The dissociation constants of carbonic acid in seawater at salinities 5 to 45 and temperatures 0 to 45°C     

Rabindra N Roy  Lakshimi N Roy  Kathleen M Vogel  C Porter-Moore  Tara Pearson  Catherine E Good  Frank J Millero  Douglas M Campbell 《Marine Chemistry》1993,44(2-4)

The pK₁^* and pK₂^* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK₁^* have been determined from emf measurements for the cell: where X is the mole fraction of CO₂ in the gas. The values of pK₂^* have been determined from emf measurements on the cell: The results have been fitted to the equations: where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK₁^* and σ = 0.0070 in lnK₂^*.Our new results are in good agreement at S = 35 (±0.002 in pK₁^*and ±0.005 in pK₂^*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H₂|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater.  相似文献   

Water resources sustainability in a globalizing world: who uses the water?          下载免费PDF全文

Megan Konar  Tom P. Evans  Morgan Levy  Christopher A. Scott  Tara J. Troy  Charles J. Vörösmarty  Murugesu Sivapalan 《水文研究》2016,30(18):3330-3336

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Characteristics of surface ozone in Agra,a sub-urban site in Indo-Gangetic Plain     

Nidhi Verma  Aparna Satsangi  Anita Lakhani  K Maharaj Kumari 《Journal of Earth System Science》2018,127(3):42

In the present study, measurements of surface ozone (\(\hbox {O}_{3}\)) and its precursors (NO and \(\hbox {NO}_{2}\)) were carried out at a sub-urban site of Agra (\(27{^{\circ }}10'\hbox {N}\), \(78{^{\circ }}05'\hbox {E}\)), India during May 2012–May 2013. During the study period, average concentrations of \(\hbox {O}_{3}\), NO, and \(\hbox {NO}_{2}\) were \(39.6 \pm 25.3\), \(0.8 \pm 0.8\) and \(9.1 \pm 6.6 \, \hbox {ppb}\), respectively. \(\hbox {O}_{3}\) showed distinct seasonal variation in peak value of diurnal variation: summer \({>}\) post-monsoon \({>}\) winter \({>}\) monsoon. However, \(\hbox {NO}_{2}\) showed highest levels in winter and lowest in monsoon. The average positive rate of change of \(\hbox {O}_{3}\) (08:00–11:00 hr) was highest in April (16.3 ppb/hr) and lowest in August (1.1 ppb/hr), while average negative rate of change of \(\hbox {O}_{3}\) (17:00–19:00 hr) was highest in December (–13.2 ppb/hr) and lowest in July (–1.1 ppb/hr). An attempt was made to identify the \(\hbox {VOC--NO}_{\mathrm{x}}\) sensitivity of the site using \(\hbox {O}_{3}/\hbox {HNO}_{3}\) ratio as photochemical indicator. Most of the days this ratio was above the threshold value (12–16), which suggests \(\hbox {NO}_{\mathrm{x}}\) sensitivity of the site. The episodic event of ozone was characterized through meteorological parameters and precursors concentration. Fine particles (\(\hbox {PM}_{2.5}\)) cause loss of ozone through heterogeneous reactions on their surface and reduction in solar radiation. In the study, statistical analyses were used to estimate the amount of ozone loss.  相似文献   

Johann Georg Goldammer, Valentin V. Furyaev (eds.): Fire in Ecosystems of Boreal Eurasia     

Tara Tchir  Edward A. Johnson 《Climatic change》1998,39(4):731-736

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Performance of seismically loaded shearwalls on nonlinear shallow foundations     

