. Wagner  B. Horsfield  C. Schubert  U. Wand 《Geo-Marine Letters》2001,21(1):23-33

Late-Quaternary sections (about 1 Ma) from the Congo deep-sea fan (ODP Leg 175, site 1075) were used to reconstruct the terrigenous organic matter supply to the easternmost equatorial Atlantic Ocean. Variations in quantity and quality of the riverine organic matter reflect the interaction between the paleoclimatic development within the continental catchment area and the paleoceanographic conditions in the Congo river plume. To characterize the delivery of organic matter from terrigenous and marine sources, we used elemental and bulk carbon isotopic analyses, Rock-Eval pyrolysis, lignin chemistry, and organic petrology. High-amplitude fluctuations occurring about every 15-25 ka reveal a mainly precessional control on organic sedimentation. Results from Rock-Eval pyrolysis indicate a mixed kerogen type III/II, as would be anticipated in front of a major river. Fluctuations in T_max from Rock-Eval pyrolysis demonstrate pronounced cyclic changes in the delivery of low- and high-mature organic matter. Contribution of the low-mature organic fraction was strongest during warm climates supporting enhanced marine production offshore of the Congo. Organic petrological observations confirm the existence of abundant terrigenous plant tissues, both non-oxidized (vitrinite) and oxidized (inertinite). Charcoal-like organic matter (fusinite) is attributed to periods of increased bush fires in the continental hinterland, and implies more arid climatic conditions. Results from ratios of specific phenolic lignin components suggest that terrigenous organic matter in Late-Quaternary sections of site 1075 mainly derives from non-woody angiosperm tissue, i.e., grasses and leaves. Correlation between the amount of specific lignin phenols and the bulk '¹³C_org signature fosters the conclusion that an appreciable amount of the terrigenous organic fraction derives from C4 plant matter. This may cause an underestimation of the terrigenous proportion of bulk organic matter when assessments are based on bulk carbon isotopic signatures alone.  相似文献   

Acoustic-gravity waves in the thermosphere of Venus     

Anthony D. Del Genio  Gerald Schubert  Joe M. Straus 《Icarus》1979,39(3):401-417

Properties of acoustic-gravity waves in the upper atmosphere of Venus are studied using a two-fluid model which includes the effects of wave-induced diffusion in a diffusively separated atmosphere. In conjunction with neutral mass spectrometer data from the Pioneer Venus orbiter, the theory should provide information on the distribution of wave sources in the Venus upper atmosphere. Observed wave structure in species density measurements should generally have periods ?30–35 min, small N₂, CO, and O amplitudes, and highly variable phase shifts relative to CO₂. A near resonance may exist between downward phase-propagating internal gravity and diffusion waves near the 165-km level at periods near 29 min. As a result, if very large He wave amplitudes are observed near this level, it will indicate that the wave source is below the 150- to 175-km level and that the exospheric temperature is close to 350°K. Wave energy dissipation may be an important mechanism for heating of the nightside Venus thermosphere. Large-density oscillations in stratospheric cloud layer constituents are also possible and may be detectable by the Pioneer Venus large probe neutral mass spectrometer.  相似文献   

A statistical model to downscale local daily temperature extremes from synoptic-scale atmospheric circulation patterns in the Australian region   总被引：3，自引：0，他引：3  

S. Schubert  A. Henderson-Sellers 《Climate Dynamics》1997,13(3):223-234

 The study seeks to describe one method of deriving information about local daily temperature extremes from larger scale atmospheric flow patterns using statistical tools. This is considered to be one step towards downscaling coarsely gridded climate data from global climate models (GCMs) to finer spatial scales. Downscaling is necessary in order to bridge the spatial mismatch between GCMs and climate impact models which need information on spatial scales that the GCMs cannot provide. The method of statistical downscaling is based on physical interaction between atmospheric processes with different spatial scales, in this case between synoptic scale mean sea level pressure (MSLP) fields and local temperature extremes at several stations in southeast Australia. In this study it was found that most of the day-to-day spatial variability of the synoptic circulation over the Australian region can be captured by six principal components. Using the scores of these PCs as multivariate indicators of the circulation a substantial part of the local daily temperature variability could be explained. The inclusion of temperature persistence noticeably improved the performance of the statistical model. The model established and tested with observations is thought to be finally applied to GCM-simulated pressure fields in order to estimate pressure-related changes in local temperature extremes under altered CO₂ conditions. Received: 26 March 1996 / Accepted: 20 September 1996  相似文献   

