Understanding contaminant transport in clay-containing soils is critical for accurate prediction of the travel distances of contaminants and for the design and implementation of corresponding remediation plans. This study examined the breakthrough behavior of methylene blue (MB) through sand-illite mixtures using laboratory soil-column experiments at five inlet concentrations, three flow rates, and five illite contents. Kinetic and equilibrium adsorption tests were performed to evaluate the maximum adsorption capacities of the sand and illite used in the soil-column experiments. In addition, the bed efficiency, MB saturation, and adsorption rate were calculated to quantitatively describe the observed breakthrough curves. The observed breakthrough curves, bed efficiencies, MB saturations, and adsorption rates in this study demonstrated the presence of a threshold illite content of ~10% for the adsorption efficiency of contaminants. This implies the need to evaluate the threshold clay content for accurate predictions of contaminant transport through gap-graded clay-containing soils.
Approximately 1700 Pg of soil carbon (C) are stored in the northern circumpolar permafrost zone, more than twice as much C than in the atmosphere. The overall amount, rate, and form of C released to the atmosphere in a warmer world will influence the strength of the permafrost C feedback to climate change. We used a survey to quantify variability in the perception of the vulnerability of permafrost C to climate change. Experts were asked to provide quantitative estimates of permafrost change in response to four scenarios of warming. For the highest warming scenario (RCP 8.5), experts hypothesized that C release from permafrost zone soils could be 19–45 Pg C by 2040, 162–288 Pg C by 2100, and 381–616 Pg C by 2300 in CO2 equivalent using 100-year CH4 global warming potential (GWP). These values become 50 % larger using 20-year CH4 GWP, with a third to a half of expected climate forcing coming from CH4 even though CH4 was only 2.3 % of the expected C release. Experts projected that two-thirds of this release could be avoided under the lowest warming scenario (RCP 2.6). These results highlight the potential risk from permafrost thaw and serve to frame a hypothesis about the magnitude of this feedback to climate change. However, the level of emissions proposed here are unlikely to overshadow the impact of fossil fuel burning, which will continue to be the main source of C emissions and climate forcing. 相似文献
Satellite-based measurements of aerosols are one of the most effective ways to understand the role of aerosols in climate in terms of spatial and temporal variability. In the present study, we attempted to analyse spatial and temporal variations of satellite derived aerosol optical depth (AOD) over Indian region using moderate resolution imaging spectrometer over a period of 2001–2011. Due to its vast spatial extent, Indian region and adjacent oceanic regions are divided into different zones for analysis. The land mass is sub divided into five different zones such as Indo Gangetic Plain (IGP), Indian mainland, North Eastern India (NE), South India-1 (SI-1), South India-2 (SI-2). Oceanic areas are divided into Arabian Sea and Bay of Bengal. Arabian Sea is further divided as three zones viz. Northern AS (NAS), Central AS (CAS) and Eastern AS (EAS) zones. Bay of Bengal is divided as North BoB (NBoB), West BoB (WBoB), Central BoB (CBoB), and East BoB (EBoB). The study revealed that among all the land regions, IGP showed the highest peak AOD value (0.52 ± 0.17) while SI-2 showed the lower values of AOD in all the months compared to all India average. The maximum AOD is observed during premonsoon season for all regions. During the winter, average AOD levels were substantially lower than the summer averages. Peak of aerosol loading (0.35 ± 0.159) is observed in March over NE region, whereas in all other regions, peak is observed during May. Frequency distribution of long term AOD (<0.2, 0.3–0.5, >0.5) shows a shift of frequency distribution of AOD from <0.3 to 0.3–0.5 during the study period in all regions except IGP. In IGP shift of frequency of AOD values occurs from 0.3–0.5 to >0.5. Oceanic areas also shows seasonal variation of AOD. Over Arabian Sea, high AOD values with greater variations were observed in summer monsoon season while in Bay of Bengal it is observed during winter monsoon. This is due to the high wind speed prevailing in Arabian Sea during monsoon season which results in production of more sea salt aerosol. Highest AOD values are observed over NAS during monsoon season and over NBOB during winter season. Lowest AOD values with its lower variations observed in both the central region of Arabian Sea and Bay of Bengal. 相似文献