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The British Tertiary Volcanic Province (BTVP) comprises within-platecentral igneous complexes associated with plateau lavas andregional dyke swarms. Lundy is the southernmost complex of theBTVP and comprises granite ({small tilde}90%) emplaced intodeformed Devonian sedimentary rocks within the Hercynian Cornubiangranite province of southwest England. The complex is intrudedby a northwest-southeast trending dyke swarm. In common withother BTVP igneous complexes, Lundy is associated with positivegravity and magnetic anomalies which are interpreted in termsof the presena of an underlying basic intrusion at shallow depth,with a volume exceeding that of the overlying granite. The Lundy intrusion is a coarse-grained megacrystic granitecontaining up to 20% alkali feldspar megacrysts in a coarse-grainedgroundmass composed of alkali feldspar, quartz, lithium-bearingmuscovite, and ‘biotite’ (lithian siderophyllite),with a range of aaxssory minerals. The main granite has a coarse-grained(locally miarolitic) pegmatitic facies and is intruded by thinsheets and veins of fine-grained aplite and microgranite. Themineralogy indicates crystallization of the Lundy granite froma highly fractionated H2O- and halogen-rich magma at a relativelyshallow crustal level. The main Lundy granite is a peraluminous leucogranite with Na2O=3–4%,K2O{small tilde}5%, low TiO2, MeO, CaO, Zr, and Sr, and highRb and Rb/Sr in comparison with many other peralurninous granites,including those from the Cornubian batholith and the BTVP. Anew Rb-Sr whole-rock isochron for the granite yields an ageof 58?7?1?6 Ma with an initial 87Sr/86Sr of 0?715?0?006. Ndvalues for the granite (–0?9 to –1?9) plot betweencontemporaneous mantle (positive Nd and Cornubian granites (Nd=ca.–11). The trace element data (Rb, Y, Nb) show affinities with syn-collisionand within-plate granites. As the Sr isotope data indicate amajor crustal component, and the Nd isotope data suggest bothmantle and crustal components, we propose that the Lundy graniteis derived from a parental magma comprising crustal components(derived from a similar source to that of the Cornubian granitebatholith) and a mantle-derived component (derived from a differentiateof contemporaneous basaltic magma This magma experienced fractionalcrystallization of plagioclase, alkai feldspar, Fe-Mg minerals,and REE-bearing accessory minerals before emplacement, and theLundy granite experienced further in situ fractional crystallization,associateded with crustal contamination by the Devonian shaleafter emplacement.  相似文献   
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The Ordovician Snowdon Volcanic Centre (SVC) of North Walescomprises a bimodal basalt–subalkaline/peralkaline associationemplaced around a caldera within a shallow marine environment.The tectonic setting was associated with closure of the LowerPalaeozoic Iapetus Ocean and cessation of ocean plate subduction.The SVC volcanic products include basaltic lavas and pyroclasticrocks, rhyolitic pyroclastic flow deposits, high-level intrusions,domes, and flows, together with reworked equivalents. A programmeof detailed field mapping, sampling, and chemical analysis hasbeen used to evaluate the structure and magmatic evolution ofthe SVC volcanic system. SVC basalts show a range in chemicalcharacteristics between volcanic arc type and within-plate,ocean island basalt (OIB) type. Subalkaline, silica-oversaturatedintermediate intrusions (icelandites) and five chemically distinctgroups of extrusive and intrusive subalkaline/peralkaline rhyolites(termed A1, A2, B1, B2, and B3) were emplaced during the evolutionof the SVC. This evolution was driven by material and thermalinput from basaltic magma. The SVC basaltic lavas were derivedas partial melts from a heterogeneous volcanic arc to OIB-typespinel lherzolite mantle and experienced up to 60% olivine gabbrofractionation during storage in sill networks in the sub-crustor lower crust. Some magma batches experienced further fractionalcrystallization ({small tilde}70%) and minor crustal contamination({small tilde}10%) to yield the icelandites. Trace element andNd isotope data do not favour an origin for the