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Tetsu Nakamura Masayuki Hara Miki Oshika Yoshihiro Tachibana 《Climate Dynamics》2015,45(11-12):3547-3562
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Sanae Koizumi Takehiko Hiraga Chihiro Tachibana Miki Tasaka Tomonori Miyazaki Tamio Kobayashi Asako Takamasa Naoki Ohashi Satoru Sano 《Physics and Chemistry of Minerals》2010,37(8):505-518
Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline
mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase
composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside.
Nano-sized powders of colloidal SiO2 and highly dispersed Mg(OH)2 with particle size of ≤50 nm are used as chemical sources for MgO and SiO2, which are common components for all of the aggregates. These powders are mixed with powders of CaCO3, MgAl2O4, and Fe(CO2CH3)2 to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense
composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully
or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders
are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to
achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral
composites with grain size of 0.3–1.1 μm are successfully synthesized with this method. 相似文献
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Shogo Tachibana Shinnosuke Tamada Haruka Kawasaki Kazuhito Ozawa Hiroko Nagahara 《Physics and Chemistry of Minerals》2013,40(6):511-519
The interdiffusion coefficient of Mg–Fe in olivine (D Mg–Fe) was obtained at 1,400–1,600 °C at the atmospheric pressure with the oxygen fugacity of 10?3.5–10?2 Pa using a diffusion couple technique. The D Mg–Fe shows the anisotropy (largest along the [001] direction and smallest along the [100] direction), and its activation energy (280–320 kJ/mol) is ~80–120 kJ/mol higher than that estimated at lower temperatures. The D Mg–Fe at temperatures of >1,400 °C can be explained by the cation-vacancy chemistry determined both by the Fe3+/Fe2+ equilibrium and by the intrinsic point defect formation with the formation enthalpy of 220–270 kJ/mol depending on the thermodynamical model for the Fe3+/Fe2+ equilibrium in olivine. The formation enthalpy of 220–270 kJ/mol for the point defect (cation vacancy) in olivine is consistent with that estimated from the Mg self-diffusion in Fe-free forsterite. The increase in the activation energy of D Mg–Fe at >1,400 °C is thus interpreted as the result of the transition of diffusion mechanism from the transition metal extrinsic domain to the intrinsic domain at the atmospheric pressure. 相似文献
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The sulfur isotopic compositions of putative primary troilite grains within 15 ferromagnesian chondrules (10 FeO-poor and 5 FeO-rich chondrules) in the least metamorphosed ordinary chondrites, Bishunpur and Semarkona, have been measured by ion microprobe. Some troilite grains are located inside metal spherules within chondrules. Since such an occurrence is unlikely to be formed by secondary sulfidization processes in the solar nebula or on parent bodies, those troilites are most likely primary, having survived chondrule-forming high-temperature events. If they are primary, they may be the residues of evaporation at high temperatures during chondrule formation and may have recorded mass-dependent isotopic fractionations. However, the supposed primary troilites measured in this study do not show any significant sulfur isotopic fractionations (<1 ‰/amu) relative to large troilite grains in matrix. Among other chondrule troilites that we measured, only one (BI-CH22) apparently has a small excess of heavy isotopes (2.7 ± 1.4 ‰/amu) consistent with isotopic fractionation during evaporation. All other grains have isotopic fractionations of <1 ‰/amu. Because sulfur is so volatile that evaporation during chondrule formation is probably inevitable, non-Rayleigh evaporation most likely explains the lack of isotopic fractionation in putative primary troilite inside chondrules. Evaporation through the surrounding silicate melt would have suppressed the isotopic fractionation after silicate dust grains melted. At lower temperatures below extensive melting of silicates, a heating rate of >104-106 K/h would be required to avoid a large degree of sulfur isotopic fractionation in the chondrule precursors. This heating rate may provide a new constraint on the chondrule formation processes. 相似文献
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An algorithm to calculate direct velocity feedback gain with limited number of sensors is developed in a simple way such that a certain performance index is minimized according to QN control method. If a limited number of velocity outputs can be measured, full velocity responses of the whole structure can be interpolated based on the mode shapes. By defining the performance index function as a combination of the structure's velocity responses and control forces only, feedback gain can be determined according to QN control method with the external excitation being taken into account throughout the entire algorithm. Control forces are then regulated by the time‐invariant feedback gain matrix. The effective location of the active control devices for a building structure subjected to intermediate‐storey excitation has been determined to be in the three floors adjacent to the vibration source. Hence for the purpose of this paper, only the optimal placement of sensors is verified. It is shown in this paper that if the dynamic behaviour of the structure is well described by a mathematical model, sufficient response reduction effect can be achieved according to the new DVFC algorithm, and the degradation of control performance due to time delay can also be verified. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
