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1.
Carbon isotopic fractionation in lipids from methanotrophic bacteria: relevance for interpretation of the geochemical record of biomarkers 总被引：11，自引：0，他引：11
Experiments with cultured aerobic methane oxidising bacteria confirm that their biomarker lipids will be significantly depleted in 13C compared to the substrate. The methanotrophic bacteria Methylococcus capsulatus and Methylomonas methanica, grown on methane and using the RuMP cycle for carbon assimilation, show maximum 13C fractionation of approximately 30% in the resultant biomass. In M. capsulatus, the maximum fractionation is observed in the earliest part of the exponential growth stage and decreases to approximately 16% as cells approach stationary phase. This change may be associated with a shift from the particulate form to the soluble form of the methane monooxygenase enzyme. Less than maximum fractionation is observed when cells are grown with reduced methane availability. Biomass of M. capsulatus grown on methanol was depleted by 9% compared to the substrate. Additional strong 13C fractionation takes place during polyisoprenoid biosynthesis in methanotrophs. The delta 13C values of individual hopanoid and steroid biomarkers produced by these organisms were as much as l0% more negative than total biomass. In individual cultures, squalene was 13C-enriched by as much as 14% compared to the triterpane skeleton of bacteriohopaneaminopentol. Much of the isotopic dispersion in lipid metabolites could be attributed to shifts in their relative abundances, combined with an overall reduction in fractionation during the growth cycle. In cells grown on methanol, where there was no apparent effect of growth stage on overall fractionation there were still significant isotopic differences between closely related lipids including a 5.3% difference between the hopane and 3 beta-methylhopane skeletons. Hopane and sterane polyisoprenoids were also 13C-depleted compared to fatty acids. These observations have significant implications for the interpretation of specific compound isotopic signatures now being measured for hydrocarbons and other lipids present in sediments and petroleum. In particular, biomarker lipids produced by a single organism do not necessarily have the same carbon isotopic composition. 相似文献
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Late Weichselian glaciation history of the northern North Sea 总被引：8，自引：1，他引：8
HANS PETTER SEJRUP HAFLIDI HAFLIDASON INGE AARSETH EDWARD KING CARL FREDRIK FORSBERG DAVID LONG KÅRE ROKOENGEN 《Boreas: An International Journal of Quaternary Research》1994,23(1):1-13
Based on new data from the Fladen, Sleipner and Troll areas, combined with earlier published results, a glaciation curve for the Late Weichselian in the northern North Sea is constructed. The youngest date on marine sedimentation prior to the late Weichselian maximum ice extent is 29.4 ka BP. At this time the North Sea and probably large parts of southern Norway were deglaciated (corresponding to the Alesund interstadial in western Norway). In a period between 29.4 and c. 22 ka BP, the northern North Sea experienced its maximum Weichselian glaciation with a coalescing British and Scandinavian ice sheet. The first recorded marine inundation is found in the Fladen area where marine sedimentation started close to 22 ka BP. After this the ice fronts receded both to the east and west. The North Sea Plateau, and possibly parts of the Norwegian Trench, were ice-free close to 19.0 ka, and after this a short readvance occurred in this area. This event is correlated with the advance recorded at Dimlington, Yorkshire, and the corresponding climatostratigraphic unit is denoted the Dimlington Stadial (18.5 ka to 15.1 ka). The Norwegian Trench was deglaciated at 15.1 ka in the Troll area. The data from the North Sea, together with the results from Andwa, northern Norway (Vorren et al . 1988; Møller et al . 1992), suggest that the maximum extent of the last glaciation along the NW-European seaboard from the British Isles to northern Norway was prior to c . 22 ka BP. 相似文献
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RJ Andres WI Rose RE Stoiber SN Williams O Matías R Morales 《Bulletin of Volcanology》1993,55(5):379-388
Measurements of the sulfur dioxide (SO2) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO2 emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO2 emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO2 emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO2 emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO2 emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO2. Santiaguito and Pacaya, together, emit 6% of the total annual SO2 emitted by continuously erupting volcanoes.Even though SO2 measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO2 emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society. 相似文献
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Quaternary geology and deglaciation of the continental shelf off Troms, north Norway 总被引：1，自引：0，他引：1
The study is based mainly on 4700 km shallow seismic profiling, soil mechanical, and micropaleontological analyses from forty localities, and seven radiocarbon datings. Six foraminiferal assemblages are recognized. The thickness of Quaternary deposits ranges from sparse to more than 200 m. They consist of top sand, soft sensitive clay, and glacial drift divided into four seismic stratigraphic units. The oldest unit, which is the thickest and most extensive, is built up of various sediments and is partly eroded, especially in the southern part. The remaining units occur as three complex linear belts running broadly parallel to the present coast and were deposited during deglaciation. Dating of the outer unit, the Nordvestsnaget Drift, suggests a maximum age of 13,300 years B.P., and datings from the top of the middle unit, the Mulegga Drift, have given a minimum age of about 12,200 years B.P. Seismic stratigraphy shows that the inner unit, the Havbrobakken Drift, is younger than the Mulegga Drift, but no datings have been obtained so far. 相似文献
