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The physico-chemical speciation of organic carbon and selected metals was measured during a coastal bloom in Ekhagen Bay, Baltic Sea, using ultrafiltration.One important objective with the study was to see if any depletion of trace metals could be measured in the directly bioavailable fraction (<1000 Da, the soluble low molecular weight fraction, LMW) during a plankton bloom. Filters with five different cut-offs were used (1 kD (1000 Da), 5 kD, 10 kD, 100 kD and 0.22 μm) in order to delineate the size distribution of colloidal organic carbon (COC) and trace metals.During the bloom in May, LMW Al, Co, Cu, Mn and Ni concentrations decreased although the colloidal and particulate concentrations were relatively high. Data show that desorption of colloidal and particulate bound trace metals to the LMW fraction was slower than the process depleting the LMW fraction.Estimates of the maximum active uptake of Cu, Ni and Mn by the phytoplankton, and the loss of non-bioactive Al from the LMW fraction, indicate that processes other than active uptake by phytoplankton must contribute to the observed depletion of trace metals in the LMW fraction. Hence, in order to estimate the bioavailable pool of trace metals for plankton during bloom conditions, these other processes must be understood and quantified.Transparent Exopolymeric Particles (TEP, reflecting sugar-rich phytoplankton exudates) increased around eight times during the plankton bloom. We hypothesize that the formation of TEP is a process that might be important for the transfer of trace metals from the LMW to the particulate fraction during the phytoplankton bloom, but the significance of TEP for this depletion in Baltic Sea surface water remains to be shown.  相似文献   
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ABSTRACT

This study investigated the impact of pastoral land use and nutrient and fine sediment inputs on Microcoleus autumnalis and filamentous algae-dominated mats, and benthic chlorophyll-a in streams (lower North Island, New Zealand). Surveying and sampling was undertaken monthly at 61 sites spanning a wide gradient in catchment cover and environmental conditions. Two boosted regression tree models were built. The first models included pastoral land cover and five environmental variables as predictors. In the second model pastoral land cover was replaced by nutrient/sediment data. The abundance of the two mat types and chlorophyll-a increased when pastoral land cover was between 20% and 70% (model 1). Replacement of pastoral land cover by nutrient/sediment data (model 2) slightly improved the model fit for all three periphyton variables. Microcoleus autumnalis-dominant mats increased with dissolved inorganic nitrogen concentrations up to ca. 0.6?mg?L?1, and in streams with more frequent flushes. In contrast, filamentous algal-dominated mats increased with turbidity, and in streams with less frequent flushes. Chlorophyll-a generally followed the response of the dominant periphyton type. Increased knowledge on responses of specific periphyton types, rather than total biomass, to environmental variables is essential to guide effective management strategies.  相似文献   
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Summary The crystal structures of 20 natural diopsides have been refined. For some samples, microprobe analyses show a Si deficiency in the tetrahedron with no A1 present; this suggests that some Ti4+ may enter the tetrahedral site. Geometrical variations in these samples with respect to the others are discussed in the light of this Si Ti4+ substitution. The volumes of their M1 sites are larger because of the absence of R3+ cations, the octahedron being very regular; in the same way, the volumes of M2 sites of these samples are greater not because of different site occupancies but because of significant charge modifications around the O3 and O1 oxygens, caused by the tetrahedral site. The low distortion of M1 site and the lengthening of (M2-O1) and M2-O3 bond lengths are a clue to the presence of small amounts of Ti at the tetrahedral site.
Kristallchemische untersuchung natürlicher diopside: Geometrische hinweise für tetraedrische Si-Ti substitution
Zusammenfassung Die Kristallstrukturen von zwanzig natürlichen Diopsiden sind verfeinert worden. In einigen Proben zeigen Mikrosondenanalysen zu geringe Si-Werte im Tetraeder ohne daß A1 anwesend wäre. Dies weist darauf hin, daß Ti4+ Tetraederplätze einnehmen könnte. Geometrische Variationen in diesen Proben werden im Lichte der genannten Substitution diskutiert. Die Volumen von M1-Plätzen sind größer wegen der Abwesenheit von R3+ Kationen, wobei das Oktaeder sehr gleichmäßig ist. Die Volumina von M2-Plätzen sind noch größer nicht wegen verschiedener Besetzungen dieser Plätze sondern wegen signifikanter Ladungsmodifikationen im Bereich von O3 und O1 Sauerstoffen, die durch die tetraedrische Position bewirkt wird. Die geringe Distortion der M1-Plätze und die Verlängerung der (M2-O1) und (M2-O3) Abstände weisen auf die Anwesenheit von geringen Titangehalten auf Tetraederplätzen hin.
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In a companion paper (this volume), the authors propose a methodology for assessing ash fall hazard on a regional scale. In this study, the methodology is applied to the Asia-Pacific region, determining the hazard from 190 volcanoes to over one million square kilometre of urban area. Ash fall hazard is quantified for each square kilometre grid cell of urban area in terms of the annual exceedance probability (AEP), and its inverse, the average recurrence interval (ARI), for ash falls exceeding 1, 10 and 100?mm. A surrogate risk variable, the Population-Weighted Hazard Score: the product of AEP and population density, approximates the relative risk for each grid cell. Within the Asia-Pacific region, urban areas in Indonesia are found to have the highest levels of hazard and risk, while Australia has the lowest. A clear demarcation emerges between the hazard in countries close to and farther from major subduction plate boundaries, with the latter having ARIs at least 2 orders of magnitude longer for the same thickness thresholds. Countries with no volcanoes, such as North Korea and Malaysia, also face ash falls from volcanoes in neighbouring countries. Ash falls exceeding 1?mm are expected to affect more than one million people living in urban areas within the study region; in Indonesia, Japan and the Philippines, this situation could occur with ARIs less than 40?years.  相似文献   
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Although mammography screening programs aim to diagnose breast cancer at an early stage, not all tumours are detected during the regular screening examination. This study examines the influence of various characteristics, including geographical residence, on the survival between screen- and interval-detected breast cancers among participants of a public population-based breast screening program in Queensland, Australia. The investigation was performed using the linked population-based datasets from BreastScreen Queensland and the Queensland Cancer Registry for the period of 1997–2008 for women aged 40–89 years at diagnosis. A Bayesian spatial relative survival modelling approach that accommodates rare outcomes in small geographic regions was adopted, with the use of Markov chain Monte Carlo computation, to evaluate the relative excess risk of breast cancer. In the multivariate Bayesian spatial model, higher relative excess risk of mortality was observed in interval-detected cancer (RER = 1.59, 95 % credible interval = [1.33, 1.89]) compared to screen-detected cancer. Higher cancer survival among the study cohort was also observed among younger women (40–59 years), those of non-Indigenous ethnicity, with localised (stage I) tumour stage as well as those not in the work force. There was no independent association with marital status. Moreover, there was no substantive evidence of either measured geographical or latent random spatial inequalities in survival among screening participants across Queensland, meaning the higher survival for screen-detected breast cancer patients compared to interval-detected women was consistent across the state. These results provide suggestive evidence supporting the effectiveness of the BreastScreen Queensland screening program in reaching socio-economically disadvantaged women as well as those living in rural and remote areas of the state, but also highlights the need for any interval cancer awareness programs to be geographically widespread.  相似文献   
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