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A conglomerate appears on a rocky coast called ??Tsubutega-ura Coast??, located on the southwestern coast near the southern tip of the Chita Peninsula, Aichi Prefecture, central Japan. The conglomerate belongs to Miocene sedimentary rocks termed the Morozaki Group. The conglomerate includes meter-scale boulders, indicating that it was formed by an extraordinary event. In the geological investigation, we observed that the conglomerate shows alternate changes of paleocurrent directions between seaward and landward. This feature is supposed to be formed by tsunami currents. In the hydrodynamical investigation, we obtained following results: (1) the lowest limit of a current velocity to move a boulder of about 3?m in diameter would be about 2?C3?m/s, (2) the speed of tsunami currents reproduced by tsunami simulation exceeds 3?m/s at 300?m in depth when the tsunami is generated by a gigantic earthquake with magnitude 9.0 or more, (3) the transport distance of the boulder would be several hundred?meters to several kilometers by one tsunami event caused by a gigantic earthquake. We conclude that tsunamis best explain the formation of the conglomerate deposited in upper bathyal environments about 200?C400?m depth, both from geological and hydrodynamical viewpoints. 相似文献
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In 2010, the Northern Hemisphere, in particular Russia and Japan, experienced an abnormally hot summer characterized by record-breaking warm temperatures and associated with a strongly positive Arctic Oscillation (AO), that is, low pressure in the Arctic and high pressure in the midlatitudes. In contrast, the AO index the previous winter and spring (2009/2010) was record-breaking negative. The AO polarity reversal that began in summer 2010 can explain the abnormally hot summer. The winter sea surface temperatures (SST) in the North Atlantic Ocean showed a tripolar anomaly pattern—warm SST anomalies over the tropics and high latitudes and cold SST anomalies over the midlatitudes—under the influence of the negative AO. The warm SST anomalies continued into summer 2010 because of the large oceanic heat capacity. A model simulation strongly suggested that the AO-related summertime North Atlantic oceanic warm temperature anomalies remotely caused blocking highs to form over Europe, which amplified the positive summertime AO. Thus, a possible cause of the AO polarity reversal might be the “memory” of the negative winter AO in the North Atlantic Ocean, suggesting an interseasonal linkage of the AO in which the oceanic memory of a wintertime negative AO induces a positive AO in the following summer. Understanding of this interseasonal linkage may aid in the long-term prediction of such abnormal summer events. 相似文献
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Maho Yamada Shogo Tachibana Hiroko Nagahara Kazuhito Ozawa 《Planetary and Space Science》2006,54(11):1096-1106
Evaporation of solid materials under low-pressure conditions could play important roles in chemical and isotopic fractionations in the early solar system. We have studied anisotropy of isotopic fractionation of 26Mg and 25Mg during kinetic evaporation of forsterite (Mg2SiO4), which is potentially a powerful tool to understand thermal histories of crystals in the early solar system. Ion-microprobe depth profiling revealed that the Mg isotopic zoning profiles of forsterite evaporated at 1500-1700 °C are notably differing along the a-, b-, and c-axes, which can be attributed to anisotropy in self-diffusion coefficient of Mg (D) and an isotopic fractionation factor for evaporation of Mg (α). The D and α were obtained from zoning profiles by applying the diffusion-controlled isotopic fractionation model of Wang et al. [1999. Evaporation of single crystal forsterite: Evaporation kinetics, magnesium isotope fractionation, and implications of mass-dependent isotopic fractionation of a diffusion-controlled reservoir. Geochim. Cosmochim. Acta 63(6), 953-966.].The D is largest and smallest along the a- and c-axes, respectively. The activation energy of 560-670 kJ/mol indicates that Mg diffusion at 1500-1700 °C occurred in the intrinsic diffusion regime.The α seems to be larger along the a- or c-axes than along the b-axis. The α along the a- or c-axes show weak temperature dependence. The α along all the crystallographic orientations is closer to unity than that expected from the kinetic theory of gases. These lines of evidence suggest that surface processes such as breaking of bonds and surface diffusion are responsible for the isotopic fractionation. 相似文献