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The 2.7–3 Ma Ertsberg East Skarn System (Indonesia), adjacent to the giant Grasberg Porphyry Copper deposit, is part of the world’s largest system of CuAu skarn deposits. Published fluid inclusion and stable isotope data show that it formed through the flux of magma-derived fluid through contact metamorphosed carbonate rock sequences at temperatures well above 600° C and pressures of less than 50 MPa. Under these conditions, the fluid has very low density and the properties of a gas. Combining a range of micro-analytical techniques, high-resolution QEMSCAN mineral mapping and computer-assisted X-ray micro-tomography, an array of coupled gas–solid reactions may be identified that controlled reactive mass transfer through the ~ 1 km3 hydrothermal skarn system. Vacancy-driven mineral chemisorption reactions are identified as a new type of reactive transport process for high-temperature skarn alteration. These gas–solid reactions are maintained by the interaction of unsatisfied bonds on mineral surfaces and dipolar gas-phase reactants such as SO2 and HCl that are continuously supplied through open fractures and intergranular diffusion. Principal reactions are (a) incongruent dissolution of almandine-grossular to andradite and anorthite (an alteration mineral not previously recognized at Ertsberg), and (b) sulfation of anorthite to anhydrite. These sulfation reactions also generate reduced sulfur with consequent co-deposition of metal sulfides. Diopside undergoes similar reactions with deposition of Fe-enriched pyroxene in crypto-veins and vein selvedges. The loss of calcium from contact metamorphic garnet to form vein anhydrite necessarily results in Fe-enrichment of wallrock, and does not require Fe-addition from a vein fluid as is commonly assumed.  相似文献   
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In conducting a search through the IAU Meteor Catalogue at Lund, a peak in activity on April 8th, not corresponding to any known shower was discovered. Analysis of the orbit shows that a subset of those meteors originated on very coherent orbits. It is suggested that there could either represent a hither to unidentified stream or that they are meteoroids which, like the April Lyrids, were ejected from Comet Thatcher but have arrived onto their current orbits as a consequence primarily of Poynting - Robertson drag.  相似文献   
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The need for accurate hydrologic analysis and rainfall–runoff modelling tools has been rapidly increasing because of the growing complexity of operational hydrologic and hydraulic problems associated with population growth, rapid urbanization and expansion of agricultural activities. Given the recent advances in remote sensing of physiographic features and the availability of near real‐time precipitation products, rainfall–runoff models are expected to predict runoff more accurately. In this study, we compare the performance and implementation requirements of two rainfall–runoff models for a semi‐urbanized watershed. One is a semi‐distributed conceptual model, the Hydrologic Engineering Center‐Hydrologic Modelling System (HEC‐HMS). The other is a physically based, distributed‐parameter hydrologic model, the Gridded Surface Subsurface Hydrologic Analysis (GSSHA). Four flood events that took place on the Leon Creek watershed, a sub‐watershed of the San Antonio River basin in Texas, were used in this study. The two models were driven by the Multisensor Precipitation Estimator radar products. One event (in 2007) was used for HEC‐HMS and GSSHA calibrations. Two events (in 2004 and 2007) were used for further calibration of HEC‐HMS. Three events (in 2002, 2004 and 2010) were used for model validation. In general, the physically based, distributed‐parameter model performed better than the conceptual model and required less calibration. The two models were prepared with the same minimum required input data, and the effort required to build the two models did not differ substantially. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Ground-based vegetation monitoring methods are expensive, time-consuming and limited in sample size. Aerial imagery is appealing to managers because of the reduced time and expense and the increase in sample size. One challenge of aerial imagery is detecting differences among observers of the same imagery. Six observers analysed a set of 1-mm ground sample distance aerial imagery for graminoid species composition and important ground-cover characteristics. Kendall's coefficient of concordance (W) was used to measure agreement among observers. The group of six observers was concordant when assessed as a group. When each of the observers was assessed independently against the other five, lack of agreement was found for those graminoid species that were difficult to identify in the aerial images.  相似文献   
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