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1.
We present an analysis of X-ray and ultraviolet (UV) data of the dwarf nova VW Hyi that were obtained with XMM–Newton during the quiescent state. The X-ray spectrum indicates the presence of an optically thin plasma in the boundary layer that cools as it settles on to the white dwarf. The plasma has a continuous temperature distribution that is well described by a power law or a cooling flow model with a maximum temperature of 6–8 keV. We estimate from the X-ray spectrum a boundary layer luminosity of  8 × 1030 erg s-1  , which is only 20 per cent of the disc luminosity. The rate of accretion on to the white dwarf is  5 × 10−12 M yr−1  , about half of the rate in the disc. From the high-resolution X-ray spectra, we estimate that the X-ray emitting part of the boundary layer is rotating with a velocity of 540 km s−1, which is close to the rotation velocity of the white dwarf but is significantly smaller than the Keplerian velocity. We detect a 60-s quasi-periodic oscillation of the X-ray flux, which is likely to be due to the rotation of the boundary layer. The X-ray and the UV flux show strong variability on a time-scale of ∼1500 s. We find that the variability in the two bands is correlated and that the X-ray fluctuations are delayed by ∼100 s. The correlation indicates that the variable UV flux is emitted near the transition region between the disc and the boundary layer and that accretion rate fluctuations in this region are propagated to the X-ray emitting part of the boundary layer within ∼100 s. An orbital modulation of the X-ray flux suggests that the inner accretion disc is tilted with respect to the orbital plane. The elemental abundances in the boundary layer are close to their solar values.  相似文献   
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Supercritical gas sorption on moist coals   总被引:2,自引:1,他引:1  
The effect of moisture on the CO2 and CH4 sorption capacity of three bituminous coals from Australia and China was investigated at 55 °C and at pressures up to 20 MPa. A gravimetric apparatus was used to measure the gas adsorption isotherms of coal with moisture contents ranging from 0 to about 8%. A modified Dubinin–Radushkevich (DR) adsorption model was found to fit the experimental data under all conditions. Moisture adsorption isotherms of these coals were measured at 21 °C. The Guggenheim–Anderson–de Boer (GAB) model was capable of accurately representing the moisture isotherms over the full range of relative pressures.Moist coal had a significantly lower maximum sorption capacity for both CO2 and CH4 than dry coal. However, the extent to which the capacity was reduced was dependent upon the rank of the coal. Higher rank coals were less affected by the presence of moisture than low rank coals. All coals exhibited a certain moisture content beyond which further moisture did not affect the sorption capacity. This limiting moisture content was dependent on the rank of the coal and the sorbate gas and, for these coals, corresponded approximately to the equilibrium moisture content that would be attained by exposing the coal to about 40–80% relative humidity. The experimental results indicate that the loss of sorption capacity by the coal in the presence of water can be simply explained by volumetric displacement of the CO2 and CH4 by the water. Below the limiting moisture content, the CO2 sorption capacity reduced by about 7.3 kg t− 1 for each 1% increase in moisture. For CH4, sorption capacity was reduced by about 1.8 kg t− 1 for each 1% increase in moisture.The heat of sorption calculated from the DR model decreased slightly on addition of moisture. One explanation is that water is preferentially attracted to high energy adsorption sites (that have high energy by virtue of their electrostatic nature), expelling CO2 and CH4 molecules.  相似文献   
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In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L−1 and dissolved manganese reached 25 nmol L−1. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L−1 and dissolved manganese concentrations were less than 5 nmol L−1. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L−1, and dissolvable iron concentrations of 12–20 nmol L−1 in the upper 100 m in the north, compared to 3.5–2 nmol L−1 Mn and 0.6 nmol L−1 Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L−1 dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L−1 dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.  相似文献   
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Physical and biological processes controlling spatial and temporal variations in material concentration and exchange between the Southern Everglades wetlands and Florida Bay were studied for 2.5 years in three of the five major creek systems draining the watershed. Daily total nitrogen (TN), and total phosphorus (TP) fluxes were measured for 2 years in Taylor River, and ten 10-day intensive studies were conducted in this creek to estimate the seasonal flux of dissolved inorganic nitrogen (N), phosphorus (P), total organic carbon (TOC), and suspended matter. Four 10-day studies were conducted simultaneously in Taylor, McCormick, and Trout Creeks to study the spatial variation in concentration and flux. The annual fluxes of TOC, TN, and TP from the Southern Everglades were estimated from regression equations. The Southern Everglades watershed, a 460-km2 area that includes Taylor Slough and the area south of the C-111 canal, exported 7.1 g C m−2, 0.46 g N m−2, and 0.007 g P m−2, annually. Everglades P flux is three to four orders of magnitude lower than published flux estimates from wetlands influenced by terrigenous sedimentary inputs. These low P flux values reflect both the inherently low P content of Everglades surface water and the efficiency of Everglades carbonate sediments and biota in conserving and recycling this limiting nutrient. The seasonal variation of freshwater input to the watershed was responsible for major temporal variations in N, P, and C export to Florida Bay; approximately 99% of the export occurred during the rainy season. Wind-driven forcing was most important during the later stages of the dry season when low freshwater head coincided with southerly winds, resulting in a net import of water and materials into the wetlands. We also observed an east to west decrease in TN:TP ratio from 212:1 to 127:1. Major spatial gradients in N:P ratios and nutrient concentration and flux among the creek were consistent with the westward decrease in surface water runoff from the P-limited Everglades and increased advection of relatively P-rich Gulf of Mexico (GOM) waters into Florida Bay. Comparison of measured nutrient flux from Everglades surface water inputs from this study with published estimates of other sources of nutrients to Florida Bay (i.e. atmospheric deposition, anthropogenic inputs from the Florida Keys, advection from the GOM) show that Everglades runoff represents only 2% of N inputs and 0.5% of P input to Florida Bay.  相似文献   
8.
