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1.
We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of26Al,40K,235U,238U and232Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN. 相似文献
2.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
3.
M. Beatriz Aguirre-Urreta Pablo J. Pazos Darío G. Lazo C. Mark Fanning Vanesa D. Litvak 《Journal of South American Earth Sciences》2008,26(1):91-99
A high-resolution ion-microprobe (SHRIMP) U–Pb zircon age from a tuff layer intercalated in the ammonoid bearing sedimentary succession of the Neuquén Basin in Argentina provides a robust geochronologic date to add to the absolute ages and to improve the relative chronology of the Early Cretaceous Hauterivian stage. The tuff layer appears interbedded between shales of the upper member (Agua de la Mula) of the Agrio Formation within the Spitidiscus riccardii ammonoid zone (base of the Late Hauterivian) yielding a date of 132.5 ± 1.3 Ma. This date confirms and supports an accurate correlation between the ammonoid biostratigraphy of the Neuquén Basin with the Western Mediterranean Province of the Tethys during the Early Cretaceous and matches with the most recently published time scale. It also casts doubts on the validity of K–Ar ages on glauconite-grains recently reported from the Lower Cretaceous of the Vocontian Basin of France. 相似文献
4.
We investigate the effect of the temperature–size rule upon zooids of the tropical American bryozoan Cupuladria exfragminis. Results show that mean zooid length, zooid width and zooid area vary significantly between clonal replicates of C. exfragminis kept under different controlled temperature conditions. Significantly larger zooids are produced during times of lowered water temperature that are comparable with the temperatures that occur during seasonal upwelling along the Pacific coast of Panama where the animal lives in abundance. Interpolation of data suggests that a drop of 1 °C causes a 5% increase in zooid size, and that almost all variation in zooid size in natural populations can be explained by temperature. Results are discussed in context of the potential use of zooid size variation in cupuladriid bryozoans to measure the strength of seasonal upwelling in ancient seas by analysing zooid size changes in fossil colonies. The technique of cloning cupuladriid colonies by fragmentation is also discussed with reference to its benefits in experimental studies where genotypes need to be controlled or replicated. 相似文献
5.
6.
A series of patterns in the chemical and isotopic composition of the groundwater of the Cerro Prieto area have been recognized. These patterns were used to define four hydrochemical and isotopical zones in the area. One of these areas located at the east side was found to be the source of recharge, while another in the central part is where an older aquifer exist in lacustrine deposits. The low permeability of the area causes the aquifer to act as an aquitard, which at least is partly surrounded by an interface zone where mixing of waters occurs. Tritium and radiocarbon method revealed that the aquitard is an isolate system whose residence time is of 32 ka. 相似文献
7.
8.
Harriet Bulkeley JoAnn Carmin Vanesa Castán Broto Gareth A.S. Edwards Sara Fuller 《Global Environmental Change》2013,23(5):914-925
Ever since climate change came to be a matter of political concern, questions of justice have been at the forefront of academic and policy debates in the international arena. Curiously, as attention has shifted to other sites and scales of climate change politics matters of justice have tended to be neglected. In this paper, we examine how discourses of justice are emerging within urban responses to climate change. Drawing on a database of initiatives taking place in 100 global cities and qualitative case-study research in Philadelphia, Quito and Toronto, we examine how notions of distributive and procedural justice are articulated in climate change projects and plans in relation to both adaptation and mitigation. We find that there is limited explicit concern with justice at the urban level. However, where discourses of justice are evident there are important differences emerging between urban responses to adaptation and mitigation, and between those in the north and in the south. Adaptation responses tend to stress the distribution of ‘rights’ to protection, although those in the South also stress the importance of procedural justice. Mitigation responses also stress ‘rights’ to the benefits of responding to climate change, with limited concern for ‘responsibilities’ or for procedural justice. Intriguingly, while adaptation responses tend to stress the rights of individuals, we also find discourses of collective rights emerging in relation to mitigation. 相似文献
9.
10.
This study defines a chemical representation of the kerogen macromolecule based on data from physicochemical analyses. The model should permit: creation of various schematic drawings representing an average macromolecule; future integration of new analytical results (for instance on structures of biomarkers or biopolymers); and determination of the distribution of chemical bonds.The models developed in this study can be represented in a 3D space, using classical chemical symbols, in the form of cyclic groups linked to each other by aliphatic chains. One cyclic group is a connected set of aromatic, naphthenoaromatic or naphthenic rings. These cyclic groups are constructed using basic elements such as atoms and bonds defined by their length and direction.Modeling of kerogen is done in three successive steps. A library is first created to define atoms, bonds and cyclic groups. Secondly, starting from a set of equations describing the analytical results, cyclic and aliphatic groups are chosen in the appropriate stoechiometric amount to match the analytical data. Finally the construction is done: cyclic groups are placed randomly in a 3D space, connections are made by aliphatic chains, and functional groups are added.The molecular modeling software XmolTM can be operated on APOLLO stations. It allows the creation of libraries, the calculation of chemical bonds corresponding to the analyses and the construction of macromolecules. An example is given for a type III kerogen at the beginning of diagenesis. 相似文献