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1.
Azizi  Shahla  Ilderomi  Ali Reza  Noori  Hamid 《Natural Hazards》2021,109(1):145-160
Natural Hazards - Hydrological modeling academic studies have focused on the response to human-caused land use changes. The effects of land use change on flood degree in the catchment basin of...  相似文献   
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This study investigates the values of pH, total dissolved solids (TDS), elevation, oxidative reduction potential (ORP), temperature, and depth, while the concentrations of Br, and potentially harmful metals (PHMs) such as Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe in the groundwater samples. Moreover, geographic information system (GIS), XLSTAT, and IBM SPSS Statistics 20 software were used for spatial distribution modeling, principal component analysis (PCA), cluster analysis (CA), and Quantile-Quantile (Q-Q) plotting to determine groundwater pollution sources, similarity index, and normal distribution reference line for the selected parameters. The mean values of pH, TDS, elevation, ORP, temperature, depth, and Br were 7.2, 322 mg/L, 364 m, 188 mV, 29.6 °C, 70 m, 0.20 mg/L, and PHMs like Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe were 0.38, 0.26, 0.08, 0.27, 0.36, 0.22, 0.04, 0.43 and 0.86 mg/L, respectively. PHMs including Cr (89%), Cd (43%), Mn (23%), Pb (79%), Co (20%), and Fe (91%) exceeded the guideline values set by the world health organization (WHO). The significant R2 values of PCA for selected parameters were also determined (0.62, 0.67, 0.78, 0.73, 0.60, 0.87, ?0.50, 0.69, 0.70, 0.74, ?0.50, 0.70, 0.67, 0.79, 0.59, and ?0.55, respectively). PCA revealed three geochemical processes such as geogenic, anthropogenic, and reducing conditions. The mineral phases of Cd(OH)2, Fe(OH)3, FeOOH, Mn3O4, Fe2O3, MnOOH, Pb(OH)2, Mn(OH)2, MnO2, and Zn(OH)2 (?3.7, 3.75, 9.7, ?5.8, 8.9, ?3.6, 2.2, ?4.6, ?7.7, ?0.9, and 0.003, respectively) showed super-saturation and under-saturation conditions. Health risk assessment (HRA) values for PHMs were also calculated and the values of hazard quotient (HQ), and hazard indices (HI) for the entire study area were increased in the following order: Cd>Ni>Cu>Pb>Mn>Zn>Cr. Relatively higher HQ and HI values of Ni, Cd, Pb, and Cu were greater than one showing unsuitability of groundwater for domestic, agriculture, and drinking purposes. The long-term ingestion of groundwater could also cause severe health concerns such as kidney, brain dysfunction, liver, stomach problems, and even cancer.  相似文献   
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The main aims of the present study are to identify the major factors affecting hydrogeochemistry of groundwater resources in the Marand plain, NW Iran and to evaluate the potential sources of major and trace elements using multivariate statistical analysis such as hierarchical clustering analysis (HCA) and factor analysis (FA). To achieve these goals, groundwater samples were collected in three sampling periods in September 2013, May 2014 and September 2014 and analyzed with regard to ions (e.g., Ca2+, Mg2+, Na+ and K+, HCO3 ?, SO4 2?, Cl?, F? and NO3 ?) and trace metals (e.g., Cr, Pb, Cd, Mn, Fe, Al and As). The piper diagrams show that the majority of samples belong to Na–Cl water type and are followed by Ca–HCO3 and mixed Ca–Na–HCO3. Cross-plots show that weathering and dissolution of different rocks and minerals, ion exchange, reverse ion exchange and anthropogenic activities, especially agricultural activities, influence the hydrogeochemistry of the study area. The results of the FA demonstrate that 6 factors with 81.7% of total variance are effective in the overall hydrogeochemistry, which are attributed to geogenic and anthropogenic impacts. The HCA categorizes the samples into two clusters. Samples of cluster C1, which appear to have higher values of some trace metals like Pb and As, are spatially located at the eastern and central parts of the plain, while samples of cluster C2, which express the salinization of the groundwater, are situated mainly westward with few local exceptions.  相似文献   
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Micromorphological evidences of climatic change in Yazd region, Iran   总被引:1,自引:0,他引:1  
The fact of, present is the key of the past, will help us to use paleosols properties as indicators of the ecological characteristics of past .time, particularly the paleoclimate. In this respect the micro- morphological properties showed to be a very good indicator. Therefore, for investigating of climate change in Ardakan-Yazd plain, Central Iran 9 pedons were digged and described. Yazd has an arid climate with less than 100 mm annual precipitation and more than 22℃ mean annual temperature (Aridic-hyper thermic soil moisture and temperature regions, respectively). Based on the morphological and physicochemical analysis Arglic, Calcic and Gypsic diagnostic horizons have been distinguished in these soils. Thin section studied showed that the illuviated form of clay includes, infillings on channel, coating on pendant, on nodules and on grains, at lower depths and also juxtaposed calcite needles on void argillan at upper part of the profiles. Mineralogical result showed fine clay in arglic horizon, too. Considering depth and forms of these pedofeatures, we concluded that, the observed illuviated clays at lower depth must be the result of the more humid climate of the past, where the carbonates have been removed completely as pendant, nodules or coating to considerable depth, following processes, clay has been dispersed and also trans located to these depths. In contrast to these features, the juxtaposed needle calcite at the shallower depth is probably the result of drier climate of today.  相似文献   
