Boron incorporation into mullite     

K. J. Griesser  A. Beran  D. Voll  H. Schneider 《Mineralogy and Petrology》2008,92(3-4):309-320

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria  相似文献   

Quaternary evolution of the Gulf of İzmit (NW Turkey): a sedimentary basin under control of the North Anatolian Fault Zone     

Erdal Dolu  Erkan Gökaşan  Engin Meriç  Mustafa Ergin  Tolga Görüm  Hüseyin Tur  Berkan Ecevitoğlu  Niyazi Avşar  Muhittin Görmüş  Fatmagül Batuk  Buğser Tok  Oktay Çetin 《Geo-Marine Letters》2007,27(6):355-381

The Quaternary evolution of the Gulf of İzmit, situated on the tectonically active North Anatolian Fault Zone (NAFZ), was investigated using seismic reflection, paleontologic, and sediment textural data. On the basis of seismic stratigraphic and sedimentologic-paleontologic interpretations, four depositional units were distinguished within the Plio-Quaternary sequence of the Gulf of İzmit. According to these data, Plio-Quaternary deposits supplied from the northern terrestrial area started to accumulate during a progradational phase, in a south-facing half-graben. A coarse-grained sedimentary unit prograding into the gulf from the south since 200 ka b.p. indicates a dramatic variation in the evolution of the gulf, with the initiation of a new strike-slip fault of the NAFZ and a corresponding uplift of the Armutlu Peninsula in the south of the gulf. During the evolution of this fault from a wide shear zone consisting of right-stepped strike-slip faults and pull-apart basins to a localized principal fault zone, sediments were deposited under the influence of northerly prograding terrestrial and shallow-marine conditions due to relative sea-level fluctuations in the Marmara Sea. During this period, the Gulf of İzmit was invaded mainly by Mediterranean and partly by Black Sea waters. In the latest glacial period, shallow areas in the gulf became subaerially exposed, whereas the central and western sub-basins of the gulf turned into lakes. The present evolution of the Gulf of İzmit is controlled by the after effects of the new rupture of the NAFZ and the estuarine nature of the gulf environment.  相似文献   

Stratigraphy of the sediment infill in Bosphorus Strait: water exchange between the Black and Mediterranean Seas during the last glacial Holocene     

O. Algan  N. Çağatay  A. Tchepalyga  D. Ongan  C. Eastoe  E. Gökaşan 《Geo-Marine Letters》2001,20(4):209-218

The sediment infill over the Paleozoic bedrock in the Bosphorus Strait consists of four sedimentary units which were deposited in the last 26,000 ¹⁴C years B.P. The stratigraphy of these units suggests that this part of the Bosphorus was a freshwater lake between 26,000 and 5,300 ¹⁴C years B.P., depositing sands with a freshwater mollusc fauna of Black Sea neo-euxinian affinity (Dreissena rostriformis, Dreissena polymorpha, and Monodacna pontica). The first appearance of euryhaline Mediterranean molluscs (e.g., Ostrea edulis, Mytilus edulis) was observed at 5,300 ¹⁴C years B.P. in this part of the Bosphorus. Deposition of coarse Mytilus-bank and Ostrea-bank units suggests that the establishment of the present dual-flow regime in the Bosphorus took place at about 4,400 ¹⁴C years B.P.  相似文献   

A sulfur isotope study of volcanogenic massive sulfide deposits of the Eastern Black Sea province,Turkey   总被引：1，自引：0，他引：1  