rhyolites bypartial or total fusion of likely crustal material, and thefive rhyolite groups are regarded as distinct homogeneous batchesof magma derived from varied basaltic magmas. The icelanditesand peralkaline rhyolites (group B3) result, respectively, from{small tilde}50% and {small tilde}80–90% zircon-free fractionalcrystallization of SVC basalts. The subalkaline rhyolites (groupsA1 and B1) result from {small tilde}80–90% fractionalcrystallization of subduction-related basalts similar to thoseof Ordovician basalts which pre-date the Lower Rhyolitic TuffFormation, and groups A2 and B2 were formed by mixing and homogenizationof A1, B1, and B3 magma batches. These data and interpretationsprovide the basis of a model for the complex evolution of asilicic magma system below the SVC caldera around the time ofcessation of Caledonian subduction in North Wales. Rhyolitemagma chambers were short lived and discontinuous; the largestwas probably disc shaped and was almost entirely evacuated duringa >60-km3 ash-flow eruption.  相似文献   
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The igneous rocks of the British Tertiary Volcanic Province(BTVP) comprise intrusive central complexes and associated lavafields in northwest Scotland and northern Ireland. These centresare associated with linear dyke swarms which are radial aroundthe major central complexes. The most extensive dyke swarm isrelated to the Mull intrusive complex and includes the Clevelanddyke, which appears to extend some 430 km from Mull throughthe Scottish Midland Valley (SMV) to the coast of northeastEngland. The dyke may have been emplaced by lateral magma migrationfrom Mull, by vertical magma migration, or by a combinationof these processes associated with the emplacement of the Mullcentre and the presence of a regional stress field in northernBritain. Petrographic, mineralogical, and geochemical data for samplescollected across and along the Cleveland dyke have been usedto evaluate its petrogenesis and emplacement mechanism. Thesegment of the dyke north of, and along, the Southern UplandsFault, the southern boundary of the SMV, is not comagmatic withthat to the south, which is now defined as the Cleveland dykesensu stricto. The Cleveland dyke is an olivine-free, plagioclase-and pyroxene-phyric basaltic andesite. Plagioclase mineralogyand bulk composition indicate that it experienced a complexmagmatic history involving polybaric fractional crystallizationand minor crustal contamination. Despite this complex evolution,the dyke magma is relatively homogeneous and shows chemicalcharacteristics closely similar to tholeiitic rocks from Mull.The data substantiate lateral emplacement from this BVTP centre,rather than by vertical emplacement through heterogeneous lithosphere. Numerical modelling of dyke dynamics is consistent with emplacementof the Cleveland dyke as a single pulse of magma from the Mullcentre, flowing in a manner transitional between laminar andturbulent conditions. According to this model, the dyke (volumec. 85 km3 was initiated in a large magma chamber below Mullsubject to a small excess magmatic pressure. Lateral migrationat relatively high velocity (1–5 ms–1) caused emplacementof the dyke in 1–5 days. Following emplacement, minorvertical ascent of magma may have contributed to the local enechelon distribution of dyke segments.  相似文献   
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New data are presented for the analysis of the elements: REE, Na20, Fe2O3, Cr, Co, Rb, Cs, Ba, Hf, Ta, Th and Il in twenty-five less well known carbonate and industrial geological reference materials by instrumental neutron activation analysis. The materials include NBS 1c, 15e, 88a and 120b from the National Bureau of Standards, Washington DC; GFS 400-403, 405, 407, 411, 412, 415 and 417 carbonate materials from George Fredrick Smith, Columbus, Ohio and BCS 267, 269, 309, 315, 319, 367, 368, 375, 376, 381 and 382/1 from the Bureau of Analysed Samples, Middles-borough, Cleveland, UK. Particular attention has been given to the correction of interferences due to the fission of uranium in the determination of the elements La, Ce, Nd and Zr.  相似文献   
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