The Fe-C system at 5 GPa and implications for Earth’s core     

Nancy L. Chabot  Andrew J. Campbell  David S. Draper  Munir Humayun  Elizabeth Cottrell 《Geochimica et cosmochimica acta》2008,72(16):4146-4158

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.  相似文献   

Stability of waterfront retaining wall subjected to pseudo-static earthquake forces     

Deepankar Choudhury  Syed Mohd. Ahmad 《Ocean Engineering》2007,34(14-15):1947-1954

Waterfront retaining walls supporting dry backfill are subjected to hydrostatic pressure on upstream face and earth pressure on the downstream face. Under seismic conditions, if such a wall retains a submerged backfill, additional hydrodynamic pressures are generated. This paper pertains to a study in which the effect of earthquakes along with the hydrodynamic pressure including inertial forces on such a retaining wall is observed. The hydrodynamic pressure is calculated using Westergaard's approach, while the earth pressure is calculated using Mononobe-Okabe's pseudo-static analysis. It is observed that when the horizontal seismic acceleration coefficient is increased from 0 to 0.2, there is a 57% decrease in the factor of safety of the retaining wall in sliding mode. For investigating the effect of different parameters, a parametric study is also done. It is observed that if φ is increased from 30° to 35°, there is an increase in the factor of safety in the sliding mode by 20.4%. Similar observations were made for other parameters as well. Comparison of results obtained from the present approach with [Ebeling, R.M., Morrison Jr, E.E., 1992. The seismic design of waterfront retaining structures. US Army Technical Report ITL-92-11. Washington DC] reveal that the factor of safety for static condition (k_h=0), calculated by both the approaches, is 1.60 while for an earthquake with k_h=0.2, they differ by 22.5% due to the consideration of wall inertia in the present study.  相似文献   

Platinum group element geochemistry of komatiites from the Alexo and Pyke Hill areas, Ontario, Canada     

Igor S. Puchtel  Munir Humayun  Rebecca A. Sproule 《Geochimica et cosmochimica acta》2004,68(6):1361-1383

Thirty-three whole-rock drill core samples and thirteen olivine, chromite, and sulfide separates from three differentiated komatiite lava flows at Alexo and Pyke Hill, Canada, were analyzed for PGEs using the Carius tube digestion ID-ICP-MS technique. The emplaced lavas are Al-undepleted komatiites with ∼27% MgO derived by ∼50% partial melting of LILE-depleted Archean mantle. Major and minor element variations during and after emplacement were controlled by 30 to 50% fractionation of olivine Fo_93-94. The emplaced lavas are characterized by (Pd/Ir)_N = 4.0 to 4.6, (Os/Ir)_N = 1.07, and Os abundances of ∼2.3 ppb. Variations in PGE abundances within individual flows indicate that Os and Ir were compatible (bulk D_Os,Ir = 2.4-7.1) and that Pt and Pd were incompatible (bulk D_Pt,Pd < 0.2) during lava differentiation, whereas bulk D_Ru was close to unity. Analyses of cumulus olivine separates indicate that PGEs were incompatible in olivine (D_PGEs^Ol-Liq = 0.04-0.7). The bulk fractionation trends cannot be accounted for by fractionation of olivine alone, and require an unidentified Os-Ir-rich phase. The composition of the mantle source (Os = 3.9 ppb, Ir = 3.6 ppb, Ru = 5.4 ppb, Pt and Pd = 5.7 ppb) was constrained empirically for Ru, Pt, and Pd; the Os/Ir ratio was taken to be identical to that in the emplaced melt, and the Ru/Ir ratio was taken to be chondritic, so that the absolute IPGE abundances of the source were determined by Ru. This is the first estimate of the PGE composition of a mantle source derived from analyses of erupted lavas. The suprachondritic Pd/Ir and Os/Ir of the inferred Abitibi komatiite mantle source are similar to those in off-craton spinel lherzolites, orogenic massif lherzolites, and enstatite chondrites, and are considered to be an intrinsic mantle feature. Bulk partition coefficients for use in komatiite melting models derived from the source and emplaced melt compositions are: D_Os,Ir = 2.3, D_Ru = 1.0, D_Pt,Pd = 0.07. Ruthenium abundances are good indicators of absolute IPGE abundances in the mantle sources of komatiite melts with 26 to 29% MgO, as Ru fractionates very little during both high degrees of partial melting and lava differentiation.  相似文献   

