The pK1* and pK2* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK1* have been determined from emf measurements for the cell:
Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag
where X is the mole fraction of CO2 in the gas. The values of pK2* have been determined from emf measurements on the cell:
Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag
where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK1* and σ = 0.0070 in lnK2*.Our new results are in good agreement at S = 35 (±0.002 in pK1*and ±0.005 in pK2*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H2|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater. 相似文献
The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).相似文献
Silicic volcanic deposits (>65 wt% SiO2), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines.
At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic
lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically
distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower
concentrations of MgO and higher concentrations of Fe2O3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic
rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K2O/Na2O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K2O/Na2O silicic magmas by fractional crystallization or partial melting of a low K2O/Na2O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme
fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation
of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized
calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen
isotopes and ages of the deposits, are consistent with this model.
Electronic Supplementary Material Supplementary material is available for this article at 相似文献
Seismic, sidescan sonar, bathymetric multibeam and ODP (Ocean Drilling Program) data obtained in the submarine channel between the volcanic islands of Gran Canaria and Tenerife allow to identify constructive features and destructive events during the evolution of both islands. The most prominent constructive features are the submarine island flanks being the acoustic basement of the seismic images. The build-up of Tenerife started following the submarine stage of Gran Canaria because the submarine island flank of Tenerife onlaps the steeper flank of Gran Canaria. The overlying sediments in the channel between Gran Canaria and Tenerife are chaotic, consisting of slumps, debris flow deposits, syn-ignimbrite turbidites, ash layers, and other volcaniclastic rocks generated by eruptions, erosion, and flank collapse of the volcanoes. Volcanic cones on the submarine island flanks reflect ongoing submarine volcanic activity. The construction of the islands is interrupted by large destructive events, especially by flank collapses resulting in giant landslides. Several Miocene flank collapses (e.g., the formation of the Horgazales basin) were identified by combining seismic and drilling data whereas young giant landslides (e.g., the Güimar debris avalanche) are documented by sidescan, bathymetric and drilling data. Sediments are also transported through numerous submarine canyons from the islands into the volcaniclastic apron. Seismic profiles across the channel do not show a major offset of reflectors. The existence of a repeatedly postulated major NE-SW-trending fault zone between Gran Canaria and Tenerife is thus in doubt. The sporadic earthquake activity in this area may be related to the regional stress field or the submarine volcanic activity in this area. Seismic reflectors cannot be correlated through the channel between the sedimentary basins north and south of Gran Canaria because the channel acts as sediment barrier. The sedimentary basins to the north and south evolved differently following the submarine growth of Gran Canaria and Tenerife in the Miocene. 相似文献
Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.
The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO2 (3–10 wt.%) and K2O (1–4 wt.%), but low SiO2 (22–37 wt.%) and Al2O3 (2–6 wt.%). Higher SiO2, Al2O3, Na2O and lower CO2 content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.
The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean. 相似文献