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Neal S. Gupta George D. Cody O. Erik Tetlie Derek E.G. Briggs Roger E. Summons 《Organic Geochemistry》2009,40(5):589-594
Diagenetic alteration is critical for the preservation of fossil cuticles of plant and animal origin and to the formation of kerogen. The process takes place over millions of years, but the stage at which it is initiated is not known. Laboratory decay experiments were carried out on shrimps, scorpions and cockroaches to monitor changes in the chitin–protein of the arthropod cuticle and associated lipids. The cockroach and scorpion exoskeleton remained largely unaltered morphologically, but the shrimp experienced rapid decomposition within a month, which progressed through the 44 week duration of the experiment as revealed using electron microscopy. Mass spectrometry and 13C NMR (nuclear magnetic resonance) spectroscopy revealed the association of an n-alkyl component with labile lipids, such as fatty acids with up to 24 carbon atoms, which were incorporated into the decaying macromolecule. The scorpion and cockroach cuticle did not reveal the incorporation of additional lipids, indicating that decay is important in initiating in situ lipid association. This experiment provides evidence that lipids can become associated with carbohydrate and proteinaceous macromolecules during the very early stages of decay, representing the first stage in the transformation process that contributes to the aliphatic rich composition ubiquitous in organic fossils and kerogen. 相似文献
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James P. Sáenz Stuart G. Wakeham Timothy I. Eglinton Roger E. Summons 《Organic Geochemistry》2011,42(11):1351-1362
The abundance and structural diversity of bacteriohopanepolyols (BHPs) was examined in three marine pelagic environments that are characterized by strong vertical redox gradients and water column suboxia or anoxia. The abundance and, in most instances, structural diversity of BHPs was highest at depths where conditions were suboxic or anoxic. However, the majority of the BHP structures that were identified are environmentally cosmopolitan and their biological sources are presently not well constrained. An isomer of bacteriohopanetetrol (denoted BHT II) was observed at all three study sites in association with anoxic and suboxic conditions within the water column. Based on the absence of BHT II from terrigenous and oxic marine environments studied to date, and its strong association with suboxic and anoxic marine pelagic environments, we propose that BHT II is a promising candidate biomarker for water column suboxia and anoxia in the marine geologic record. The molecular fingerprint of BHPs in suspended and sinking particles and core-top sediments indicates that hopanoids produced within the water column are exported to marine sediments and that their biological source is most likely associated with settling particles and not the free-water phase. Based on our observations, BHPs likely represent an important input to the sedimentary hopanoid inventory, particularly in upwelling environments characterized by pelagic oxygen minimum zones (OMZ) and anoxic marine basins. 相似文献
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Heterogeneous coarse grained channels are often characterized by local transitions in bed surface roughness. Distinct spatial zones in terms of grain size have been reported, for example sand ribbons and bedload sheets. The transition from areas of finer to coarser grained surface sediment is often abrupt. However, the effects of these transitions on the shape of the velocity profile and associated shear velocity and roughness length estimates have not been investigated in detail in coarse grained channels. This paper therefore examines the combined effects of a sudden change in surface roughness and of superimposed scales of resistancé on the structure of the turbulent boundary layer. Measurements along roughness transitions from smooth to rough beds were conducted in a flume using artificial roughness features and in a natural gravel bed river. Immediately at the transition from a zone of close packed roughness to a rougher section dominated by obstacles superimposed on the more or less uniform roughness surface, boundary shear stress and roughness length increase considerably. Downstream from this transition, velocity profiles become concave upwards. Downstream and upstream sections show significant differences in terms of near bed velocities (deceleration downstream of the transition), velocity gradient and turbulence intensity of the streamwise velocity component. Comparing the mean velocity profiles corresponding to these two different roughness surfaces gives some indication of the proportion of total shear velocity (or shear stress) associated with the pressure drag produced by large and isolated obstacles. 相似文献
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Birgit Nabbefeld Kliti Grice Roger E. Summons Lindsay E. Hays Changqun Cao 《Applied Geochemistry》2010
In this study the abundances of several polycyclic aromatic hydrocarbons (PAHs Table 1, I–XXI) have been measured throughout three Permian/Triassic (P/Tr) sections from Meishan (South China), Kap Stosch area (East Greenland) and Peace River Basin (Western Canada). Dibenzothiophene (I) and dibenzofuran (II) were found to decrease in abundance just before or shortly after the P/Tr transition in all three sections while perylene (III) was observed to increase in abundance at the onset of the main extinction horizon (bed 25) in Meishan. Perylene has been attributed to a wood degrading fungal source and, therefore, it seems possible these phenomena are related to the demise of land plants. Further, distinct patterns of various combustion-derived PAHs occurring in each section imply that forest fire events occurred within the Late Permian and Early Triassic. In the Meishan section high amounts of combustion-derived PAHs [pyrene (IV), fluoranthene (V), benzo[a]anthracene (VI), benzofluoranthenes (sum, i.e. VII), benzo[a]pyrene (VIII), benzo[e]pyrene (IX) and coronene (X)] occur within bed 25, also containing ash attributed to the fallout from massive volcanic eruptions in Siberia and/or China. 相似文献