M. N. Çagatay  C. J. Eastoe 《Mineralium Deposita》1995,30(1):55-66

Kuroko-type massive sulfide deposits of the Eastern Black Sea province of Turkey are related to the Upper Cretaceous felsic lavas and pyroclastic rocks, and associated with clay and carbonate alteration zones in the footwall and hangingwall lithologies. A complete upward-vertical section of a typical orebody consists of a stringer-disseminated sulfide zone composed mainly of pyrite and chalcopyrite; a massive pyrite zone; a massive yellow ore consisting mainly of chalcopyrite and pyrite; a black ore made up mainly of galena and sphalerite with minor amounts of chalcopyrite, bornite, pyrite and various sulfosalts; and a barite zone. Most of the deposits in the province are associated with gypsum in the footwall or hangingwall. The paragenetic sequence in the massive ore is pyrite, sphalerite, chalcopyrite, bornite, galena and various sulfosalts, with some overlap between the mineral phases. Massive, stringer and disseminated sulfides from eight kuroko-type VMS deposits of the Eastern Black Sea province have a ³⁴S range of 0–7 per mil, consistent with the ³⁴S range of felsic igneous rocks. Sulfides in the massive ore at Madenköy (4.3–6.1 per mil) differ isotopically from sulfides in the stringer zone (6.3–7.2 per mil) suggesting a slightly increased input of H₂S derived from marine sulfate with time. Barite and coarse-grained gypsum have a ³⁴S range of 17.7–21.5 per mil, a few per mil higher than the ³⁴S value of contemporaneous seawater sulfate. The deposits may, therefore, have formed in restricted basins in which bacterial reduction of sulfate was taking place. Fine-grained, disseminated gypsum at Kutlular and Tunca has ³⁴S values (2.6–6.1 per mil) overlapping those of ore sulfides, indicating sulfide oxidation during waning stages of hydrothermal activity.  相似文献   

The occurrence of OH absorptions in phenakite—an IR spectroscopic study     

Prof. Dr. A. Beran 《Mineralogy and Petrology》1990,41(2-4):73-79

Summary IR spectra of phenakite single crystals from different localities show a distinct variability in the region of the OH stretching fundamental. Minute hydrous mineral phases (tourmaline, bertrandite) are included in Piracicaba phenakite. Structural OH, ranging up to 0.005 equivalent wt.% H₂O, is characterized by two extremely pleochroic bands centered at 3380 and 3120 cm^–1. On the basis of their pleochroic scheme it is proposed that (O₂(OH)₂) and (O₃(OH)) tetrahedra occur as structural elements, assuming that the vacancies are on Be sites.

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Das Auftreten von OH Absorptionen in Phenakit—eine IR spektroskopische Untersuchung

Zusammenfassung Die IR Spektren von Phenakit-Einkristallen verschiedener Vorkommen zeigen im Bereich der OH-Streckschwingungen eine deutliche Variabilität. Piracicaba Phenakit enthält feinste Einschlüsse von OH-hältigen Mineralphasen (Turmalin, Bertrandit). Strukturell gebundene OH-Gruppen (bis 0,005 äquivalente Gew.% H₂O) sind durch zwei extrem pleochroitische Banden bei 3380 und 3120 cm^–1 charakterisiert. Unter der Annahme von Be-Leerstellen werden aufgrund des Pleochroismus dieser Banden (O₂(OH)₂) und (O₃(OH)) Tetraeder als strukturelle Baueinheiten vorgeschlagen.

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With 3 Figures  相似文献   

Results from a Multi-disciplinary Sedimentary Pilot Study of Tectonic Lake Iznik (NW Turkey) – Geochemistry and Paleolimnology of the Recent Past     

Sven O. Franz  Lorenz Schwark  Cathrin Brüchmann  Burkhard Scharf  Ralf Klingel  Jon D. Van Alstine  Namık Çagatay  Umut B. Ülgen 《Journal of Paleolimnology》2006,35(4):715-736