Highly siderophile element geochemistry of Os-enriched 2.8 Ga Kostomuksha komatiites, Baltic Shield     

Igor S. Puchtel  Munir Humayun 《Geochimica et cosmochimica acta》2005,69(6):1607-1618

New analyses of highly siderophile elements (HSE; Re, Os, Ir, Ru, Pt, and Pd) obtained by Carius tube digestion isotope dilution inductively coupled plasma mass-spectrometry (ID-ICPMS) technique are reported for ¹⁸⁷Os-enriched 2.8 Ga komatiites from the Kostomuksha greenstone belt. As a result of a significant improvement in the yield over our previous digestions by the NiS fire-assay technique, these komatiites have now been shown to contain 22 to 25% more Os, Ir, and Pt and 34% more Ru. The emplaced komatiite lavas at Kostomuksha thus had siderophile element abundances comparable to those of the Abitibi belt. The discrepancies observed between the two techniques are interpreted to be the result of incomplete digestion of HSE carriers (particularly chromite) during the NiS fire-assay procedure. Our results for UB-N peridotite reference material agree well with those obtained by the high-pressure ashing digestion ID-ICPMS technique reported in the literature. Two types of komatiite lavas have been distinguished in this study based on the IPGE (Os, Ir, and Ru) behavior during lava differentiation. The Kostomuksha type is unique and is characterized by an incompatible behavior of IPGEs, with bulk solid-liquid partition coefficients for IPGEs being close to those for olivine. Cumulate zones in this type of komatiite lava occupy <20% of the total thickness of the flows. The Munro type exhibits a compatible behavior of IPGEs during lava differentiation. The cumulate zone in this type of komatiite occupies >20% of the total thickness of the flows. The calculated bulk partition coefficients indicate that, as with the other Munro-type komatiite lavas, the bulk cumulate contained an IPGE-rich minor phase(s) in addition to olivine. The non-CI chondritic HSE pattern for the source of the Kostomuksha komatiites calculated here is similar to that of Abitibi komatiites and to average depleted spinel lherzolite (ADSL) and supports the hypothesis of a non-CI chondritic HSE composition of the Earth’s mantle. The absolute HSE abundances in the source of the Kostomuksha komatiite have been demonstrated to be comparable to those of the source of Abitibi komatiites, even though the two komatiites contrast in their Os isotopic compositions. This supports the earlier hypothesis that if core-mantle interaction produced the ¹⁸⁷Os/¹⁸⁸Os radiogenic signature in the Kostomuksha source, it must have occurred in the form of isotope exchange at the core-mantle boundary. Other explanations of the radiogenic Os signature are similarly constrained to conserve the elemental abundance pattern in the mantle source of Kostomuksha komatiites.  相似文献   

Compositions of group IVB iron meteorites and their parent melt     

Andrew J. Campbell  Munir Humayun 《Geochimica et cosmochimica acta》2005,69(19):4733-4744

The concentrations of P, V, Cr, Fe, Co, Ni, Cu, Ga, Ge, As, Mo, Ru, Rh, Pd, W, Re, Os, Ir, Pt, and Au in the group IVB iron meteorites Cape of Good Hope, Hoba, Skookum, Santa Clara, Tawallah Valley, Tlacotepec, and Warburton Range have been measured by laser ablation inductively coupled plasma mass spectrometry. The data were fitted to a model of fractional crystallization of the IVB parent body core, from which the composition of the parent melt and metal/melt distribution coefficients for each element in the system were determined, for a chosen value of D(Ni). Relative to Ni and chondritic abundances, the parent melt was enriched in refractory siderophiles, with greatest enrichment of 5× chondritic in the most refractory elements, and was strongly volatile-depleted, down to 0.00014× chondritic in Ge. Comparison to an equilibrium condensation sequence from a gas of solar composition indicates that no single temperature satisfactorily explains the volatility trend in the IVB parent melt; a small (<1%) complement of ultrarefractory components added to metal that is volatile-depleted but otherwise has nearly chondritic abundances (for Fe, Co and Ni) best explains the volatility trend. In addition to this volatility processing, which probably occurred in a nebular setting, there was substantial oxidation of the metal in the IVB parent body, leading to loss of Fe and other moderately siderophile elements such as Cr, Ga, and W, and producing the high Ni contents that are observed in the IVB irons. By assuming that the entire IVB parent body underwent a similar chemical history as its core, the composition of the silicate that is complementary to the IVB parent melt was also estimated, and appears to be similar to that of the angrite parent.  相似文献   