Reminiscences of my life in science     

Gerald Schubert 《天文和天体物理学研究(英文版)》2019,(4)

With a great deal of humility I attempt in the following to recall important events in my life and in my scientific career of more than five decades. I am not through yet. I continue to do research though, I admit, not with the energy and fervor I once had. Still, I hope to contribute to science in meaningful ways.  相似文献   

Age and origin of groundwater resources in the Ararat Valley,Armenia: a baseline study applying hydrogeochemistry and environmental tracers     

Schubert  Michael  Michelsen  Nils  Schmidt  Axel  Eichenauer  Laura  Knoeller  Kay  Arakelyan  Alexander  Harutyunyan  Lilith  Schüth  Christoph 《Hydrogeology Journal》2021,29(7):2517-2527

Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ²H, δ¹⁸O) and radioactive (³⁵S, ³H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (³⁵S), the detected ³H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.

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Wasserchemie und Stoffwirtschaft     

M. Schubert  J. Kaeding 《洁净——土壤、空气、水》1984,12(2):117-120

For the solving of the most important main tasks of water quality economy, of the supply of drinking water, industrial water and irrigation water without damaging or otherwise detrimental substances we need the available findings and results of specialized research in water chemistry. In the logical continuation of the further development up to the level of maturity for practice, the experts of the engineering disciplines have to be consulted. The design of the sequence of water treatment processes depends on the aims of the tasks set, there being increasing by raised the question concerning the possibilities of the saving and winning of energy and raw materials. — Already in the sphere of production, however, in the interest of environment protection one endeavours to achieve a direct or indirect low-waste or non-waste process design. Finally, possibilities of materials and power economy are discussed by the examples of the treatment of the wastewaters of the chemical industry and of municipal wastewaters.  相似文献   

Measurements of tropospheric OH concentrations: A comparison of field data with model predictions     

D. Perner  U. Platt  M. Trainer  G. Hübler  J. Drummond  W. Junkermann  J. Rudolph  B. Schubert  A. Volz  D. H. Ehhalt  K. J. Rumpel  G. Helas 《Journal of Atmospheric Chemistry》1987,5(2):185-216

Using long path UV absorption spectroscopy we have measured OH concentrations close to the earth's surface. The OH values observed at two locations in Germany during 1980 through 1983 range from 0.7×10⁶ to 3.2×10⁶ cm^-3. Simultaneously we measured the concentrations of O₃, H₂O, NO, NO₂, CH₄, CO, and the light non methane hydrocarbons. We also determined the photolysis rates of O₃ and NO₂. This allows calculations of OH using a zero dimensional time depdendent model. The modelled OH concentrations significantly exceed the measured values for low NO _x concentrations. It is argued that additional, so far unidentified. HO _x loss reactions must be responsible for that discrepancy.  相似文献   