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Like tree rings, high‐resolution soil sampling of low‐permeability (low‐k) zones can be used to evaluate the style of source history at contaminated sites (i.e., historical pattern of concentration and composition vs. time since releases occurred at the interface with the low‐k zone). This is valuable for the development of conceptual site model (CSM) and can serve as an important line of evidence supporting monitored natural attenuation (MNA) as a long‐term remedy. Source histories were successfully reconstructed at two sites at Naval Air Station Jacksonville using a simple one‐dimensional (1D) model. The plume arrival time and historical composition were reconstructed from the time initial releases that were suspected to occur decades earlier. At the first site (Building 106), the source reconstructions showed relatively constant source concentrations, but significant attenuation over time in the downgradient plume in the transmissive zone, suggesting MNA may not be an appropriate remedy if source control is a requirement, but attenuation processes are clearly helping to maintain plume stability and reduce risk. At the second site (Building 780), source concentrations in the transmissive zone showed an approximately a one order of magnitude over time, but apparently less attenuation in the downgradient plume. The source reconstruction method appeared to reflect site remediation efforts (excavation, soil vapor extraction) implemented in the 1990s. Finally, a detailed analysis using molecular biological tools, carbon isotopes, and by‐products suggests that most degradation activity is associated with high‐k zones but not with low‐k zones at these source areas. Overall, the source reconstruction methodology provided insight into historical concentration trends not obtainable otherwise given the limited long‐term monitoring data.  相似文献   
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Contaminant plume classification system based on mass discharge   总被引:1,自引:0,他引:1  
Estimation of mass discharge has become an increasingly valuable analysis technique at sites with contaminated groundwater plumes. We propose a simple plume magnitude classification system based on mass discharge comprised of 10 separate magnitude categories, such as a "Mag 7 plume." This system can be a useful tool for scientists, engineers, regulators, and stakeholders to better communicate site conceptual models, prioritize sites, evaluate plumes both spatially and temporally, and determine potential impacts.  相似文献   
9.
Soil complexity and its multivariable nature restrict the precision of soil maps that are essential tools for soil sustainable management. Most methods developed for reducing impurities of soil map units focus on soil external properties. Taking into account the soil internal properties like geochemical weathering indices could increase the map unit’s purity. However, the compatibility of these indices with Soil Taxonomic Classes has not been studied yet. This study has been performed in a hilly region with different soil types, vegetation and diverse topographic attributes to illustrate the spatial variability of soil weathering indices and their compatibility with Soil Taxonomic Classes. The grid sampling is at 100 m interval. Physico-chemical and total elemental analyses were performed on 184 and 56 soil samples respectively. Eight topographic attributes and 14 common soil development indices were determined. Principal components analysis (PCA) was done to identify the most important components. The results indicated that Morphological Index (MI) was the best index to show the degree of soil development in the studied region. Spatial distribution of Soil Taxonomic Classes showed relatively good compatibility with the first principal component (PC1), Vogt (V) and morphological indices. This study showed that using soil development indices with the conventional methods could be helpful tools in soil survey investigations  相似文献   
10.
Evaluation of Methane Sources in Groundwater in Northeastern Pennsylvania   总被引:1,自引:0,他引:1  
Testing of 1701 water wells in northeastern Pennsylvania shows that methane is ubiquitous in groundwater, with higher concentrations observed in valleys vs. upland areas and in association with calcium‐sodium‐bicarbonate, sodium‐bicarbonate, and sodium‐chloride rich waters—indicating that, on a regional scale, methane concentrations are best correlated to topographic and hydrogeologic features, rather than shale‐gas extraction. In addition, our assessment of isotopic and molecular analyses of hydrocarbon gases in the Dimock Township suggest that gases present in local water wells are most consistent with Middle and Upper Devonian gases sampled in the annular spaces of local gas wells, as opposed to Marcellus Production gas. Combined, these findings suggest that the methane concentrations in Susquehanna County water wells can be explained without the migration of Marcellus shale gas through fractures, an observation that has important implications for understanding the nature of risks associated with shale‐gas extraction.  相似文献   
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