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A pyralspite garnet from an anomalously magnetic concentrate of a pegmatitic cassiterite ore has been investigated using 57Fe nuclear gamma-ray resonance spectroscopy. The quadrupole splitting and isomer shift values of 3.6 mm/s and 1.4 mm/s, respectively, are among the largest observed for Fe2+ ions and indicate a very low covalency of the dodecahedral Fe2+ — O2-bonds. These data support the more recent and lower value (10.2–10.1 kcal/ mole) of White and Moore (1972) for the CFSE of the dodecahedral Fe2+ ion and suggest that the CFSE should be a useful approximation to the site preference energy of Fe2+ for this site.  相似文献   
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Many coastal urban areas and many coastal facilities must be protected against pluvial and marine floods, as their location near the sea is necessary. As part of the development of a Probabilistic Flood Hazard Approach (PFHA), several flood phenomena have to be modelled at the same time (or with an offset time) to estimate the contribution of each one. Modelling the combination and the dependence of several flooding sources is a key issue in the context of a PFHA. As coastal zones in France are densely populated, marine flooding represents a natural hazard threatening the coastal populations and facilities in several areas along the shore. Indeed, marine flooding is the most important source of coastal lowlands inundations. It is mainly generated by storm action that makes sea level rise above the tide. Furthermore, when combined with rainfall, coastal flooding can be more consequent. While there are several approaches to analyse and characterize marine flooding hazard with either extreme sea levels or intense rainfall, only few studies combine these two phenomena in a PFHA framework. Thus this study aims to develop a method for the analysis of a combined action of rainfall and sea level. This analysis is performed on the city of Le Havre, a French urban city on the English Channel coast, as a case study. In this work, we have used deterministic materials for rainfall and sea level modelling and proposed a new approach for estimating the probabilities of flooding.

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