A limnogeological reconnaissance study was carried out on Lake Iznik, located in the southeast of the Marmara region of Turkey, involving a seismic survey and collection of short sediment cores. This lake is located on the middle branch of the North Anatolian Fault Zone (NAFZ), a transform plate boundary between the Eurasian and Anatolian Plates. It is, therefore, tectonically active and offers an opportunity to investigate the interplay of sedimentary and seismo-tectonic processes, as well as climate change and human impact in the region. Short cores of the three sub-basins, maximum length of 35.5 cm, recovered non-laminated, blackish clays and silts with varying amounts of biogenic and minerogenic (allochthonous, autochthonous) material, which documented almost the last 80 years of deposition and environmental history. High sedimentation rates in the deeper core sections are accompanied by changes in land use (conversion of woodland to farmland) in the northern areas of Lake Iznik, which caused the deposition of more weathered material (high K/Na ratios) and higher contents of Mn in the lake. A tendency towards eutrophic conditions within the last 20 years is indicated by high nutrient content (N, TOC, P), decreasing C/N-ratios, and characteristic diatom and cladoceran associations. Also increased pollution is revealed by higher Pb, Cu, and Zn contents and increased supply of human and animal faeces (high coprostanol content) during the last two decades. But simultaneous lower sedimentation rates towards the core tops complicate the reconstruction of recent and past eutrophication and pollution states of Lake Iznik. This requires an extension of the pilot study and deeper sediment cores, to recover non-anthropogenic influenced sediment levels.  相似文献   

Remote sensing of water depths in shallow waters via artificial neural networks     

Özçelik Ceyhun  Arısoy Yalçın 《Estuarine, Coastal and Shelf Science》2010

Determination of the water depths in coastal zones is a common requirement for the majority of coastal engineering and coastal science applications. However, production of high quality bathymetric maps requires expensive field survey, high technology equipment and expert personnel. Remotely sensed images can be conveniently used to reduce the cost and labor needed for bathymetric measurements and to overcome the difficulties in spatial and temporal depth provision. An Artificial Neural Network (ANN) methodology is introduced in this study to derive bathymetric maps in shallow waters via remote sensing images and sample depth measurements. This methodology provides fast and practical solution for depth estimation in shallow waters, coupling temporal and spatial capabilities of remote sensing imagery with modeling flexibility of ANN. Its main advantage in practice is that it enables to directly use image reflectance values in depth estimations, without refining depth-caused scatterings from other environmental factors (e.g. bottom material and vegetation). Its function-free structure allows evaluating nonlinear relationships between multi-band images and in-situ depth measurements, therefore leads more reliable depth estimations than classical regressive approaches. The west coast of the Foca, Izmir/Turkey was used as a test bed. Aster first three band images and Quickbird pan-sharpened images were used to derive ANN based bathymetric maps of this study area. In-situ depth measurements were supplied from the General Command of Mapping, Turkey (HGK). Two models were set, one for Aster and one for Quickbird image inputs. Bathymetric maps relying solely on in-situ depth measurements were used to evaluate resultant derived bathymetric maps. The efficiency of the methodology was discussed at the end of the paper. It is concluded that the proposed methodology could decrease spatial and repetitive depth measurement requirements in bathymetric mapping especially for preliminary engineering application.  相似文献   

Impact of Overcut on Interaction Between Shield and Ground in the Tunneling with a Double-shield TBM     

Rohola Hasanpour  Jamal Rostami  Yılmaz Özçelik 《Rock Mechanics and Rock Engineering》2016,49(5):2015-2022

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An Integrated Geomechanical Investigation,Multi-Parameter Monitoring and Analyses of Babadağ-Gündoğdu Creep-like Landslide     

Halil Kumsar  Ömer Aydan  Hisataka Tano  Sefer Beran Çelik  Reşat Ulusay 《Rock Mechanics and Rock Engineering》2016,49(6):2277-2299

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P–T–t evolution of eclogite/blueschist facies metamorphism in Alanya Massif: time and space relations with HP event in Bitlis Massif,Turkey     

Mete Çetinkaplan  Amaury Pourteau  Osman Candan  O. Ersin Koralay  Roland Oberhänsli  Aral I. Okay  Fukun Chen  Hüseyin Kozlu  Fırat Şengün 《International Journal of Earth Sciences》2016,105(1):247-281

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