Supercritical gas sorption on moist coals   总被引：2，自引：1，他引：1  

Stuart Day  Richard Sakurovs  Steve Weir 《International Journal of Coal Geology》2008,74(3-4):203-214

The effect of moisture on the CO₂ and CH₄ sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO₂ and CH₄ than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO₂ and CH₄ by the water. Below the limiting moisture content, the CO₂ sorption capacity reduced by about 7.3 kg t^− 1 for each 1% increase in moisture. For CH₄, sorption capacity was reduced by about 1.8 kg t^− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO₂ and CH₄ molecules.  相似文献   

Meadow fragmentation and reproductive output of the SE Asian seagrass Enhalus acoroides     

Jan E. Vermaat  Rene N. Rollon  Cristina Day A. Lacap  Claire Billot  Filipe Alberto  Hildie M.E. Nacorda  Frank Wiegman  Jorge Terrados 《Journal of Sea Research》2004,52(4):201

Flower and fruit production of the abundant, tall, long-lived, dioecious, surface-pollinating seagrass species Enhalus acoroides (L.) Royle were estimated at seven sites in the reef flats off Bolinao (NW Luzon, The Philippines) featuring different fragmentation of the seagrass meadows. Fragmentation of the seagrass meadow was quantified as cover of E. acoroides and all seagrass species present in 20×20 m plots. E. acoroides and overall seagrass cover were correlated positively. The proportion of female flowers of E. acoroides that developed a fruit increased sharply as overall seagrass cover was around 50%. Apparent sex ratio bore no relationship with overall seagrass cover. This threshold-type of relationship suggests that fragmentation of seagrass meadows can have a major effect on the reproductive output of this species. A possible mechanism underlying these results would be a non-linear increase of the efficiency of trapping the surface-dispersed pollen with increasing seagrass canopy density. This provides the first evidence based on real data that fragmentation can affect the population dynamics of seagrass species.  相似文献   

Factors affecting spatial and temporal variability in material exchange between the Southern Everglades wetlands and Florida Bay (USA)     

Martha A. Sutula  Brian C. Perez  Enrique Reyes  Daniel L. Childers  Steve Davis  John W. Day  Jr.  David Rudnick  Fred Sklar 《Estuarine, Coastal and Shelf Science》2003,57(5-6):757-781

Physical and biological processes controlling spatial and temporal variations in material concentration and exchange between the Southern Everglades wetlands and Florida Bay were studied for 2.5 years in three of the five major creek systems draining the watershed. Daily total nitrogen (TN), and total phosphorus (TP) fluxes were measured for 2 years in Taylor River, and ten 10-day intensive studies were conducted in this creek to estimate the seasonal flux of dissolved inorganic nitrogen (N), phosphorus (P), total organic carbon (TOC), and suspended matter. Four 10-day studies were conducted simultaneously in Taylor, McCormick, and Trout Creeks to study the spatial variation in concentration and flux. The annual fluxes of TOC, TN, and TP from the Southern Everglades were estimated from regression equations. The Southern Everglades watershed, a 460-km² area that includes Taylor Slough and the area south of the C-111 canal, exported 7.1 g C m⁻², 0.46 g N m⁻², and 0.007 g P m⁻², annually. Everglades P flux is three to four orders of magnitude lower than published flux estimates from wetlands influenced by terrigenous sedimentary inputs. These low P flux values reflect both the inherently low P content of Everglades surface water and the efficiency of Everglades carbonate sediments and biota in conserving and recycling this limiting nutrient. The seasonal variation of freshwater input to the watershed was responsible for major temporal variations in N, P, and C export to Florida Bay; approximately 99% of the export occurred during the rainy season. Wind-driven forcing was most important during the later stages of the dry season when low freshwater head coincided with southerly winds, resulting in a net import of water and materials into the wetlands. We also observed an east to west decrease in TN:TP ratio from 212:1 to 127:1. Major spatial gradients in N:P ratios and nutrient concentration and flux among the creek were consistent with the westward decrease in surface water runoff from the P-limited Everglades and increased advection of relatively P-rich Gulf of Mexico (GOM) waters into Florida Bay. Comparison of measured nutrient flux from Everglades surface water inputs from this study with published estimates of other sources of nutrients to Florida Bay (i.e. atmospheric deposition, anthropogenic inputs from the Florida Keys, advection from the GOM) show that Everglades runoff represents only 2% of N inputs and 0.5% of P input to Florida Bay.  相似文献   