Unique achondrite Northwest Africa 11042: Exploring the melting and breakup of the L chondrite parent body     

Zoltn Vci  Carl B. Agee  Munir Humayun  Karen Ziegler  Yemane Asmerom  Victor Polyak  Henner Busemann  Daniela Krietsch  Matthew Heizler  Matthew E. Sanborn  Qing‐Zhu Yin 《Meteoritics & planetary science》2020,55(3):622-648

Northwest Africa (NWA) 11042 is a heavily shocked achondrite with medium‐grained cumulate textures. Its olivine and pyroxene compositions, oxygen isotopic composition, and chromium isotopic composition are consistent with L chondrites. Sm‐Nd dating of its primary phases shows a crystallization age of 4100 ± 160 Ma. Ar‐Ar dating of its shocked mineral maskelynite reveals an age of 484.0 ± 1.5 Ma. This age coincides roughly with the breakup event of the L chondrite parent body evident in the shock ages of many L chondrites and the terrestrial record of fossil L chondritic chromite. NWA 11042 shows large depletions in siderophile elements (<0.01×CI) suggestive of a complex igneous history involving extraction of a Fe‐Ni‐S liquid on the L chondrite parent body. Due to its relatively young crystallization age, the heat source for such an igneous process is most likely impact. Because its mineralogy, petrology, and O isotopes are similar to the ungrouped achondrite NWA 4284 (this work), the two meteorites are likely paired and derived from the same parent body.  相似文献   

Optimal site selection for an optical-astronomical observatory in Pakistan using Multicriteria Decision Analysis     

Daniyal  Syed Jamil Hassan Kazmi 《天文和天体物理学研究(英文版)》2019,(9)

An astronomical observatory is the core component of any astronomical research facility that connects astronomers with their lab: the Cosmos. The research quality of an astronomical facility is rooted in the precision of data, collected by its observatory. For optimal performance, an observatory is sited while considering certain astronomical, environmental, geological and social parameters. This study aims to identify the potential sites in Pakistan for locating an optical-astronomical observatory using the Multicriteria Decision Analysis(MCDA) technique. The study uses the Analytic Hierarchy Process(AHP) for deriving the influence weights of nine evaluation criteria: Photometric Night Fraction; Night-time Sky Brightness;Sky Transparency; Aerosol Concentration; Altitude; Terrain Slope; Accessibility; Seismic Vulnerability;and Landuse/Land Cover. On the basis of experts' opinions and previous studies, the evaluation criteria have been ordered in two possible preference sequences for identifying their influence weights with respect to each other for taking part in MCDA. Consequently, the process of MCDA identified certain areas with respect to each preference sequence, whereas some areas were found to be suitable according to both preference sequences. The study synchronizes the required eclectic data into an evaluation matrix that augments the process of astronomical site selection. In the future, this study will be useful for astronomical societies and for furthering astronomical research in the country.  相似文献   

A Major Geoeffective CME from NOAA 12371: Initiation,CME–CME Interactions,and Interplanetary Consequences     

Bhuwan Joshi  M. Syed Ibrahim  A. Shanmugaraju  D. Chakrabarty 《Solar physics》2018,293(7):107

