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1.
Amaelle Landais Valérie Masson-Delmotte Jean Jouzel Dominique Raynaud Sigfus Johnsen Christof Huber Markus Leuenberger Jakob Schwander Bénédicte Minster 《Climate Dynamics》2006,26(2-3):273-284
The mechanisms involved in the glacial inception are still poorly constrained due to a lack of high resolution and cross-dated
climate records at various locations. Using air isotopic measurements in the recently drilled NorthGRIP ice core, we show
that no evidence exists for stratigraphic disturbance of the climate record of the last glacial inception (∼123–100 kyears
BP) encompassing Dansgaard–Oeschger events (DO) 25, 24 and 23, even if we lack sufficient resolution to completely rule out
disturbance over DO 25. We quantify the rapid surface temperature variability over DO 23 and 24 with associated warmings of
10±2.5 and 16±2.5°C, amplitudes which mimic those observed in full glacial conditions. We use records of δ18O of O2 to propose a common timescale for the NorthGRIP and the Antarctic Vostok ice cores, with a maximum uncertainty of 2,500 years,
and to examine the interhemispheric sequence of events over this period. After a synchronous North–South temperature decrease,
the onset of rapid events is triggered in the North through DO 25. As for later events, DO 24 and 23 have a clear Antarctic
counterpart which does not seem to be the case for the very first abrupt warming (DO 25). This information, when added to
intermediate levels of CO2 and to the absence of clear ice rafting associated with DO 25, highlights the uniqueness of this first event, while DO 24
and 23 appear similar to typical full glacial DO events. 相似文献
2.
Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 μM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations. 相似文献
3.
Summary Barylite has been identified for the first time in Greenland in several specimens from the nepheline syenite pegmatite pockets at Narssârssuk. The crystals are orthorhombic, showing the forms {100}, {210} and {201}, and form thin plates parallel to {100}. Electron microprobe analysis and emission spectrography show a composition close to the ideal formula. The refined unit cell paramters are:a=9.835(2) Å,b=11.654(3) Å andc=4.673(1) Å. The barylite is biaxial negative, 2V
=66o±2o,n
=1.694,n
= 1.697 andn
calc.=1.698.
Das erste grönländische Vorkommen des seltenen Minerales Barylith
Zusammenfassung Der seltene Barylith wurde zum ersten Mal in Grönland in verschiedenen Proben aus Nephelin-Syenit-Pegmatit-Drusen bei Narssârssuk identifiziert. Die Kristalle sind orthorhombisch mit den Formen {100}, {210} und {201}, sie bilden dünne Tafeln nach {100}. Elektronensonden-Analyse und Emissions-Spektrographie ergeben eine chemische Zussammensetzung, die der Idealform nahekommt. Die verfeinerten Zellparameter sind folgende:a=9,835(2) Å,b=11,654(3) Å undc=4,673(1) Å. Barylith ist zweiachsig negativ, 2V =66o±2o,n =1,694,n =1.697 undn calc.= 1,698.相似文献
4.
Bhoopesh Mishra Maxim Boyanov Shelly D. Kelly Jeremy B. Fein 《Geochimica et cosmochimica acta》2010,74(15):4219-9603
Bulk Cd adsorption isotherm experiments, thermodynamic equilibrium modeling, and Cd K edge EXAFS were used to constrain the mechanisms of proton and Cd adsorption to bacterial cells of the commonly occurring Gram-positive and Gram-negative bacteria, Bacillus subtilis and Shewanella oneidensis, respectively. Potentiometric titrations were used to characterize the functional group reactivity of the S. oneidensis cells, and we model the titration data using the same type of non-electrostatic surface complexation approach as was applied to titrations of B. subtilis suspensions by Fein et al. (2005). Similar to the results for B. subtilis, the S. oneidensis cells exhibit buffering behavior from approximately pH 3-9 that requires the presence of four distinct sites, with pKa values of 3.3 ± 0.2, 4.8 ± 0.2, 6.7 ± 0.4, and 9.4 ± 0.5, and site concentrations of 8.9(±2.6) × 10−5, 1.3(±0.2) × 10−4, 5.9(±3.3) × 10−5, and 1.1(±0.6) × 10−4 moles/g bacteria (wet mass), respectively. The bulk Cd isotherm adsorption data for both species, conducted at pH 5.9 as a function of Cd concentration at a fixed biomass concentration, were best modeled by reactions with a Cd:site stoichiometry of 1:1. EXAFS data were collected for both bacterial species as a function of Cd concentration at pH 5.9 and 10 g/L bacteria. The EXAFS results show that the same types of binding sites are responsible for Cd sorption to both bacterial species at all Cd loadings tested (1-200 ppm). Carboxyl sites are responsible for the binding at intermediate Cd loadings. Phosphoryl ligands are more important than carboxyl ligands for Cd binding at high Cd loadings. For the lowest Cd loadings studied here, a sulfhydryl site was found to dominate the bound Cd budgets for both species, in addition to the carboxyl and phosphoryl sites that dominate the higher loadings. The EXAFS results suggest that both Gram-positive and Gram-negative bacterial cell walls have a low concentration of very high-affinity sulfhydryl sites which become masked by the more abundant carboxyl and phosphoryl sites at higher metal:bacteria ratios. This study demonstrates that metal loading plays a vital role in determining the important metal-binding reactions that occur on bacterial cell walls, and that high affinity, low-density sites can be revealed by spectroscopy of biomass samples. Such sites may control the fate and transport of metals in realistic geologic settings, where metal concentrations are low. 相似文献
5.