The west-central Florida inner shelf represents a transition between the quartz-dominated barrier-island system and the carbonate-dominated mid-outer shelf. Surface sediments exhibit a complex distribution pattern that can be attributed to multiple sediment sources and the ineffectiveness of physical processes for large-scale sediment redistribution. The west Florida shelf is the submerged extension of the Florida carbonate platform, consisting of a limestone karst surface veneered with a thin unconsolidated sediment cover. A total of 498 surface sediment samples were collected on the inner shelf and analyzed for texture and composition. Results show that sediment consists of a combination of fine quartz sand and coarse, biogenic carbonate sand and gravel, with variable but subordinate amounts of black, phosphorite-rich sand. The carbonate component consists primarily of molluskan fragments. The distribution is patchy and discontinuous with no discernible pattern, and the transition between sediment types is generally abrupt. Quartz-rich sediment dominates the inner 15 km north of the entrance into Tampa Bay, but south of the Bay is common only along the inner 3 km. Elsewhere, carbonate-rich sediment is the predominate sediment type, except where there is little sediment cover, in which cases black, phosphorite-rich sand dominates. Sediment sources are likely within, or around the periphery of the basin. Fine quartz sand is likely reworked from coastal units deposited during Pleistocene sea-level high stands. Carbonate sand and gravel is produced by marine organisms within the depositional basin. The black, phosphorite-rich sand likely originates from the bioerosion and reworking of the underlying strata that irregularly crop out within the study area. The distribution pattern contains elements of both storm- and tide-dominated siliciclastic shelves, but it is dictated primarily by the sediment source, similar to some carbonate systems. Other systems with similar sediment attributes include cool-water carbonate, sediment-starved, and mixed carbonate/siliciclastic systems. This study suggests a possible genetic link among the three systems.  相似文献   
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This paper presents a simple and effective approach that incorporates single-frequency, L1 time-differenced GPS carrier phase (TDCP) measurements without the need of ambiguity resolution techniques and the complexity to accommodate the delayed-state terms. Static trial results are included to illustrate the stochastic characteristics and effectiveness of the TDCP measurements in controlling position error growth. The formulation of the TDCP observation model is also described in a 17-state tightly-coupled GPS/INS iterative, extended Kalman filter (IEKF) approach. Preliminary land vehicle trial results are also presented to illustrate the effectiveness of the TDCP which provides sub-meter positional accuracies when operating for more than 10 min.  相似文献   
10.
Agricultural Census data is summarised over spatially coarse reporting units for reasons of farm confidentiality. This is problematic for research at a local level. This article describes an approach combining dasymetric and volume preserving techniques to create a national land use dataset at 1 km2 resolution. The results for an English county are compared with contemporaneous aggregated habitat data. The results show that the accurate estimates of local agricultural land use (Arable and Grass) patterns can be estimated when individual 1 km squares are combined into blocks of > 9 squares, thereby providing local estimates of agricultural land use. This in turn allows more detailed modelling of land uses related to specific livestock and cropping activities. The dataset created by this work has been subject to extensive external validation through its incorporation into a number of other national models: nitrate leaching (e.g. MAGPIE, NEAP‐N), waste, and pathogen modelling related to agricultural activity.  相似文献   
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