In this article, we present a multi-wavelength and multi-instrument investigation of a halo coronal mass ejection (CME) from active region NOAA 12371 on 21 June 2015 that led to a major geomagnetic storm of minimum \(\mathrm{Dst} = -204\) nT. The observations from the Atmospheric Imaging Assembly onboard the Solar Dynamics Observatory in the hot EUV channel of 94 Å confirm the CME to be associated with a coronal sigmoid that displayed an intense emission (\(T \sim6\) MK) from its core before the onset of the eruption. Multi-wavelength observations of the source active region suggest tether-cutting reconnection to be the primary triggering mechanism of the flux rope eruption. Interestingly, the flux rope eruption exhibited a two-phase evolution during which the “standard” large-scale flare reconnection process originated two composite M-class flares. The eruption of the flux rope is followed by the coronagraphic observation of a fast, halo CME with linear projected speed of 1366 km?s^?1. The dynamic radio spectrum in the decameter-hectometer frequency range reveals multiple continuum-like enhancements in type II radio emission which imply the interaction of the CME with other preceding slow speed CMEs in the corona within \(\approx10\)?–?\(90~\mbox{R} _{\odot}\). The scenario of CME–CME interaction in the corona and interplanetary medium is further confirmed by the height–time plots of the CMEs occurring during 19?–?21 June. In situ measurements of solar wind magnetic field and plasma parameters at 1 AU exhibit two distinct magnetic clouds, separated by a magnetic hole. Synthesis of near-Sun observations, interplanetary radio emissions, and in situ measurements at 1 AU reveal complex processes of CME–CME interactions right from the source active region to the corona and interplanetary medium that have played a crucial role towards the large enhancement of the geoeffectiveness of the halo CME on 21 June 2015.  相似文献   

An analytical solution for deforming twin‐parallel tunnels in an elastic half plane          下载免费PDF全文

Jinyang Fu  Junsheng Yang  Li Yan  Syed Muntazir Abbas 《国际地质力学数值与分析法杂志》2015,39(5):524-538

The interaction between twin‐parallel tunnels affects the tunnelling‐induced ground deformation, which may endanger the nearby structures. In this paper, an analytical solution is presented for problems in determining displacements and stresses around deforming twin‐parallel tunnels in an elastic half plane, on the basis of complex variable theory. As an example, a uniform radial displacement was assumed as the boundary condition for each of the two tunnels. Special attention was paid to the effects of tunnel depth and spacing between the two tunnels on the surface movement to gain deep insight into the effect of the interaction between twin‐parallel tunnels using the proposed analytical approach. It is revealed that the influence of twin tunnel interaction on surface movements diminishes with both the increase of the tunnel depth and the spacing between the two tunnels. The presented analytical solution manifests that, similar to most of the existing numerical results, the principle of superposition can be applied to determine ground deformation of twin‐parallel tunnels with a certain large depth and spacing; otherwise, the interaction effect between the two tunnels should be taken into account for predicting reliable ground movement. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Diversity patterns of free‐living marine nematodes in the southwest continental shelf off Bay of Bengal and their link to abiotic variables          下载免费PDF全文

Kapuli Gani Mohamed Thameemul Ansari  Somasundharanair Lyla  Syed Ajmal Khan  Punyasloke Bhadury 《Marine Ecology》2016,37(3):631-644

Marine sediments in continental shelf ecosystems harbor a rich biodiversity of benthic communities. In this study, the spatial and temporal diversity and community assemblages of free‐living marine nematodes were studied by sampling at six depths and over 3 years from the southwest continental shelf off Bay of Bengal, one of the least explored tropical shelf ecosystems. The dominant marine nematode species were related with abiotic variables as part of this study. The effects of sediment granulometry generally decreased with increasing depth and the highest nematode density and species diversity were recorded on coarse sand (shallower depths). Multivariate analysis of the nematode community data showed that community structure differed significantly among depths as well as among years. Statistical analyses showed significant correlations between the nematode community and abiotic variables. Sediment texture, organic matter, water pressure and depth profile were crucial factors for determining diversity, vertical profile and feeding types of the nematode community. Other environmental factors, including anthropogenic pressure, did not have an effect on nematode diversity except for the presence of some tolerant species (Metachromadora spp., Sabatieria spp. and Siplophorella sp.). This study represents a baseline of knowledge of free‐living marine nematode communities that can be used in the future to compare nematode assemblages from temperate shelf ecosystems.  相似文献