Independent calendar year chronologies are a basic requirement for the establishment of high resolution land-ice teleconnections.
The annually laminated Meerfelder Maar record provides both an independent chronology, established by varve counting, and
high resolution lithological proxy data for the period of the last Glacial/Interglacial transition. These data reveal a series
of four periods of climatic deterioration coinciding with negative isotopic deviations in the GRIP record signal, thus demonstrating
the synchronicity of environment changes in Western Germany and temperature shifts in Greenland. The terrestrial data supports
a further sub-division of the event stratigraphy based on the GRIP core, by introducing the cold event GI-1c2 between 13 500
and 13 400 calendar years BP. Multiproxy analyses reveal that the environmental response at Meerfelder Maar was not linear
throughout the Lateglacial but was modified by local processes. A change in the response of the lake environment to climate
deterioration was observed during sub-stage GI-1b (Gerzensee oscillation), the only event with gradual rather than abrupt
transitions. The two-fold character of the Younger Dryas as seen in the GRIP record is more pronounced in the Meerfelder Maar
record. This lithological signal occurred with a delay of 60 years to the GRIP signal, and has been linked to a shift in the
catchment. It is proposed that the trigger for this shift was a trend towards a more humid second half of the Younger Dryas.
Received: 21 May 1999 / Accepted: 18 August 1999 相似文献
6.
Rate coefficients for the association reactions of NO+ ions with N2 and CO2, O2+ with N2, and N+ and N2+ with N2 have been determined as a function of gas temperature in a laboratory experiment employing a variable-temperature drift-tube apparatus. The measured rate coefficients were fitted to power laws of the form where the exponents x ranged from 2.2 to 4.3. The strong temperature dependence observed in the case of the reaction of NO+ with N2 (x = 4.3) supports the thesis by Arnold et al. (1979) that the temperature variability of D-region ion densities is a result of this reaction step in the ion clustering sequence. 相似文献
7.
Jeffrey A. Macdonald Manfred A. Biondi Rainer Johnsen 《Planetary and Space Science》1984,32(5):651-654
The dissociative recombination coefficients α for capture of electrons by H3+ and H5+ ions have been determined as a function of electron temperature Te using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures Tu+ = Tn = 240 K, the coefficient α (H3+) is found to vary slowly with Te at first, decreasing from 1.6 × 10?7 cm3/s at Te = 240 K to 1.2 × 10?7 cm3/s at Te = 500 K, thereafter falling as Te?1 over the range 500 K ? Te, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T+ = Tn = 128 K, the coefficient α(H5+) is found to be (1.8 ± 0.3) × 10?6 [Te(K)/300]?0.69 cm3/s over the range 128 K ? Te ? 3000 K, with a more rapid decrease, as Te?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on. 相似文献
8.
A whole-core injection method was used to determine depth-related rates of microbial mineralization of (14)C-phenanthrene added to both contaminated and clean marine sediments of Puget Sound, WA. For 26-day incubations under micro-aerobic conditions, conversions of (14)C-phenanthrene to (14)CO(2) in heavily PAH-contaminated sediments from two sites in Eagle Harbor were much higher (up to 30%) than those in clean sediments from nearby Blakely Harbor (<3%). The averaged (14)C-phenanthrene degradation rates in the surface sediment horizons (0-3 cm) were more rapid (2-3 times) than in the deeper sediment horizons examined (>6 cm), especially in the most PAH polluted EH9 site. Differences in mineralization were associated with properties of the sediments as a function of sediment depth, including grain-size distribution, PAH concentration, total organic matter and total bacterial abundance. When strictly anaerobic incubations (in N(2)/H(2)/CO(2) atmosphere) were used, the phenanthrene biodegradation rates at all sediment depths were two times slower than under micro-aerobic conditions, with methanogenesis observed after 24 days. The main rate-limiting factor for phenanthrene degradation under anaerobic conditions appeared to be the availability of suitable electron acceptors. Addition of calcium sulfate enhanced the first order rate coefficient (k(1) increased from 0.003 to 0.006 day(-1)), whereas addition of soluble nitrate, even at very low concentration (<0.5 mM), inhibited mineralization. Long-term storage of heavily polluted Eagle Harbor sediment as intact cores under micro-aerobic conditions also appeared to enhance anaerobic biodegradation rates (k(1) up to 0.11 day(-1)). 相似文献
9.
Cessation of the Norwegian drift net fishery: changes observed in Norwegian and Russian populations of Atlantic salmon 总被引：3，自引：2，他引：1
10.
A significant amount of marine debris has accumulated in the North Pacific Central Gyre (NPCG). The effects on larger marine organisms have been documented through cases of entanglement and ingestion; however, little is known about the effects on lower trophic level marine organisms. This study is the first to document ingestion and quantify the amount of plastic found in the gut of common planktivorous fish in the NPCG. From February 11 to 14, 2008, 11 neuston samples were collected by manta trawl in the NPCG. Plastic from each trawl and fish stomach was counted and weighed and categorized by type, size class and color. Approximately 35% of the fish studied had ingested plastic, averaging 2.1 pieces per fish. Additional studies are needed to determine the residence time of ingested plastics and their effects on fish health and the food chain implications. 相似文献