Erhitzungsversuche am Markasit     

Dr. Enno Schubert 《Contributions to Mineralogy and Petrology》1959,6(6):388-398

Zusammenfassung Allen, Crenshaw, Johnston andLarsen (1915) untersuchten den Existenzbereich des Markasits gegenüber thermischer Beanspruchung. Sie konnten eine Modifikationsänderung mit meßbarer Geschwindigkeit his hinunter zur Temperatur von 450° C nachweisen. Umwandlungsversuche bei geringeren Temperaturen waren ergebnislos.Durch Erhitzungsversuche an Erzen von den telethermalen Verdrängungslagerstätten um Aachen wurde gezeigt, daß bei Normaldruck his herab zur Temperatur von etwa 350° C eine Umwandlung mit meßbarer Geschwindigkeit stattfindet. Wahrscheinlich ist also Markasit bei Normaldruck bis 350° C existent gegenüber thermischer Beanspruchung.Die Umwandlungserscheinungen in den verschiedenen Stadien wurden durch Mikrophotographien dargestellt.Als geologisches Thermometer ist das Auftreten von Markasit in natürlichen Paragenesen anwendbar mit folgenden Aussagen:Der mögliche Bildungsbereich der betreffenden Paragenese reicht bei normalem Druck bis zur Temperatur von etwa 350° C.Das Existenzfeld des Markasits gegeniiber rein thermischer Beanspruchung reicht bei normalem Druck bis 350° C, also kann die betreffende Paragenese niemals auf höhere Temperaturen erhitzt gewesen sein.Für die Anregung and fur ihr stets Interesse an meiner Arbeit möchte ich Frau Professor Dr.Schachner and Herrn Doz. Dr.Lindley aufrichtig danken.Auszug aus der Dissertation des Verfassers, TH Aachen 1959.  相似文献   

Der Original-Beerbachit im Odenwald,ein Amphibolit-Hornfels in Pyroxen-Hornfelsfazies     

Siegfried Matthes  Wolfgang Schubert 《Contributions to Mineralogy and Petrology》1971,33(1):62-86

With this petrographic re-investigation of the beerbachite (Chelius, 1892) from Odenwald/Germany geochemical and phase-petrological data are given for the first time.By petrofabric relics (Fig. 7) and geochemical characteristics (Figs. 8–11) is shown that the beerbachite-xenoliths are due to blocks broken down from the surrounding amphibolite series. They are present high grade hornfelses.Beerbachite, porphyroblastic by plagioclase (here porphyroblastic beerbachite, Bbp) (Chelius' Gabbroporphyrit) (Fig. 6) frequently forms marginal zones of beerbachite blocks and is explained as beerbachite-metablastite.Phase relation (Fig. 13) and mineral reactions with increasing metamorphic grade from amphibolite to amphibolite-hornfels (containing hornblende) finally to beerbachite are demonstrated and discussed.The first step may be the mineral reaction: plag_I(An 35–40)+hbl_I+sphene= plag_II(An 50–60)+hbl_II+cpx+opx+magnetite/ilmenite+H₂O. The pyroxene-hornfels facies respectively the orthopyroxene subfacies of the K-feldspar-cordierite-hornfels facies (Winkler, 1967) is only reached with the typical assemblage: plag(An 55–70)-cpx-opx-mt/ilm±(quartz) of beerbachite.On condition that the load correspondends to 3–4 km the maximum temperatures may not have exceeded 720–750° C. This valuation would result from experimental data of Choudhuri and Winkler (1967) of the model reaction: hbl=en+di+an+H₂O, if . The natural conditions will differ from this experimental model because of resp. P _load (p. 81)The very probably required temperature for the mineral assemblage of beerbachite would still be within sub-solidus temperatures of the corresponding model system, according to Fig. 13d. Therefore, the coarse grained plagioclases of Bbp (p. 69) could not be formed from cotectic pockets, too.Finally, convergences and divergences to the beerbachite concept are discussed out of the recent literature.

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Herrn Dr. E. Knauer vom hiesigen Institut danken wir sehr für die Bestimmung des Chemismus zweier Pyroxen-Paare aus Beerbachit bzw. Hornfels mit der Mikrosonde (CAMEGA MS 46), Leihgabe der Deutschen Forschungsgemeinschaft. Den Herren Prof. E. Nickel und Dr. M. Maggetti vom Mineralogischen Institut der Universität Fribourg (Schweiz) und Dr. H. D. Trochim, Mineralogisches Institut der Universität Bochum, verdanken wir Vergleichsproben oder Einsichtnahme in vorhandene Dünnschliffe.  相似文献