Prishati Raychowdhury  Tara C. Hutchinson 《国际地质力学数值与分析法杂志》2011,35(7):846-858

If utilized, the energy dissipative capability of seismically loaded shallow foundations due to inelastic behavior can result in more economic design, provided the consequences, such as excessive deformations are accounted for. In this article, a Beam‐on‐Nonlinear‐Winkler‐Foundation (BNWF) model is used to assess the performance of shearwall‐foundation systems with different attributes, when subjected to ground motions of varied hazard levels. The numerical study indicates that the force and drift demands to the shearwall reduce significantly, when nonlinear foundation behavior is realized, while permanent settlement is well below the permissible limit. These results support the concept of shallow foundation capacity mobilization in future design. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Impacts of salinity parameterizations on temperature simulation over and in a hypersaline lake     

WEN Lijuan  NAGABHATLA Nidhi  ZHAO Lin  LI Zhaoguo  CHEN Shiqiang 《中国海洋湖沼学报》2015,33(3)

In this paper,we introduced parameterizations of the salinity effects(on heat capacity,thermal conductivity,freezing point and saturated vapor pressure) in a lake scheme integrated in the Weather Research and Forecasting model coupled with the Community Land Model(WRF-CLM). This was done to improve temperature simulation over and in a saline lake and to test the contributions of salinity effects on various water properties via sensitivity experiments. The modified lake scheme consists of the lake module in the CLM model,which is the land component of the WRF-CLM model. The Great Salt Lake(GSL) in the USA was selected as the study area. The simulation was performed from September 3,2001 to September 30,2002. Our results show that the modif ied WRF-CLM model that includes the lake scheme considering salinity effects can reasonably simulate temperature over and in the GSL. This model had much greater accuracy than neglecting salinity effects,particularly in a very cold event when that effect alters the freezing point. The salinity effect on saturated vapor pressure can reduce latent heat flux over the lake and make it slightly warmer. The salinity effect on heat capacity can also make lake temperature prone to changes. However,the salinity effect on thermal conductivity was found insignificant in our simulations.  相似文献   

Trapping and amplification of quasi-longitudinal whistler wave in kinetic Alfvén wave localized structures     

Rajesh Kumar Rai  Swati Sharma  Nidhi Gaur  R. P. Sharma 《Astrophysics and Space Science》2016,361(3):110

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Analytical and numerical investigation of multicomponent multiphase WAG displacements     

Tara LaForce  Kristian Jessen 《Computational Geosciences》2010,14(4):745-754

In this paper the ability of analytical solutions for four-component three-phase flow to predict displacement efficiency in water alternating gas (WAG) injection processes is studied. First analytical solutions for Riemann problems with injection compositions that are the average water and gas mixture for various WAG injection schemes are presented. These solutions are compared to numerical calculations with variable slug sizes and used to explore the effect of slug size, injecting water vs gas first, and the average injection composition on displacement efficiency in compositional WAG schemes. The example model is partially miscible WAG injection of water and CO₂ into an oil reservoir containing C₁₀ and CH₄ with and without a mobile aqueous phase present initially. The trailing end of the water and gas profiles are sensitive to whether water or gas is injected first, but the magnitude of the oil bank and the breakthrough time of the injected fluids are accurately predicted by the analytical solutions, even for displacements where large water and gas slugs are injected. Fluctuations in the saturation and composition profiles resulting from the alternating injection sequence in the WAG simulations appear as super-imposed on top of the sequence of rarefaction and shock waves predicted by analytical solutions. As the number of slugs increases, the effect of alternating boundary conditions diminishes and the displacements predicted by numerical calculations converge to the analytical solutions.  相似文献   

Coherence of river and ocean conditions along the US West Coast during storms     

Tara A. Kniskern  Jonathan A. Warrick  Katherine L. Farnsworth  Robert A. Wheatcroft  Miguel A. Goñi 《Continental Shelf Research》2011,31(7-8):789-805

The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast.  相似文献   

Key natural analogue input required to build a safety case for direct disposal of spent nuclear fuel in Japan     

Ian G. McKinley  Hideki Kawamura  Susie M. L. Hardie  Elizaveta Klein  Tara M. Beattie 《Swiss Journal of Geoscience》2015,108(1):147-154

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