Springs of Great Britain     

J. B. W. Day 《Environmental Geology》1996,27(2):77-78

Predictably, in a country such as Britain, with its preponderance of consolidated, sedimentary, mainly fissure-flow aquifers, there is a very large number of springs, many of which are, or have been, used for public supply. Migratory springs are a feature of the British (Ur. Cretaceous) Chalk, the most important British aquifer. The Chalk's low specific yield and high capillary moisture retention together give rise to very considerable fluctuations (more than 33 m in some areas) of the unconfined water table. Along the gentle dip slopes of the Chalk (North and South Downs of southern and southeastern England) springs may migrate laterally for several miles, giving rise to seasonal streams locally known as bournes or lavants. However, springs such as at Duncton, West Sussex, at the base of the much steeper scarp slopes of the Chalk, form point sources, the flows from which tend to be relatively steady; such springs commonly supply and are the original reason for the existence of many of the small towns and villages which nestle along the bases of the chalk scarps of Sussex and Kent.Where the Chalk forms coastal cliffs, a number of springs break out at the base of the cliff between high and low tide levels; there are major chalk coastal springs, for instance, at St. Margaret's Bay (Kent) and at Arish Mells, east of Lulworth Cove, Dorset. Such springs are not used for direct supply (their salinity is usually too high) but are indicators of the presence of local reserves of groundwater for possible future development.  相似文献   

Evolved mare basalt magmatism, high Mg/Fe feldspathic crust, chondritic impactors, and the petrogenesis of Antarctic lunar breccia meteorites Meteorite Hills 01210 and Pecora Escarpment 02007     

James M.D. Day  Christine Floss  Lawrence A. Taylor  Mahesh Anand  Allan D. Patchen 《Geochimica et cosmochimica acta》2006,70(24):5957-5989

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Ocean-bottom seismograph tomographic experiments—a consideration of acquisition geometries vs. resources     

Christine Peirce  Anthony J. Day 《Geophysical Journal International》2002,151(2):543-565

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Ritter Island Volcano—lateral collapse and the tsunami of 1888     

Steven N. Ward  Simon Day 《Geophysical Journal International》2003,154(3):891-902

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Local provenance in rehabilitation of degraded landscapes: a case study from the Hawkesbury–Nepean catchment, Australia     

Shelley Burgin  J Carson  B Maheshwari 《Area》2005,37(3):324-331

Throughout Australia thousands of volunteers are engaged in Landcare projects that should help rehabilitate degraded landscapes. Many of these projects involve tree planting, but their seed is not necessarily of local provenance. Based on a survey of 85 Landcare groups working in the Hawkesbury–Nepean catchment, data were collected about Landcare groups' knowledge of their seed source, understanding of local provenance and the ecosystem in which they were planting trees and the source of funding for their projects. The findings from the study indicate that about one in five (21%) of the groups surveyed that introduced plant material were not aware of local provenance issues. Indirect indications were that a large number of Landcare groups state-wide may be doing more harm than good to the landscape while trying to rehabilitate it. The data also showed that one in seven (13%) of the groups funded by the Australian Government through the Natural Heritage Trust (NHT) had limited awareness of local provenance issues. With millions of dollars being spent on 'works on the ground', it would be prudent to allocate some funds to document and monitor current Landcare activities, so that the environmental outcomes can be quantified and more effective Landcare policies can be developed in the future.  相似文献   

Pre‐ and post‐impoundment nitrogen in the lower Missouri River          下载免费PDF全文

Dale W. Blevins  Donald H. Wilkison  Shelley L. Niesen 《水文研究》2014,28(4):2535-2549

Large water‐sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre‐impoundment and post‐impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20^th century, carcass waste, stock‐yard manure, and untreated human wastes measurably increased ammonia and organic‐nitrogen concentrations during low flows. Average total‐nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate‐organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended‐sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20^th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post‐impoundment period. If strategies to decrease total‐nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate‐reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   

Temperature evolution in the presence of anisotropic stresses     

Megandhren Govender  Adhir Maharaj  Darren Lortan  David Day 《Astrophysics and Space Science》2018,363(8):165

In a recent paper by Das et al. (Astrophys. Space Sci. 361:99, 2016) it was shown that the sign of the anisotropy parameter plays a pivotal role in determining the time of formation of the horizon of a collapsing radiating star. Spurred on by this observation we investigate the impact of the (an)isotropy featured in the (Das et al. in Astrophys. Space Sci. 361:99, 2016) collapsing model on the temperature profiles of the evolving system. We show that the temperature within the stellar interior is increased as the anisotropy in the pressure grows. Relaxational effects due to heat dissipation within the core further enhances the temperature at each interior point of the stellar distribution.  相似文献